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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
08 - 10 February 2017
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2017

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Version / remarks:
2003
Deviations:
no
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
Vinyl propionate
EC Number:
203-293-5
EC Name:
Vinyl propionate
Cas Number:
105-38-4
Molecular formula:
C5H8O2
IUPAC Name:
ethenyl propanoate
impurity 1
Reference substance name:
Unknown impurities.
Molecular formula:
Not available as unknown impurities.
IUPAC Name:
Unknown impurities.
impurity 2
Chemical structure
Reference substance name:
Water
EC Number:
231-791-2
EC Name:
Water
Cas Number:
7732-18-5
Molecular formula:
H2O
IUPAC Name:
Oxidane
Test material form:
liquid: volatile
Details on test material:
Batch No: 57161235
Storage: Room temperature (approx. 20°C)

Results and discussion

Auto-ignition temperature (liquids / gases)
Key result
Auto-ignition temperature:
395 °C
Atm. press.:
>= 1 008.7 - <= 1 014.9 hPa

Any other information on results incl. tables

Preliminary test:

The lowest temperature at which an ignition occurred was 408°C.

Main test:

Based on the results of the main test series, the lowest auto-ignition temperature was 398°C, see table below.

 Main test series  Lowest temperatures of an ignition  Highest temperatures without an ignition  Atmospheric Pressure
 1  398°C  395°C  1010.7 - 1014.9 hPa
 2  398°C  395°C  1012.3 - 1014.5 hPa
 3  400°C  397°C

 1008.7 - 1008.9 hPa

Regulation EC No. 440/2008 and DIN 51794: The auto-ignition temperature rounded down to the nearest multiple of 5°C was determined as 395°C.

Applicant's summary and conclusion

Conclusions:
The auto-ignition temperature of the test item was determined to be 395°C. According to DIN EN 13463-1 the test item has to be assigned to temperature class T2.
Executive summary:

The test item Vinylpropionate (CAS 105 -38 -4) has an auto-ignition temperature of 395°C according to the Regulation EC No. 440/2008 Method A.15. Auto-Ignition Temperature (Liquids and Gases) and DIN 51794 (2003).