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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
phototransformation in water
Type of information:
migrated information: read-across from supporting substance (structural analogue or surrogate)
Adequacy of study:
other information
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Reliable source.

Data source

Referenceopen allclose all

Reference Type:
study report
Title:
Unnamed
Year:
1986
Reference Type:
study report
Title:
Unnamed
Year:
1990

Materials and methods

Study type:
not specified
Principles of method if other than guideline:
no data
GLP compliance:
not specified

Test material

Constituent 1
Chemical structure
Reference substance name:
(R)-2-(4-chloro-2-methylphenoxy)propionic acid
EC Number:
240-539-0
EC Name:
(R)-2-(4-chloro-2-methylphenoxy)propionic acid
Cas Number:
16484-77-8
Molecular formula:
C10H11ClO3
IUPAC Name:
(2R)-2-(4-chloro-2-methylphenoxy)propanoic acid
Constituent 2
Reference substance name:
Mecoprop-P acid
IUPAC Name:
Mecoprop-P acid
Constituent 3
Reference substance name:
MCPP-P acid
IUPAC Name:
MCPP-P acid

Results and discussion

% Degradationopen allclose all
% Degr.:
50
Sampling time:
680 h
Test condition:
pH 5
% Degr.:
50
Sampling time:
1 019 h
Test condition:
pH 7
% Degr.:
50
Sampling time:
415 h
Test condition:
pH 9

Applicant's summary and conclusion

Validity criteria fulfilled:
not specified
Remarks:
expected to be a valid source
Conclusions:
For Mecoprop-P acid (MCPP-P acid) phototransformation in water revealed half-lives of 680, 1019 and 415 hours at pH 5, 7 and 9, respectively.
Executive summary:

Mecoprop-P n-octyl ester hydrolyses rapidly in natural water. Therefore, the hydrolysis product Mecoprop-P acid (MCPP-P acid) was used for further risk assessment of Mecoprop-P n-octyl ester in the environment.

 

For Mecoprop-P acid (MCPP-P acid) phototransformation in water revealed half-lives of 680, 1019 and 415 hours at pH 5, 7 and 9, respectively.