Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Auto flammability

Currently viewing:

Administrative data

Link to relevant study record(s)

Reference
Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
Testing was conducted between 9th November and 26th November 2015.
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
Deviations:
no
GLP compliance:
yes (incl. QA statement)
Specific details on test material used for the study:
Identification: 1,3-Propanediol, 2-ethyl-2-(hydroxymethyl)-, oligomeric reaction product with
(chloromethyl)oxirane
CAS RN: 30499-70-8
Appearance / Physical State: Clear colorless liquid
Batch: AAB1584600
Purity: 58% C15H26O6 + 25% C12H22O5
Expiry Date: 31 October 2015
Storage Conditions: Room temperature in the dark
Auto-ignition temperature:
304 °C
Atm. press.:
100.7 - 102.3 kPa
Remarks on result:
other: The test item has been determined to have an auto-ignition temperature of 304 ± 5 °C.

Results

Results of the auto-ignition temperature determination are shown in the following table:

 

Test Temperature (ºC)

Test Volume (µL)

Ignition Delay (s)

Observations

200 (fresh flask)

70

>300

No ignition.

250 (fresh flask)

70

>300

No Ignition. Grey fumes were emitted.

300 (fresh flask)

70

>300

No Ignition. Grey fumes were emitted.

350

70

4

An orange flame. Grey fumes were emitted.

330

70

5

An orange flame. Grey fumes were emitted.

320

70

2

An orange flame. Grey fumes were emitted.

310

70

>300

No Ignition. Grey fumes were emitted.

316 (fresh flask)

70

8

An orange flame. Grey fumes were emitted.

312 (fresh flask)

70

9

An orange flame. Grey fumes were emitted.

310 (fresh flask)

70

>300

No Ignition. Grey fumes were emitted.

310 (fresh flask)

200

16

An orange flame. Grey fumes were emitted.

308 (fresh flask)

200

26

An orange flame. Grey fumes were emitted.

306 (fresh flask)

200

>300

No Ignition. Grey fumes were emitted.

306 (fresh flask)

400

>300

No Ignition. Grey fumes were emitted.

306 (fresh flask)

600

18

An orange flame. Grey fumes were emitted.

304 (fresh flask)

600

>300

No Ignition. Grey fumes were emitted.

304 (fresh flask)

800

>300

No Ignition. Grey fumes were emitted.

304 (fresh flask)

1000

>300

No Ignition. Grey fumes were emitted.

304 (fresh flask)

1200

24

An orange flame. Grey fumes were emitted.

302 (fresh flask)

1200

>300

No Ignition. Grey fumes were emitted.

302 (fresh flask)

1400

>300

No Ignition. Grey fumes were emitted.

302 (fresh flask)

1600

>300

No Ignition. Grey fumes were emitted.

302 (fresh flask)

1800

>300

No Ignition. Grey fumes were emitted.

302 (fresh flask)

2000

>300

No Ignition. Grey fumes were emitted.

 

Room temperature: 20 to 21 °C
Atmospheric pressure: 100.7 to 102.3 kPa

Result: The test item has been determined to have an auto-ignition temperature of 304 ± 5 °C.

Conclusions:
The test item has been determined to have an auto-ignition temperature of 304 ± 5 °C.
Executive summary:

Auto-Ignition Temperature (Liquids and Gases): 304 ± 5 °C, using a procedure designed to be compatible with Method A15 Auto-Ignition Temperature (Liquids and Gases) of Commission Regulation (EC) No 440/2008 of 30 May 2008.

Description of key information

Auto-Ignition Temperature (Liquids and Gases). 304 ± 5 °C

Key value for chemical safety assessment

Autoflammability / Self-ignition temperature at 101 325 Pa:
304 °C

Additional information