Registration Dossier
Registration Dossier
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EC number: 216-447-1 | CAS number: 1586-92-1
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General advice:
Immediate medical attention is required.
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
If inhaled:
If breathed in, move person into fresh air.
Consult a physician after significant exposure.
In case of skin contact:
Take off contaminated clothing and shoes immediately.
Rinse immediately with plenty of water.
Immediate medical treatment is necessary as untreated wounds from corrosion of the skin heal slowly and with difficulty.
In case of eye contact:
Rinse with plenty of water.
Get medical attention immediately. Continue to rinse during transport.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
Small amounts splashed into eyes can cause irreversible tissue damage and blindness.
If swallowed:
Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
Do not induce vomiting! May cause chemical burns in mouth and throat.
Most important symptoms and effects, both acute and delayed
Symptoms:
The symptoms and effects are as expected from the hazards as shown in Hazards Identification on SDS. No specific product related symptoms are known.
Indication of any immediate medical attention and special treatment needed
Treatment:
Treat symptomatically.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
In case of fire: Use vermiculite, dry chemical powder or dry sand for extinction.
Unsuitable extinguishing media:
Water
Foam
Carbon dioxide (CO2)
Special hazards arising from the substance or mixture
Specific hazards during firefighting / Specific hazards arising from the chemical:
CAUTION: reignition may occur.
Waterspray may only be used by experienced fire fighters.
Combustion products:
Fire will produce smoke containing hazardous combustion products (see Stability and Reactivity).
Advice for firefighters
Special protective equipment for firefighters:
Wear self-contained breathing apparatus and protective suit.
Further information:
After fire has been extinguished or has been allowed to burn out completely, wait CONSIDERABLE TIME (until smoke is no longer observed).
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions:
Use personal protective equipment.
Ensure adequate ventilation.
Ignition will occur.
Allow controlled hydrolysis.
Stop leak if safe to do so.
Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas.
Environmental precautions
Environmental precautions:
Prevent product from entering drains.
Methods and materials for containment and cleaning up
Methods for cleaning up / Methods for containment:
Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see Disposal Considerations).
Ensure that the product is completely non-reactive before cleaning up.
Reference to other sections
Additional advice:
For personal protection see Exposure Controls / Personal Protection.
Handling and storage
Precautions for safe handling
Advice on safe handling:
For personal protection see Exposure Controls / Personal Protection.
Smoking, eating and drinking should be prohibited in the application area.
Handle and open container with care.
Advice on protection against fire and explosion:
Keep away from sources of ignition - No smoking.
No sparking tools should be used.
Do not cut or weld on or near this container even when empty.
Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
No smoking.
Keep container tightly closed in a dry and well-ventilated place.
Electrical installations / working materials must comply with the technological safety standards.
Keep under nitrogen.
Advice on common storage:
Never allow product to get in contact with water during storage.
Other data:
No decomposition if stored and applied as directed.
Specific end use(s)
Specific use(s):
Consult the technical guidelines for the use of this substance/mixture.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 3394
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SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 3394
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 3394
Shipping information
- Proper shipping name and description:
- Organometallic Substance, Liquid, Pyrophoric, Water-reactive (Diethylaluminum ethoxide)
- Chemical name:
- Diethylaluminum ethoxide
- Labels:
- 4.2 (4.3)
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- Not permitted for transport
Shipping information
- Proper shipping name and description:
- Not permitted for transport
- Chemical name:
- Not permitted for transport
- Labels:
- Not permitted for transport
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Control parameters
Components with workplace control parameters
Contains no substances with occupational exposure limit values.
Exposure controls
Engineering Controls
Effective exhaust ventilation system
Ensure that eyewash stations and safety showers are close to the workstation location.
Personal protective equipment
Respiratory protection:
In the case of vapour or aerosol formation use a respirator with an approved filter.
Filter A
Hand protection:
Heavy PVC or leather (cowhide); both with long gauntlets.
Eye protection:
Safety glasses and face-shield
Skin and body protection:
Aluminised suit and protective boots.
For further advice contact manufacturer.
Hygiene measures:
Handle in accordance with good industrial hygiene and safety practice.
Wash hands before breaks and at the end of workday.
Environmental exposure controls
General advice:
Prevent product from entering drains.
Stability and reactivity
10.1 Reactivity
Stable under normal conditions.
10.2 Chemical stability
To avoid thermal decomposition, do not overheat.
10.3 Possibility of hazardous reactions
Reacts violently with water.
10.4 Conditions to avoid
Conditions to avoid
:
Heat, flames and sparks.
Exposure to moisture.
10.5 Incompatible materials
Materials to avoid
:
Avoid contact with moisture and water, alcohols, acids, organic halides and oxygen containing compounds.
10.6 Hazardous decomposition products
Hazardous decomposition products
:
Aluminium oxide
Carbon oxides
Hydrocarbons
Thermal decomposition
:
To avoid thermal decomposition, do not overheat.
Disposal considerations
Waste treatment methods
Product:
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with chemical or used container.
Hazardous waste
Dispose of contents/container in accordance with local regulation.
Contaminated packaging:
Empty remaining contents.
Dispose of as unused product.
Do not burn, or use a cutting torch on, the empty drum.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
