Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 475-900-3 | CAS number: -
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
First aid measures
If inhaled
- In case of accident by inhalation remove casualty to freash air and keep at rest
- Victim to lie down in the recovery position, cover and keep him warm.
- Oxygen or artificial respiration if needed.
- Immediate medical attention is required.
In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Immediate medical attention is required.
In case of skin contact
- Remove and wash contaminated clothing before to re-use.
- Wash off with soap and water.
- If symptoms persist call a physician
If swallowed
- If swallowed, rinse mouth with water ( only if the person is conscious).
- Do not induce vomiting
- Artificial respiration and/or oxygen may be necessary.
- Take victim immediately to hospital
Most important symptoms/effects, acute and delayed
Inhalation
- May cause respiratory irritation and drowsiness or dizziness.
- Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting.
- Risk of loss of consciousness
- Risk of lung oedema, chemical pneumonitis.
Skin contact
- Causes skin irritation
- Swelling of tissues
- Repeated exposure may cause skin dryness or cracking
- Chronic exposure may cause dermatitis
- May cause an allergic skin reaction
Eye contact
- Risk of temporary eye lesions
- Symptoms: severe eye irritation, redness, lachrymation.
Ingestion
- Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
- Feelings of intoxication, restleness, dizziness and drowsiness.
If inhaled
- In case of accident by inhalation remove casualty to freash air and keep at rest
- Victim to lie down in the recovery position, cover and keep him warm.
- Oxygen or artificial respiration if needed.
- Immediate medical attention is required.
In case of eye contact
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- Immediate medical attention is required.
In case of skin contact
- Remove and wash contaminated clothing before to re-use.
- Wash off with soap and water.
- If symptoms persist call a physician
If swallowed
- If swallowed, rinse mouth with water ( only if the person is conscious).
- Do not induce vomiting
- Artificial respiration and/or oxygen may be necessary.
- Take victim immediately to hospital
Most important symptoms/effects, acute and delayed
Inhalation
- May cause respiratory irritation and drowsiness or dizziness.
- Inhalation of high vapour concentrations may cause symptoms like headache, dizziness, tiredness, nausea and vomiting.
- Risk of loss of consciousness
- Risk of lung oedema, chemical pneumonitis.
Skin contact
- Causes skin irritation
- Swelling of tissues
- Repeated exposure may cause skin dryness or cracking
- Chronic exposure may cause dermatitis
- May cause an allergic skin reaction
Eye contact
- Risk of temporary eye lesions
- Symptoms: severe eye irritation, redness, lachrymation.
Ingestion
- Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhoea.
- Feelings of intoxication, restleness, dizziness and drowsiness.
Fire-fighting measures
Suitable Extinguishing media
- Powder
- Carbon dioxide
Unsuitable extinguishing media
- Never use water
Specific hazards arising from the chemical
- Flammable liquids and vapours
- Explosion risk in case of fire
- Vapours may form explosive mixtures with air
- Hazardous decomposition products formed under fire conditions
Special protective actions for fire-fighters
- Wear self-contained breathing apparatus and protective suit
- Full protective flameproof clothing
- Wear chemical resistant oversuit
- Keep product and empty containers away from heat and sources of ignition
- Powder
- Carbon dioxide
Unsuitable extinguishing media
- Never use water
Specific hazards arising from the chemical
- Flammable liquids and vapours
- Explosion risk in case of fire
- Vapours may form explosive mixtures with air
- Hazardous decomposition products formed under fire conditions
Special protective actions for fire-fighters
- Wear self-contained breathing apparatus and protective suit
- Full protective flameproof clothing
- Wear chemical resistant oversuit
- Keep product and empty containers away from heat and sources of ignition
Accidental release measures
Personal precautions, protective equipments and emergency procedures
Advice for non-emergency personnel
- Prevent further leakage if safe to do so
- Keep away from incompatible products
Advice for emergency responders
- Evacuate personnel to safe areas
- Keep people away from and upwind of spill/leak.
