ethyl 1-azabicyclo[2.2.2]oct-2-ene-3-carboxylate

Guidance on Safe Use

First-aid measures

General notes: Seek medical attention if feel unwell. Delayed effects can be expected after exposure.  

Following inhalation: If breathed in, move person into fresh air. Give water to drink. If not breathing, give artificial respiration.

Following skin contact: Wash off with plenty of water at least for 20 minutes. Contaminated clothing and footwear should be laundered before reuse.

Following eye contact: Flush eyes with water as a precaution at least for 20 minutes.

Following ingestion: Never give anything by mouth to an unconscious person. Rinse mouse with water. If ingestion of a large amount does occur, call the ambulance or provide medical attention immediately.

Self-protection of the firs aider: Attention! Making the "mouth to mouth" artificial respiration may be dangerous. Make a contactless artificial respiration.

May cause eye irritation and conjunctivitis. If swallowed, may cause irritation of the digestive tract, nausea, vomiting and dizziness. If inhaled, can cause upper respiratory irritation, lung damage, dizziness, headache, cough, nausea, unconsciousness. In contact with the skin may cause inflammation, irritation, dry skin and dermatitis. Symptoms: vomiting, rattling breath, dizziness, drowsiness, weakness, loss of coordination. The substance Expected to be harmful if swallowed, in contact with skin or if inhaled.

Fire-fighting measures

Suitable extinguishing media: Water spray, Carbon dioxide (CO2). Dry chemical. Chemical foam.

Special hazards arising from the substance or mixture: Thermal decomposition can lead to release of acrid smoke or irritating gases and vapours. Emits toxic fumes under fire conditions: carbon monoxide (CO), carbon dioxide (CO2), nitrogen oxides (NOx) and other pyrolysis products typical of burning organic material.

Fire fighter’s clothing conforming to European standard EN469 provides a basic level of protection for chemical incidents and includes helmets, protective boots and gloves. Clothing not conforming to EN469 may not be suitable in any chemical incident.

Accidental release measures

Use personal protective equipment: wear self – contained breathing apparatus, rubber boots and heavy rubber gloves.

For containment: Remove all ignition sources. Clean up all spills immediately. Avoid contact with skin and eyes. Control personal contact by using protective equipment. In case of major spills alert emergency responders and tell them location and nature of hazard. Prevent, by any means available, spillage from entering drains or watercourses.

Handling and storage

Measures to prevent fire: Avoid contact with incompatible materials, water and moisture. Keep away from sources of ignition.

Measures to prevent aerosol and dust generation: Use in a well-ventilated area. Prevent concentration in hollows and sumps. DO NOT enter confined spaces until atmosphere has been checked. Avoid all personal contact, including vapour inhalation.

Measures to protect the environment: Wear protective clothing when risk of exposure occurs. Keep jars securely sealed when not in use. Avoid physical damage to jars.

Advice on general occupational hygiene: Use good occupational work practice. Observe manufacturer's storing and handling recommendations. Always wash hands with soap and water after handling. Work clothes should be laundered separately. Launder contaminated clothing before re-use.

Technical measures and storage conditions: Store in original jars. Keep jars tightly closed when not in use. Check that all jars are clearly labelled. Protect jars against physical damage and check regularly for leaks.

Packing materials: Dark glass jar closed by polyethylene cover.

Requirements for storage rooms and vessels: Store at 0-15 °C.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

Not dangerous goods

Shipping

Labels:

Not dangerous goods

SpecialProvisions

Inland waterway transport (UN RTDG/ADN(R))

UN number:

Not dangerous goods

Shipping

Labels:

Not dangerous goods

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

Not dangerous goods

Shipping information

Proper shipping name and description:

3-carbethoxy-∆2-dehydro quinuclidine

Chemical name:

3-carbethoxy-∆2-dehydro quinuclidine

Labels:

Not dangerous goods

Remarks

Air transport (UN RTDG/ICAO/IATA)

UN number:

Not dangerous goods

Shipping information

Proper shipping name and description:

3-carbethoxy-∆2-dehydro quinuclidine

Chemical name:

3-carbethoxy-∆2-dehydro quinuclidine

Labels:

Not dangerous goods

Remarks

SpecialProvisions

Exposure controls / personal protection

Occupational exposure to the substance may occur through ingestion, vapour inhalation and dermal contact with this compound at workplaces where it is produced or used. Individual protection measures, such as personal protective equipment.

Appropriate engineering controls – Choose the working organization, technology and equipment in order to prevent or minimize any exposure.

Individual protection equipment:

Eye/face protection – For laboratory, larger scale or bulk handling or where regular exposure in an occupational setting occurs – chemical goggles.

Full-face shield may be required for supplementary but never for primary protection of eyes.

Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. DO NOT wear contact lenses.

Skin protection – Choose body protection according to the amount and concentration of the dangerous substance at the work place.

Hand protection: The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 and US F739. Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include such as frequency and duration of contact, chemical resistance of glove material, glove thickness and dexterity.

When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended.

When only brief contact is expected, a glove with a protection class of 3 or higher (breakthrough time greater than 60 minutes according to EN 374) is recommended. Contaminated gloves should be replaced.

Glove material – natural rubber, nitrile rubber, neoprene or PVC.

Other skin protection: Barrier cream, skin-cleansing cream, eye wash uni

Stability and reactivity

Reactivity – No dangerous reactions known.

Chemical stability – Stable under normal ambient and anticipated storage and handling conditions.

Conditions to avoid – Sources of ignition, moisture, light, heat.

Incompatible materials – Strong oxidizing and reducing agents, acid, bases.

Disposal considerations

Product / Packaging disposal:

Contact a licensed professional waste disposal service to dispose of this material. All waste must be handled in accordance with local, state and federal regulations. Legislation addressing waste disposal requirements may differ by country, state and/or territory. Each user must refer to laws operating in their area. Decontaminate empty glass jars.