Registration Dossier
Registration Dossier
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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 215-851-5 | CAS number: 1429-50-1
Guidance on Safe Use
Administrative data
First-aid measures
General Notes Immediately call a POISON CENTER or doctor/physician.
Inhalation Remove patient to fresh air, keep warm and at rest, administer oxygen if necessary.
Skin Contact Thoroughly wash the contaminated skin. Remove the contaminated clothes and shoes. Consult a doctor if symptoms develop. Wash the clothes and shoes before reusing them
Eye Contact Immediately wash the eyes thoroughly, opening eyelashes from time to time. Check if the victim is wearing contact lenses; if yes, remove them. Wash for at least 10 minutes. Consult a doctor in case of irritation.
Ingestion Immediately consult a physician for advice.
Fire-fighting measures
Extinguishing media:
Suitable extinguishing media: Water spray, foam, dry chemical, or carbon dioxide
Unsuitable extinguishing media: None known
Special Hazards arising from the substance / mixture: Decomposes and gives irritant fumes.
Hazardous Combustion Product: Can release CO, CO2, NOx, PxOy and Phosphines.
Advise for fire fighters:
Wear self-contained breathing apparatus and suitable protective clothing.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non emergency personnel:
Protective Equipment Use personal protection recommended in section 8
Emergency Procedures Evacuate the spill area safely to permit authorised personnel to handle the spill.
For Emergency Responders Emergency responders must wear the proper personal protective equipment (and have appropriate fire-suppression equipment) suitable for the situation to which they are responding.
Environmental precautions:
Keep out of drains and watercourses. Use containment walls to contain, reclaim or safely dispose off spills. Follow local regulations for safe disposal of contaminated absorbent materials and containers. Wash spill areas with water.
Methods and material for containment and cleaning up:
Contain large spills with containment walls and transfer the material to appropriate containers for reclamation or disposal. Collect by sweep, scoop or vacuum and remove. Flush spill area with water. Small spills can be neutralised with lime or soda followed by flushing with water or by absorbing on inert materials like sand, diatomaceous earth etc. Dispose off such materials following local regulations.
Additional information: Avoid contact with skin and eyes. If spillage occurs on the public highway, indicate the danger and notify the authorities (police, fire brigade).
Handling and storage
Precautions for safe handling:
Protective measures Handle in accordance with good industrial hygiene and safety practices as mentioned in section 8.2. These practices include using appropriate personal protection, avoiding unnecessary exposure and removal of material from eyes, skin and clothing. Do not eat, drink or smoke when handling this product. Wash thoroughly after handling, avoid breathing dust. Emptied containers retain vapour and product residue. Observe all recommended safety precautions until container is cleaned, recPersonal precautions, protective equipment and emergency procedures
For non emergency personnel:
Protective Equipment Use personal protection recommended in section 8
Emergency Procedures Evacuate the spill area safely to permit authorised personnel to handle the spill.
For Emergency Responders Emergency responders must wear the proper personal protective equipment (and have appropriate fire-suppression equipment) suitable for the situation to which they are responding.
Environmental precautions:
Keep out of drains and watercourses. Use containment walls to contain, reclaim or safely dispose off spills. Follow local regulations for safe disposal of contaminated absorbent materials and containers. Wash spill areas with water.
Methods and material for containment and cleaning up:
Contain large spills with containment walls and transfer the material to appropriate containers for reclamation or disposal. Collect by sweep, scoop or vacuum and remove. Flush spill area with water. Small spills can be neutralised with lime or soda followed by flushing with water or by absorbing on inert materials like sand, diatomaceous earth etc. Dispose off such materials following local regulations.
Additional information: Avoid contact with skin and eyes. If spillage occurs on the public highway, indicate the danger and notify the authorities (police, fire brigade).
onditioned or destroyed. The reuse of this material's container for non-industrial purposes is prohibited and any reuse must be in consideration of the data provided in this material safety data sheet.
