Registration Dossier
Registration Dossier
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EC number: 266-018-8 | CAS number: 65996-84-1 The reaction product obtained by neutralizing coal tar base extract oil with an alkaline solution, such as aqueous sodium hydroxide, to obtain the free bases. Composed primarily of such organic bases as acridine, phenanthridine, pyridine, quinoline and their alkyl derivatives.
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General information
Personal protection for the First Aider.
Instantly remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the
accident.
After inhalation
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness bring patient into stable side position for transport.
After skin contact
Instantly rinse with water.
Rinse with ethanoic acid 8% and plenty of water.
Seek medical treatment.
After eye contact
Rinse opened eye for several minutes under running water.
Seek medical treatment.
After swallowing
Attention, danger of aspiration!
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; instantly call for medical help.
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Information for doctor
Therapeutically measures: basic help, decontamination, symptomatic treatment.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
General information
Personal protection for the First Aider.
Instantly remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the
accident.
After inhalation
Supply fresh air or oxygen; call for doctor.
In case of unconsciousness bring patient into stable side position for transport.
After skin contact
Instantly rinse with water.
Rinse with ethanoic acid 8% and plenty of water.
Seek medical treatment.
After eye contact
Rinse opened eye for several minutes under running water.
Seek medical treatment.
After swallowing
Attention, danger of aspiration!
Rinse out mouth and then drink plenty of water.
Do not induce vomiting; instantly call for medical help.
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Information for doctor
Therapeutically measures: basic help, decontamination, symptomatic treatment.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Fire-fighting measures
Extinguishing media
Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fire with foam.
For safety reasons unsuitable extinguishing agents
Water with a full water jet.
Special hazards arising from the substance or mixture
Can be released in case of fire
Nitrogen oxides (NOx)
Carbon monoxide (CO)
Advice for firefighters
Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear self-contained breathing apparatus.
Additional information
Cool endangered containers with water spray jet.
Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fire with foam.
For safety reasons unsuitable extinguishing agents
Water with a full water jet.
Special hazards arising from the substance or mixture
Can be released in case of fire
Nitrogen oxides (NOx)
Carbon monoxide (CO)
Advice for firefighters
Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear self-contained breathing apparatus.
Additional information
Cool endangered containers with water spray jet.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment.
Keep unprotected persons away.
Environmental precautions:
Do not allow to enter drainage system, surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Reference to other sections
See Section "Handling and storage" for information on safe handling
See Section "Exposure controls/personal protection" for information on personal protection equipment.
See Section "Disposal considerations" for information on disposal.
Wear protective equipment.
Keep unprotected persons away.
Environmental precautions:
Do not allow to enter drainage system, surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Reference to other sections
See Section "Handling and storage" for information on safe handling
See Section "Exposure controls/personal protection" for information on personal protection equipment.
See Section "Disposal considerations" for information on disposal.
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(4) for on-site isolated intermediates and in accordance with REACH regulation Article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor or Manufacturer / Downstream User of the Registrant’s intermediate.
Precautions for safe handling
Only handle and refill product in closed systems.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and containers:
Store only in the original container.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Specific end use(s)
No further relevant information available.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor or Manufacturer / Downstream User of the Registrant’s intermediate.
Precautions for safe handling
Only handle and refill product in closed systems.
Ensure good ventilation/exhaustion at the workplace.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and containers:
Store only in the original container.
Information about storage in one common storage facility:
Store away from oxidizing agents.
Further information about storage conditions:
Keep container tightly sealed.
Specific end use(s)
No further relevant information available.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(4) for on-site isolated intermediates and in accordance with REACH regulation Article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each Manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor or Manufacturer / Downstream User of the Registrant’s intermediate.
Control parameters
Components with limit values that require monitoring at the workplace:
62-53-3 aniline
WEL Long-term value: 4 mg/m³, 1 ppm
Sk
110-86-1 pyridine
WEL Short-term value: 33 mg/m³, 10 ppm
Long-term value: 16 mg/m³, 5 ppm
95-53-4 o-toluidine
WEL Long-term value: 0.89 mg/m³, 0.2 ppm
Carc; Sk
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Store protective clothing separately.
Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air.
Filter ABEK
Protection of hands:
Only use chemical-protective gloves with CE-labelling of category III (EN 374).
Material of gloves
Nitrile rubber, NBR
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
For the permanent contact in work areas without heightened risk of injury (e.g. Laboratory) gloves made of the following material are suitable:
Nitril rubber, NBR
Butyl rubber, BR
As protection from splashes gloves made of the following materials are suitable:
Nitril rubber, NBR
Butyl rubber, BR
Eye protection:
Gauze goggles
Tightly sealed safety glasses.
Body protection:
Protective work clothing.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor or Manufacturer / Downstream User of the Registrant’s intermediate.
Control parameters
Components with limit values that require monitoring at the workplace:
62-53-3 aniline
WEL Long-term value: 4 mg/m³, 1 ppm
Sk
110-86-1 pyridine
WEL Short-term value: 33 mg/m³, 10 ppm
Long-term value: 16 mg/m³, 5 ppm
95-53-4 o-toluidine
WEL Long-term value: 0.89 mg/m³, 0.2 ppm
Carc; Sk
Exposure controls
Personal protective equipment
General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Store protective clothing separately.
Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that is independent of circulating air.
Filter ABEK
Protection of hands:
Only use chemical-protective gloves with CE-labelling of category III (EN 374).
Material of gloves
Nitrile rubber, NBR
Butyl rubber, BR
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
For the permanent contact in work areas without heightened risk of injury (e.g. Laboratory) gloves made of the following material are suitable:
Nitril rubber, NBR
Butyl rubber, BR
As protection from splashes gloves made of the following materials are suitable:
Nitril rubber, NBR
Butyl rubber, BR
Eye protection:
Gauze goggles
Tightly sealed safety glasses.
Body protection:
Protective work clothing.
Stability and reactivity
Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No further relevant information available.
Incompatible materials:
No further relevant information available.
Hazardous decomposition products:
No dangerous decomposition products known
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Possibility of hazardous reactions
No dangerous reactions known
Conditions to avoid
No further relevant information available.
Incompatible materials:
No further relevant information available.
Hazardous decomposition products:
No dangerous decomposition products known
Disposal considerations
Waste treatment methods
Recommendation
Remove according to local authority recommendations, e.g. convey to a suitable incinerator.
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
European waste catalogue
The waste code classification is to be carried out according to the European Waste Catalogue (EWC) specifically for each branch of industry and each type of process.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
Recommendation
Remove according to local authority recommendations, e.g. convey to a suitable incinerator.
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
European waste catalogue
The waste code classification is to be carried out according to the European Waste Catalogue (EWC) specifically for each branch of industry and each type of process.
Uncleaned packagings:
Recommendation:
Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
