Registration Dossier
Registration Dossier
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EC number: 246-107-8 | CAS number: 24245-27-0
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
General information: If symptoms persist, call a physician. Remove/Take off immediately all contaminated clothing.
After inhalation: Remove to fresh air.
After contact with skin: In case of contact, immediately flush skin with soap and plenty of water.
After contact with eyes: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After ingestion: Get medical attention immediately.
Most important symptoms and effects, both acute and delayed
Symptoms: Irritating to mucous membranes. Irritating to eyes.
Hazards: No additional hazards are known except those derived from the labelling.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat symptomatically.
After inhalation: Remove to fresh air.
After contact with skin: In case of contact, immediately flush skin with soap and plenty of water.
After contact with eyes: In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
After ingestion: Get medical attention immediately.
Most important symptoms and effects, both acute and delayed
Symptoms: Irritating to mucous membranes. Irritating to eyes.
Hazards: No additional hazards are known except those derived from the labelling.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat symptomatically.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Carbon dioxide (CO2); Dry powder; Water mist; Alcohol-resistant foam
Extinguishing media that must not be used for safety reasons: High volume water jet
Special hazards arising from the substance or mixture
In case of fire hazardous decomposition products may be produced such as: Carbon monoxide; Carbon dioxide (CO2)
Advice for firefighters
Special protective equipment for firefighting: Self-contained breathing apparatus
Suitable extinguishing media: Carbon dioxide (CO2); Dry powder; Water mist; Alcohol-resistant foam
Extinguishing media that must not be used for safety reasons: High volume water jet
Special hazards arising from the substance or mixture
In case of fire hazardous decomposition products may be produced such as: Carbon monoxide; Carbon dioxide (CO2)
Advice for firefighters
Special protective equipment for firefighting: Self-contained breathing apparatus
Accidental release measures
Personal precautions, protective equipment and emergency procedures: Wear suitable protective equipment. Avoid contact with skin and eyes.
Environmental precautions: Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water.
Methods and material for containment and cleaning up: Brush up wearing suitable PPE. Dispose of material in accordance with the regulations.
Additional information: Information regarding Safe handling, see respective chapter.
Environmental precautions: Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water.
Methods and material for containment and cleaning up: Brush up wearing suitable PPE. Dispose of material in accordance with the regulations.
Additional information: Information regarding Safe handling, see respective chapter.
Handling and storage
Precautions for safe handling
Advice on safe handling: Handle and open container with care.
Hygiene measures: Wash hands before breaks and at the end of workday. Take off immediately all contaminated clothing and wash it before reuse.
Advice on protection against fire and explosion: The product is not easily combustible, does not add to the spreading of fire, is not self combustible nor is it explosive.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep containers tightly closed in a cool, well-ventilated place. Handle and open container with care.
Specific end use(s): No further recommendations.
Advice on safe handling: Handle and open container with care.
Hygiene measures: Wash hands before breaks and at the end of workday. Take off immediately all contaminated clothing and wash it before reuse.
Advice on protection against fire and explosion: The product is not easily combustible, does not add to the spreading of fire, is not self combustible nor is it explosive.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep containers tightly closed in a cool, well-ventilated place. Handle and open container with care.
Specific end use(s): No further recommendations.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 2811
Shipping information
- Proper shipping name and description:
- Toxic solid, organic, n.o.s.
Hazard inducer(s): Diphenylguanidine derivative
Special provisions / remarks
- Remarks:
- Shipment permitted
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 2811
Shipping information
- Proper shipping name and description:
- Toxic solid, organic, n.o.s.
Hazard inducer(s): Diphenylguanidine derivative
Special provisions / remarks
- Remarks:
- Shipment permitted
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 2811
Shipping information
- Proper shipping name and description:
- Toxic solid, organic, n.o.s.
Special provisions / remarks
- Remarks:
- Shipment permitted
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 2811
Shipping information
- Proper shipping name and description:
- Toxic solid, organic, n.o.s.
Hazard inducer(s): Diphenylguanidine derivative
Special provisions / remarks
- Remarks:
- Shipment permitted
Additional transport information
Additional information
- Special provisions / remarks / other:
- Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International Bulk Chemicals Code)
Exposure controls / personal protection
Control parameters
Exposure limit values: Exposure limit values are not available.
