Phenol, 2-methyl-, C9-rich C8-10-branched alkyl derivs.

Guidance on Safe Use

Handling and storage

Precautions for safe handling:

DO NOT handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. All equipment used when handling the product must be grounded. Use good personal hygiene practices Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get

his material in contact with eyes. Do not get this material in contact with skin. Do not get this material on clothing. Wear personal protective equipment. Do not use in areas without adequate ventilation. Avoid prolonged exposure. Wash thoroughly after handling. "Empty" containers retain product residue (liquid or vapour) and can be dangerous. Do not reuse empty containers. Organics can obtain an electrostatic charge during processing activities including: storage, mixing, filtering, or pumping which may represent a spark hazard and, therefore, a fire hazard. Also, a sudden release of such materials from storage or process equipment particularly at elevated temperatures, and/or pressures, can result in ignitions from static absent any apparent ignition source. Flashpoint and autoignition values obtained from standard test conditions may not be applicable to other situations and, thus,  the safe use of this material in any process should be reviewed by one familiar with both the storage, processing conditions and this material. Note: materials that are static accumulators may have such high potential differences created that such a situation may result in a discharge as sparks capable of causing ignition of organic vapors. Such discharges can occur from insulated conductors (plant items, drums), bulk liquids, mists and insulating plastic materials.

Conditions for safe storage, including any incompatibilities:

Use care in handling/storage. The pressure in sealed containers can increase under the influence of heat. Keep away from heat and sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Prevent electrostatic charge buildup by using common bonding and grounding techniques. Store in a wellventilated place. Keep container tightly closed.

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Shipping

Remarks

SpecialProvisions

Exposure controls / personal protection

Recommended monitoring procedures

Additional exposure data All PPE use is to be determined by a qualified person.

Switzerland SUVA Limit Values at the Workplace: Skin designation

ORTHOCRESOL (CAS 95487) Can be absorbed through the skin.

Control parameters

Occupational exposure limits

France:

Threshold Limit Values (VLEP) for Occupational Exposure to Chemicals in France, INRS ED 984

Components Type Value

ORTHOCRESOL (95487) VME 22 mg/m3, 5 ppm

Switzerland:

SUVA Limit Values at the Workplace

Components Type Value

ORTHOCRESOL (95487) STEL 22 mg/m3, 5 ppm

TWA 22 mg/m3, 5 ppm

United Kingdom:

No exposure limits noted for the ingredient(s).

EU. Indicative Exposure and Directives relating to the protection of risks related to work exposure to chemical, physical, and biological agents.

Components Type Value

ORTHOCRESOL (95487) TWA 22 mg/m3, 5 ppm

Derived No Effect Level (DNEL)

Not available.

Predicted no effect concentrations (PNECs)

Not available.

Recommended monitoring procedures

Not available.

Exposure controls

Appropriate engineering controls

Ensure adequate ventilation, especially in confined areas. Ventilation should be sufficient to effectively remove, and prevent buildup of, any vapors, dusts, or fumes that may be generated during handling or thermal processing. In order to ensure appropriate electrical safety practices are followed, consult applicable standards. These may include guidelines such as the National Fire Protection Association [NFPA] 70, "The National Electrical Code" and NFPA 499, "Recommended Practice for the Classification of Combustible Dusts and of Hazardous (Classified) Locations for Electrical Installations in Chemical Process Areas ". NOTE: since this material's vapors, dust or fumes can form explosive mixtures in air, ensure that any potential areas where explosions may occur are designed to minimize potential damage. For recommendations to prevent such explosions and associated damage, consult applicable guidelines such as NFPA 69, "Standard on Explosion Prevention Systems" and/or NFPA 68, "Guide for Venting Deflagrations".

Individual protection measures, such as personal protective equipment

General information

Avoid contact with eyes. Avoid contact with skin.

Eye/face protection

Avoid contact with eyes. Wear safety glasses with side shields (or goggles). If splashes are likely to occur, wear: Faceshield. Eye wash fountain is recommended.

Skin protection

Hand protection

Wear protective gloves.

Other

Do not get this material in contact with skin. Wear suitable protective clothing.

Respiratory protection

Do not breathe dust/fume/gas/mist/vapors/spray. If engineering controls do not maintain airborne concentrations below recommended exposure limits (where applicable) or to an acceptable level (in countries where exposure limits have not been established), an approved respirator must be

worn. Use a positivepressure airsupplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where airpurifying respirators may not provide adequate protection.

Thermal hazards

Not available

Hygiene measures

Do not get in eyes, on skin, on clothing. Wash hands after handling and before eating. Handle in accordance with good industrial hygiene and safety practices.

Environmental exposure controls

Not available.