Reaction mass of (((1,3-phenylenebis(oxy))bis(ethane-2,1-diyl))bis(oxy))bis(ethane-2,1-diyl) bis(2-methylacrylate) and (1,3-phenylenebis(oxy))bis(propane-3,1-diyl) bis(2-methylacrylate) and 3-(3-(2-(2-(methacryloyloxy)ethoxy)ethoxy)phenoxy)propyl methacrylaterate

Guidance on Safe Use

First-aid measures

Inhalation: Remove person to fresh air.  If you feel unwell, get medical attention.

Skin Contact:  Immediately flush with large amounts of water for at least 15 minutes.  Remove contaminated clothing.  Get immediate medical attention.  Wash clothing before reuse.

Eye Contact:  Immediately flush with large amounts of water for at least 15 minutes.  Remove contact lenses if easy to do.  Continue rinsing.  Immediately get medical attention.

If Swallowed: Rinse mouth.  Do not induce vomiting.  Get immediate medical attention.

Most important symptoms and effects, both acute and delayed:

No critical symptoms or effects. See Section 11.1, information on toxicological effects.

Indication of any immediate medical attention and special treatment required: Not applicable

Fire-fighting measures

Extinguishing media

In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

Special hazards arising from the substance or mixture: None inherent in this product.

Hazardous Decomposition or By-Products

Substance                        Condition

Hydrocarbons                 During Combustion

Carbon monoxide         During Combustion

Carbon dioxide                 During Combustion

Advice for fire-fighters: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.

Accidental release measures

Personal precautions, protective equipment and emergency procedures:

Evacuate area.  Ventilate the area with fresh air.  For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice.

Environmental precautions: Avoid release to the environment.

Methods and material for containment and cleaning up: Contain spill.  Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material.  Mix in sufficient absorbent until it appears dry.  Remember, adding an absorbent material does not remove a physical, health, or environmental hazard.  Collect as much of the spilled material as possible.  Place in a closed container approved for transportation by appropriate authorities.  Clean up residue with an appropriate solvent selected by a qualified and authorized person.  Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS.  Seal the container.  Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations.

Handling and storage

Precautions for safe handling:

Avoid breathing dust/fume/gas/mist/vapors/spray.  Do not get in eyes, on skin, or on clothing.  Do not eat, drink or smoke when using this product.  Wash thoroughly after handling.  Contaminated work clothing should not be allowed out of the workplace.  Avoid release to the environment.  Wash contaminated clothing before reuse.  Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.)

Conditions for safe storage including any incompatibilities:

Store away from acids.  Store away from strong bases.  Store away from oxidizing agents.

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Shipping

Remarks

SpecialProvisions

Exposure controls / personal protection

Control parameters:

Occupational exposure limits: No occupational exposure limit values exist for any of the components listed in Section 3 of the SDS.

Exposure controls

Engineering controls: Use in a well-ventilated area.

Personal protective equipment (PPE):

Eye/face protection: None required.

Skin/hand protection: Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing.  Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.

Gloves made from the following material(s) are recommended:

Material                                Thickness (mm)                       Breakthrough Time

Polymer laminate                No data available                No data available

Applicable norms/standards: Use gloves tested to EN 374

If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary.  Select and use body protection to prevent contact based on the results of an exposure assessment.  The following protective clothing material(s) are recommended: Apron - polymer laminate

Respiratory protection: An exposure assessment may be needed to decide if a respirator is required.  If a respirator is needed, use respirators as part of a full respiratory protection program.  Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:

Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates

For questions about suitability for a specific application, consult with your respirator manufacturer.

Applicable norms/standards

Use a respirator conforming to EN 140 or EN 136: filter types A & P

Stability and reactivity

Reactivity: This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.

Chemical stability: Stable.  

 

Possibility of hazardous reactions: Hazardous polymerization will not occur.  

Conditions to avoid

Light

Incompatible materials

Strong acids

Strong bases

Reducing agents

Strong oxidizing agents

Hazardous decomposition products

None known.       

Refer to section 5.2 of the SDS for hazardous decomposition products during combustion.

Disposal considerations

Waste treatment methods

Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. If no other disposal options are available, waste product that has been completely cured or polymerized may be placed in a landfill properly designed for industrial waste. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.