N1,N3-diallylpropane-1,3-diamine dihydrochloride

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Link to relevant study record(s)

Reference

Endpoint:

relative self-ignition temperature (solids)

Type of information:

experimental study

Adequacy of study:

key study

Study period:

2018-05-02

Reliability:

2 (reliable with restrictions)

Rationale for reliability incl. deficiencies:

comparable to guideline study with acceptable restrictions

Qualifier:

no guideline followed

Principles of method if other than guideline:

Self-ignition properties of the test item were deduced from data of the Grewer oven test.

GLP compliance:

no

Key result

Remarks on result:

no self ignition observed under the test conditions

The temperature of the solid test item and the temperature of the reference substance (graphite) do not differ until approx. 220 °C. At this point a slightly endothermic was observed followed by an exothermic behavior of the test item at approx. 240 °C (maximum temperature difference of reference and test item Tmax = 19 °C). The exothermic event was finished at approx. 260 °C. Additional heating until 374 °C did not lead to a difference in the temperature profile of the test item and the reference substance.

No self-ignition test was performed with the test item. However, according to different references (ESCIS Heft 1. 4. Auflage 1998; Grewer T., Zur Selbstentzündung von abgelagertem Staub, Staub-Reinhaltung Luft 31(3), p. 97 - 101, 1971), self-ignition of a solid can be excluded, if in the course of the Grewer oven test there is no temperature excursion of the sample of more than 400 °C (in relation to the reference sample). Based on data from the Grewer oven test the maximum observed temperature of the test item was 374 °C (no difference to the reference sample), which is quite below 400 °C. Therefore, the test item does not have any self-ignition properties.

Conclusions:

The test item does not have any self-ignition properties.

Executive summary:

In the Grever oven test, the temperature of the solid test item and the temperature of the reference substance (graphite) do not differ until approx. 220 °C. At this point a slightly endothermic was observed followed by an exothermic behavior of the test item at approx. 240 °C (maximum temperature difference of reference and test item Tmax = 19 °C). The exothermic event was finished at approx. 260 °C. Additional heating until 374 °C did not lead to a difference in the temperature profile of the test item and the reference substance.

No self-ignition test was performed with the test item. However, according to different references, self-ignition of a solid can be excluded, if in the course of the Grewer oven test there is no temperature excursion of the sample of more than 400 °C (in relation to the reference sample). Based on data from the Grewer oven test the maximum observed temperature of the test item was 374 °C (no difference to the reference sample), which is quite below 400 °C. Therefore, the test item does not have any self-ignition properties.

Description of key information

Based on results from the Grewer oven test, the test item does not have any self-ignition properties.