Registration Dossier
Registration Dossier
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EC number: 701-324-1 | CAS number: -
Guidance on Safe Use
Administrative data
First-aid measures
SECTION 4: First aid measures
IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware
of the material(s) involved, and take precautions to protect themselves.
General information
4.1. Description of first aid measures
If exposed to excessive levels of dusts or fumes, remove to fresh air and get medical attention if
cough or other symptoms develop. If breathing is difficult, trained personnel should give oxygen.
Inhalation
Skin contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Immediately flush skin with plenty of water. Take off contaminated clothing and wash before reuse.
Eye contact
If swallowed, rinse mouth with water (only if the person is conscious). IF SWALLOWED:
Immediately call a POISON CENTRE or doctor/physician. Do not induce vomiting without advice
from poison control center.
Ingestion
4.2. Most important symptoms
and effects, both acute and
delayed
Dusts may irritate the respiratory tract, skin and eyes.
4.3. Indication of any
immediate medical attention
and special treatment needed
No specific antidotes are recommended. Treat according to locally accepted protocols. For
additional guidance, refer to the current prescribing information or to the local poison control
information centre.
Fire-fighting measures
SECTION 5: Firefighting measures
General fire hazards
5.1. Extinguishing media
This material will support combustion. May form explosible dust-air mixture if dispersed.
Suitable extinguishing
media: Water. Foam. Dry chemical powder.
Unsuitable extinguishing
media
Carbon dioxide (CO2).
5.2. Special hazards arising
from the substance or mixture
Explosion hazard: Avoid generating dust; fine dust dispersed in air in sufficient concentrations and
in the presence of an ignition source is a potential dust explosion hazard. Toxic, corrosive or
flammable thermal decomposition products, which might include chlorine compounds, are
expected when the material is exposed to fire.
5.3. Advice for firefighters
Special protective
equipment for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Special fire fighting
procedures: Move containers from fire area if you can do so without risk. Apply extinguishing media carefully to
avoid creating airborne dust.
Specific methods
Use standard firefighting procedures and consider the hazards of other involved materials.
Accidental release measures
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Use only
non-sparking tools. Dust deposits should not be allowed to accumulate on surfaces, as these may
form an explosive mixture if they are released into the atmosphere in sufficient concentration.
Wear appropriate protective equipment and clothing during clean-up. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
For non-emergency
personnel
For emergency responders
Keep unnecessary personnel away. Use personal protection recommended in Section 8 of the
SDS.
6.2. Environmental precautions
Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take
precautionary measures against static discharge. Use only non-sparking tools. Avoid dispersal of
dust in the air (i.e., clearing dust surfaces with compressed air). Collect dust using a vacuum
cleaner equipped with HEPA filter. Stop the flow of material, if this is without risk.
Avoid discharge into drains, water courses or onto the ground.
6.3. Methods and material for
containment and cleaning up
Large Spills: Wet down with water and dike for later disposal. Shovel the material into waste
container. Following product recovery, flush area with water.
Small Spills: Sweep up or vacuum up spillage and collect in suitable container for disposal.
Never return spills to original containers for re-use.
Handling and storage
SECTION 7: Handling and storage
7.1. Precautions for safe
handling
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid significant deposits of
material, especially on horizontal surfaces, which may become airborne and form combustible dust
clouds and may contribute to secondary explosions. Dry powders can build static electricity
charges when subjected to the friction of transfer and mixing operations. Provide adequate
precautions, such as electrical grounding and bonding, or inert atmospheres. Ground/bond
container and receiving equipment. Minimise the use of plastics when handling this material. Avoid
prolonged exposure. Wear appropriate personal protective equipment. Observe good industrial
hygiene practices.
7.2. Conditions for safe
storage, including any
incompatibilities
Keep away from heat, sparks and open flame. Keep containers tightly closed in a dry, cool and
well-ventilated place. Use care in handling/storage. Store away from incompatible materials (see
Section 10 of the SDS).
7.3. Specific end use(s)
Isolated Chemical Intermediate.
Transport information
Shippingopen allclose all
SpecialProvisionsopen allclose all
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Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
Shippingopen allclose all
Remarksopen allclose all
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SpecialProvisionsopen allclose all
Exposure controls / personal protection
Biological limit values
Not available.
No biological exposure limits noted for the ingredient(s).
Recommended monitoring
procedures
Derived no effect levels
(DNELs)
Not available.
Predicted no effect
concentrations (PNECs)
Not available.
8.2. Exposure controls
Ventilate as needed to control airborne dust. Use explosion-proof ventilation equipment if airborne
dust levels are high. Use process enclosures, local exhaust ventilation, or other engineering
controls to control airborne levels below recommended exposure limits.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Use personal protective equipment as required.
General information
Wear safety glasses with side shields (or goggles). (e.g. EN 166). Eye wash fountain is
recommended.
Eye/face protection
Skin protection
- Hand protection
Wear appropriate chemical resistant gloves. Select suitable chemical resistant protective gloves
(EN 374) with a protective index 6 (>480min permeation time). The choice of an appropriate glove
does not only depend on its material but also on other quality features and is different from one
producer to the other. Suitable gloves can be recommended by the glove supplier. Glove selection
must take into account any solvents and other hazards present.
- Other
When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators. Where breathable aerosols/dust are formed, use suitable combination filter for
gases/vapours of organic, inorganic, acid inorganic, alkaline compounds and toxic particles (eg.
EN 14387).
Wear appropriate chemical resistant clothing. (EN 14605 for splashes, EN ISO 13982 for dust).
Respiratory protection
Thermal hazards
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants. For advice on suitable monitoring methods, seek guidance
from a qualified environment, health and safety professional.
Wear appropriate thermal protective clothing, when necessary.
Hygiene measures
Environmental exposure controls
Hazard guidance and
control recommendations
Environmental manager must be informed of all major releases.
Stability and reactivity
SECTION 10: Stability and reactivity
10.1. Reactivity
Material is stable under normal conditions.
The product is stable and non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability
No dangerous reaction known under conditions of normal use.
10.3. Possibility of hazardous
reactions
Keep away from heat, sparks and open flame. Contact with incompatible materials. Minimise dust
generation and accumulation. Avoid dispersion as a dust cloud.
10.4. Conditions to avoid
10.5. Incompatible materials
Irritating and/or toxic fumes and gases may be emitted upon the product's decomposition.
Strong oxidising agents.
10.6. Hazardous
decomposition products
Disposal considerations
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Residual waste
Contaminated packaging
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal.
EU waste code
The Waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Disposal methods/information
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not
discharge into drains, water courses or onto the ground. Dispose in accordance with all applicable
regulations.
Special precautions
Dispose in accordance with all applicable regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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