- Remove all sources of ignition
- Wear self-contained breathing apparatus and protective suit.
- Cover the spreading liquid with foam in order to slow down the evaporation.
Environmental precautions
- Do not flush into surface water or sanitary sewer system
- If the product contaminates rivers and lakes or drains, inform respective authorities.
Methods and materials for containment and cleaning up
- Dam up
- Soak up with inert absorbent material
- Prevent product from entering drains
- Keep in properly labelled containers
- Keep in suitable, closed containers for disposal
Advice for non-emergency personnel
- Prevent further leakage if safe to do so
- Keep away from incompatible products
Advice for emergency responders
- Evacuate personnel to safe areas
- Keep people away from and upwind of spill/leak.
- Remove all sources of ignition
- Wear self-contained breathing apparatus and protective suit.
- Cover the spreading liquid with foam in order to slow down the evaporation.
Environmental precautions
- Do not flush into surface water or sanitary sewer system
- If the product contaminates rivers and lakes or drains, inform respective authorities.
Methods and materials for containment and cleaning up
- Dam up
- Soak up with inert absorbent material
- Prevent product from entering drains
- Keep in properly labelled containers
- Keep in suitable, closed containers for disposal
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4).
Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
Precautions for safe handling
- Use in closed system
- Use only in well ventilated areas
- Keep away from heat and sources of ignition
- Keep in a dry cool place
- Heating can release vapours which can be ignited.
- To avoid ignition of vapours by static electric discharge, all metal parts of the equipment must be grounded.
- When transferring from one container to another apply earthing measures and use conductive hose material
- Preferable transfer by pump or gravity
- Do not use sparking tools
- Keep away from incompatible products.
Conditions for storage including incompatibilities
- Store in original container
- Keep in a cool well-ventilated place
- Keep container closed
- Keep in a bunded area
- Keep away from incompatible products
- Keep away from heat/sparks/open flames/hot surfaces. No smoking
- Ensure all equipment is electrically grounded before beginning transfer operations.
- Take measures to prevent the build up of electrostatic charge
Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
Precautions for safe handling
- Use in closed system
- Use only in well ventilated areas
- Keep away from heat and sources of ignition
- Keep in a dry cool place
- Heating can release vapours which can be ignited.
- To avoid ignition of vapours by static electric discharge, all metal parts of the equipment must be grounded.
- When transferring from one container to another apply earthing measures and use conductive hose material
- Preferable transfer by pump or gravity
- Do not use sparking tools
- Keep away from incompatible products.
Conditions for storage including incompatibilities
- Store in original container
- Keep in a cool well-ventilated place
- Keep container closed
- Keep in a bunded area
- Keep away from incompatible products
- Keep away from heat/sparks/open flames/hot surfaces. No smoking
- Ensure all equipment is electrically grounded before beginning transfer operations.
- Take measures to prevent the build up of electrostatic charge
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- Transport code: UN-Nr. 3384
Shipping information
- Proper shipping name and description:
- TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S.(4-ETHOXY-TRIFLUORO-3-BUTENE-2-ONE)
- Chemical name:
- 4-ETHOXY-TRIFLUORO-3-BUTENE-2-ONE
- Language:
- English
- Labels:
- ADR/RID-labels 6.1 + 3
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3384
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3384
Shipping information
- Proper shipping name and description:
- TOXIC BY INHALATION LIQUID, FLAMMABLE, N.O.S.(4-ETHOXY-TRIFLUORO-3-BUTENE-2-ONE)
- Chemical name:
- 4-ETHOXY-TRIFLUORO-3-BUTENE-2-ONE
- Labels:
- IMDG-Labels: Toxic + Flammable Liquid
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- FORBIDDEN
Shipping information
- Proper shipping name and description:
- N.A.
- Chemical name:
- N.A.
- Labels:
- N.A.
Remarksopen allclose all
Additional transport information
Additional information
- Special provisions / remarks / other:
- For in-plant transport use the original packaging or other secure containers which are labelled according to the regulations.
Keep them tightly closed and secure them against falling by taking the appropriate measures.
