Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

- Following inhalation:  Move to fresh air. Consult a physician after significant exposure. If unconscious, place in recovery position and seek medical advice. If breathing is irregularor stopped, administer artificial respiration. Keep respiratory tract clear.

- Following skin contact:  Wash immediately with plenty of soap and water. If on clothes, remove clothes. In the case of skin irritation or allergic reactions see a physician.

- Following eye contact: Immediately flush eye(s) with plenty of water. Remove contact lenses. Keep eye wide open while rinsing. Protect unharmed eye. If eye irritation persists, consult a specialist.

- Following ingestion: Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Take victim immediately to hospital.

Fire-fighting measures

- Suitable extinguishing media:  Water spray, Alcohol-resistant foam, Dry chemical

- Unsuitable extinguishing media:  no information available

- Special hazards arising from the substance or mixture:  Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard., Heating or fire can release toxic gas. Do not allow run-off from fire fighting to enter drains or water courses.

- Advice for fire fighter: In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Use water spray to cool unopened containers. Collect contaminated fire extinguishing water separately. This must not discharged into drains.

Accidental release measures

- Personal precautions/ Protective equipment and emergency procedures:  Use personal protective equipment. Avoid dust formation. In the case of respirable dust and/or fumes, use self-contained breathing apparatus and dust impervious protective suit.

- Environmental precautions: Prevent product from entering drains. Prevent further leakage or spillageif safe to do so.

- Methods and material for containment and cleaning up: Pick up and arrange disposal without creating dust.Shovel into suitable container for disposal.

Handling and storage

- Precautions for safe handling: Avoid dust formation of respirable particles. Do not breathe vapours / dust. Avoid exposure- obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations.

Avoid dust formation. Provide approriate exhaust ventilation at places where dust is formed. Take precautionary measures against static discharges.

- Conditions for safe storage, including any incompatibilities: Keep in a dry place. No decomposition if stored and applied as directed.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN1588
Shipping information
Proper shipping name and description:
CYANIDES, INORGANIC, SOLID, N.O.S.
Chemical name:
(Manganese-(II)-hexacyanomanganate (II) sodium salt hydrate)
Language:
English
Labels:
6.1
Hazard identification number: 60
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Marine transport (UN RTDG/IMDG)

UN number:
1588
Shipping information
Proper shipping name and description:
Cyanides, inorganic, solid, n.o.s.
Chemical name:
(Manganese-(II)-hexacyanomanganate (II) sodium salt hydrate)
Marine pollutant
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Air transport (UN RTDG/ICAO/IATA)

UN number:
UN1588
Shipping information
Proper shipping name and description:
Cyanides, inorganic, solid, n.o.s.
Chemical name:
(Manganese-(II)-hexacyanomanganate (II) sodium salt hydrate)
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Exposure controls / personal protection

1. Technical protection measures: It is recommended that all dust control equipment such as local exhaust ventilation and material transport systems involved in handling of this product contain explosion relief vents or an explosion suppression system or an oxygen deficient environment. Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment). Use only appropriately classified electrical equipment and powered industrial trucks.

2. Organisational protection measures: Avoid contact with skin, eyes, and clothing. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product.

3. Hand protection: Wear protective gloves. Break through time : > 480 min. Suitabkle material: Nitrile Rubber. Take note of the information given by the producer concerning permeability and break through times and special work place conditions (mechanical strain, duration of contact).

4. Feet protection: See below under Body protection

5. Body protection: Choose body protection according to the amount and concentration of the dangerous substance at the work place. Dust impervious protective suit.

6. Eye protection: Safety glasses with side shields confirming to EN 166.

7. Respiratory protection: In case of dust or aerosol formation use respirator with an approved filter. Half mask with a particle filter P2 (EN143).

Stability and reactivity

1. Reactivity: No decomposition if stored and applied as directed.

2. Chemical stability: Stable under recommended storage conditions.

3. Possibility of hazardous reactions: Stable under recommended storage conditions. thermal decomposition: 120 °C

4. Conditions to avoid : Heat

5. Incompatible materials: Strong acids and strong bases, Strong oxidizing agents

6. Hazardous decomposition products: Hydrogen cyanide (hydrocyanic acid)

Disposal considerations

Product : Dispose of contents/container in accordance with local regulation.

Contact waste disposal services.

Contaminated packaging : Empty containers should be taken to an approved waste handling site for recycling or disposal.