DNEL/DMEL values: DNEL/DMEL values are not available.
PNEC values: PNEC values are not available.
Exposure controls
General protective measures: Observe the usual precautions for handling chemicals.
Respiratory protection: Use respiratory protection in case of insufficient exhaust ventilation or prolonged exposure. Full mask to standard DIN EN 136. Combination filter A/P3 to standard DIN EN 141. The use of filter apparatus presupposes that the environment atmosphere contains at least 17% oxygen by volume, and does not exceed the maximum gas concentration, usually 0.5% by volume. Relevant guidelines to be considered include EN 136/141/143/371/372 as well as other national regulations. Observe applicable relevant national regulations,(e.g. TRGS 900 and BGR 190 in Germany).Take note of the recommendedations regarding the duration for which Respiratory Protective Equipment may be worn, according to chapter 19 Abs. 5 GefStoffV in conjunction with the rules of wearing such equipment.
Hand protection : PVC-coated gloves. Minimum breakthrough time / gloves : > 1 h. Minimum thickness / gloves 0,8 mm. Nitrile rubber gloves. Minimum breakthrough time / gloves : > 1 h Minimum thickness / gloves 0,35 mm. These types of protective gloves are offered by various manufacturers. Please note the manufacturers´ detailed statements, especially about the minimum thickness and the minimum breakthrough time. Consider also the particular working conditions under which the gloves are being used.
Eye protection : Safety goggles
Exposure limit values: Exposure limit values are not available.
DNEL/DMEL values: DNEL/DMEL values are not available.
PNEC values: PNEC values are not available.
Exposure controls
General protective measures: Observe the usual precautions for handling chemicals.
Respiratory protection: Use respiratory protection in case of insufficient exhaust ventilation or prolonged exposure. Full mask to standard DIN EN 136. Combination filter A/P3 to standard DIN EN 141. The use of filter apparatus presupposes that the environment atmosphere contains at least 17% oxygen by volume, and does not exceed the maximum gas concentration, usually 0.5% by volume. Relevant guidelines to be considered include EN 136/141/143/371/372 as well as other national regulations. Observe applicable relevant national regulations,(e.g. TRGS 900 and BGR 190 in Germany).Take note of the recommendedations regarding the duration for which Respiratory Protective Equipment may be worn, according to chapter 19 Abs. 5 GefStoffV in conjunction with the rules of wearing such equipment.
Hand protection : PVC-coated gloves. Minimum breakthrough time / gloves : > 1 h. Minimum thickness / gloves 0,8 mm. Nitrile rubber gloves. Minimum breakthrough time / gloves : > 1 h Minimum thickness / gloves 0,35 mm. These types of protective gloves are offered by various manufacturers. Please note the manufacturers´ detailed statements, especially about the minimum thickness and the minimum breakthrough time. Consider also the particular working conditions under which the gloves are being used.
Eye protection : Safety goggles
Stability and reactivity
Reactivity: See respective section "Possibility of hazardous reactions"
Chemical stability: Stable under normal conditions.
Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use.
Conditions to avoid: Strong oxidizing agents
Incompatible materials: not known
Hazardous decomposition products: Nitrogen oxides (NOx); Hydrogen chloride; Ammonia
Chemical stability: Stable under normal conditions.
Possibility of hazardous reactions: No dangerous reaction known under conditions of normal use.
Conditions to avoid: Strong oxidizing agents
Incompatible materials: not known
Hazardous decomposition products: Nitrogen oxides (NOx); Hydrogen chloride; Ammonia
Disposal considerations
Waste treatment methods
Product: Product should be taken to a suitable and authorized waste disposal site in accordance with relevant regulations and if necessary after consultation with the waste disposal operator and/or the competent Authorities.
Uncleaned packaging: Contaminated packaging material should be treated equivalent to residual chemicals. Clean packaging material should be subjected to waste management schemes (recovery recycling, reuse) according to local legislation.
Product: Product should be taken to a suitable and authorized waste disposal site in accordance with relevant regulations and if necessary after consultation with the waste disposal operator and/or the competent Authorities.
Uncleaned packaging: Contaminated packaging material should be treated equivalent to residual chemicals. Clean packaging material should be subjected to waste management schemes (recovery recycling, reuse) according to local legislation.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