Advice on general occupational Hygiene Keep personal protective equipment in a clean place, away from the work area. Use clean and correctly maintained personal protective equipment. Always wash your hands after handling the product.
Do NOT eat or drink in the workplace.
7.2 Conditions for safe storage including any incompatibilities:
Technical measures and storage conditions Take all necessary precautions to avoid the accidental release of the product outside due to the rupture of containers or transfer systems. Ensure there is a suitable retention system. Storage facilities should be dry.
Packing Material:
Suitable packing and storage material Fiber drums, laminated paper bags, Original containers or metal containers with glass, PVC, PP, PE or GRP lining.
Unsuitable packing and storage material Do not store in metal containers such as carbon steel, aluminium etc.
Requirements for storage rooms and vessels Store in a cool, well ventilated area.
Storage Class 13
Further information on storage conditions Shelf life: 24 months
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control Parameters
1mg/m3 TWA and 7 mg/m3 STEL
DNEL Oral
(mg/kg bw/day) Inhalation
(mg/m³) Dermal
(mg/kg bw/day)
Industry – long term – local effects - - -
Industry – long term – systemic effects - 0.02 0.011
Industry – short term – local effects - - -
Industry – short term – systemic effects - 0.02 0.011
Consumer – long term – local effects - - -
Consumer – long term – systemic effects 0.19 0.0065 0.008
Consumer – short term – local effects - - -
Consumer – short term – systemic effects 0.19 0.0065 0.008
PNEC Value
PNECaqua – freshwater (mg/L) 0.25
PNECaqua - marine water (mg/l) 0.025
PNECsediment (freshwater) (mg/kg sediment WWT) 301
PNEC sediment (marine water) (mg/kg sediment WWT) 30
PNECsoil (mg/kg wwt) 120
PNECstp (mg/L) >10
PNECoral ( mg/kg food) NA
Exposure controls
Appropriate engineering controls No specific additional engineering controls are required. Provide good natural or artificial ventilation.
Personal Protection equipment
Eye / face protection Face shield and/or chemical goggles. Have eye wash facilities immediately available at any location where eye contact can occur.
Skin protection
Hand Protection:
Other skin protection: Wear gloves, suitable materials include PVC, Nitrile Rubber. Wear suitable protective clothing, wash thoroughly after handling. Although this product does not present a significant skin concern, minimize skin contamination by following good industrial practice.
Respiratory protection Avoid breathing vapour / mist. Use approved respiratory protection equipment when air borne exposure is excessive. Consult respirator manufacturer to determine the appropriate type of equipment for a given application. Observe respirator use limitations specified by the manufacturer. In case of insufficient ventilation, wear suitable respiratory equipment
Environmental Protection Control Avoid direct discharge into drains
Stability and reactivity
Reactivity Reacts vigorously with alkalis, metals and oxidising agents
Chemical Stability Stable under normal conditions of storage and transport
Possibility of hazardous reactions Reacts vigorously with alkalis, metals and oxidising agents. Can liberate flammable hydrogen gas on reaction with metals.
Conditions to avoid None specific
Incompatible materials Alkalis, metals and oxidising agents
Hazardous decomposition products Carbon monoxide, carbon dioxide, phosphines, phosphorous oxides (PxOy) and NOx
Disposal considerations
Disposal considerations
Waste treatment methods
Product
Methods of disposal: The generation of waste should be avoided or minimized wherever
possible. All local and national regulations should be followed. Consult regulatory officials for disposal requirement. For small quantities neutralize with lime or soda ash and flush away with plenty of water. For large quantities send to special waste disposal system and burn in proper incinerator. This product should not be dumped in public storage and sewers / waterways. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.
For disposal within the EC, the appropriate code according to the European Waste List (EWL) should be used. It is among the tasks of the polluter to assign the waste to waste codes
Hazardous waste The classification of the product meet the criteria for a hazardous waste as per Annex III of DIRECTIVE 2008/98/EC: (H4- Irritant)
Packaging
Methods of disposal The generation of waste should be avoided or minimised wherever possible. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible
Special precautions This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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