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Physical & Chemical properties

Vapour pressure

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
GLP compliance:
yes (incl. QA statement)
Type of method:
effusion method: vapour pressure balance
Specific details on test material used for the study:
Identification: di-tert-butyl hydroquinone
CAS No: 88-58-4
Appearance/Physical state: White solid
Batch: TS140610
Purity: 99.6%
Expiry date: 01 March 2019
Storage conditions: Room temperature in the dark
Key result
Test no.:
#3
Temp.:
25 °C
Vapour pressure:
< 0.006 Pa

The test item did not change in appearance under the conditions used in the determination.

No statistical analyses were performed because the balance readings were too low and variable for a line of best fit to have any meaning. Instead it was considered more appropriate to impose a regression slope on a chosen data point to provide an estimate of the maximum value for the vapor pressure at 25 ºC.

Run 3 was chosen because the sample had been under vacuum for the longest period prior to this run and so degassing would have been the most complete. The reading at 30 ºC (303 K) was chosen because this is the data point which gives the highest estimated vapor pressure at any given temperature when a slope of –1500 K is imposed upon it.

The value of –1500 K is an in-house value and is the shallowest slope observed whilst determining the vapor pressure on a wide range of samples using the vapor pressure balance method. Extrapolation to 25 ºC gave a vapor pressure of 6.29 x 10-3 Pa which has been taken as a maximum for this material.

The results may represent rounded values obtained by calculations based on the exact raw data. Conclusion

The vapor pressure of the test item has been determined to be less than 6.3 x 10-3 Pa at 25 ºC.

Conclusions:
The vapor pressure of di-tert-butyl hydroquinone has been determined to be less than 6.3 x 10-3 Pa at 25 °C,
Executive summary:

The vapor pressure of di-tert-butyl hydroquinone has been determined to be less than 6.3 x 10-3 Pa at 25 °C, using the vapor pressure balance method, designed to be compatible with Method A.4 Vapour Pressure of Commission Regulation (EC) No 440/2008 of 30 May 2008 and Method 104 of the OECD Guidelines for Testing of Chemicals, 23 March 2006.

Description of key information

Key value for chemical safety assessment

Vapour pressure:
0.006 Pa
at the temperature of:
25 °C

Additional information