Exposure controls / personal protection
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4).
Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
Control paramjeters
Exposure Limit Values
- SAEL (Solvay Acceptable Exposure Limit): Ceiling Limit Value: ppm (0.35 mg/m3)
- Remarks Skin sensitiser
Exposure controls
Appropriate engineering controls
- Provide appropriate exhaust ventilation at machinery.
- Apply technical measures to comply with the occupational exposure limit.
Individual protection measures
Respiratory protection
- In case of insufficient ventilation wear suitable respiratory equipment.
- When workers are facing concentrations above the exposure limit they must use appropriate certified respirators:
Self-contained breathing apparatus (EN 133);
Respirator with a vapour filter (EN 141). Recommended filter type A.
Hand protection
- Wear suitable gloves.
- Take note of the information given by the producer concernign permeability and break through times, and of special workplace conditions ( mechanical strain, duration of contact).
Eye protection
- Chemical resistant googles must be worn.
- If splashes are likely to occur, wear tightly fitting safety googles, face-shields.
Skin and body protection
- Flame-resistant clothing.
- If splashes are likely to occur, wear apron, boots, Neoprene.
Hygiene measures
- Eye wash bottles or eye wash stations in compliance with applicable standards.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.
Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site.
Written confirmation of application of Strictly Controlled Conditions has been received from every affected Distributor and Downstream Processor/User of the Registrant’s intermediate.
Control paramjeters
Exposure Limit Values
- SAEL (Solvay Acceptable Exposure Limit): Ceiling Limit Value: ppm (0.35 mg/m3)
- Remarks Skin sensitiser
Exposure controls
Appropriate engineering controls
- Provide appropriate exhaust ventilation at machinery.
- Apply technical measures to comply with the occupational exposure limit.
Individual protection measures
Respiratory protection
- In case of insufficient ventilation wear suitable respiratory equipment.
- When workers are facing concentrations above the exposure limit they must use appropriate certified respirators:
Self-contained breathing apparatus (EN 133);
Respirator with a vapour filter (EN 141). Recommended filter type A.
Hand protection
- Wear suitable gloves.
- Take note of the information given by the producer concernign permeability and break through times, and of special workplace conditions ( mechanical strain, duration of contact).
Eye protection
- Chemical resistant googles must be worn.
- If splashes are likely to occur, wear tightly fitting safety googles, face-shields.
Skin and body protection
- Flame-resistant clothing.
- If splashes are likely to occur, wear apron, boots, Neoprene.
Hygiene measures
- Eye wash bottles or eye wash stations in compliance with applicable standards.
- When using do not eat, drink or smoke.
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice.
Environmental exposure controls
- Dispose of rinse water in accordance with local and national regulations.
Stability and reactivity
Reactivity
- Reacts violently with water
- Risk of violent reaction
- Risk of explosion
Chemical stability
- Stable under recommended storage conditions
Conditions to avoid
- To avoid thermal decomposition, do not overheat
- Heat, flames and sparks
- Exposure to moisture
Materials to avoid
- Water, strong oxidising agents
Hazardous decomposition products
- Hydrogen fluoride, carbon oxide
- Reacts violently with water
- Risk of violent reaction
- Risk of explosion
Chemical stability
- Stable under recommended storage conditions
Conditions to avoid
- To avoid thermal decomposition, do not overheat
- Heat, flames and sparks
- Exposure to moisture
Materials to avoid
- Water, strong oxidising agents
Hazardous decomposition products
- Hydrogen fluoride, carbon oxide
Disposal considerations
Waste-disposal method
- in accordance with local and national regulations
- Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities
- The incinerator must be equipped with a system for the neutralisation or recovery of HF
Contaminated packaging
- Empty containers: dispose as unused product.
- in accordance with local and national regulations
- Must be incinerated in a suitable incineration plant holding a permit delivered by the competent authorities
- The incinerator must be equipped with a system for the neutralisation or recovery of HF
Contaminated packaging
- Empty containers: dispose as unused product.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
