legislation-obligation

Substance Regulatory Obligations

OBL

Benzene-1,4-diamine dihydrochloride

EC number: 210-834-9

CAS number: 624-18-0

Last updated: 11/03/2020
ECHA Legislation Regulatory Obligations

Regulatory obligations may exist for this substance under the legislations under ECHA’s remit or for which ECHA has delegated tasks (i.e. REACH, CLP, BPR, PIC, CAD / CMD, WFD, and POPs). Please check the substance Infocard.

CAD - Chemical Agents Directive

EU. Worker Protection-Hazardous (98/24)

This list represents a calculated inventory of substances based on the list of harmonized substances contained in Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). Note that this list is not exhaustive. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP.

Name CAS
benzene-1,4-diamine dihydrochloride; p-phenylenediamine dihydrochloride
624-18-0
Cosmetic Products Regulation

EU. Cosmetics Regulation, Annex III, Restricted Substances

This list contains substances whose use in cosmetic products in the EU is banned except under certain conditions as indicated in the annex. The list specifies the field of application or use, maximum allowable concentration limits in finished products, and any additional limitations.

Ref No. Substance Identification Restrictions Warning Label Notes  
Name EC Number CAS Product type, body parts Function(s) Maximum Threshold Minimum Threshold Restriction(s) Qualifier(s) Expressed As
8a
p-Phenylenediamine HCl
210-834-9
624-18-0
General use hair dye substance in oxidative hair dye products
2 %
For general use
After mixing under oxidative conditions the maximum concentration applied to hair must not exceed 2 % calculated as free base
As free base
To be printed on the label: The mixing ratio. ''Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not intended for use on persons under the age of 16. Temporary ''black henna'' tattoos may increase your risk of allergy. Do not colour your hair if: you have a rash on your face or sensitive, irritated and damaged scalp, you have ever experienced any reaction after colouring your hair, you have experienced a reaction to a temporary ''black henna'' tattoo in the past. Contains phenylenediamines. Do not use to dye eyelashes or eyebrows.''
Details
8a
p-Phenylenediamine HCl
210-834-9
624-18-0
Professional use hair dye substance in oxidative hair dye products
2 %
For professional use only
After mixing under oxidative conditions the maximum concentration applied to hair must not exceed 2 % calculated as free base
As free base
To be printed on the label: The mixing ratio. ''For professional use only. Hair colourants can cause severe allergic reactions. Read and follow instructions. This product is not intended for use on persons under the age of 16. Temporary ''black henna'' tattoos may increase your risk of allergy. Do not colour your hair if: you have a rash on your face or sensitive, irritated and damaged scalp, you have ever experienced any reaction after colouring your hair, you have experienced a reaction to a temporary ''black henna'' tattoo in the past. Contains phenylenediamines. Wear suitable gloves.''
Details
8b
p-Phenylenediamine HCl
210-834-9
624-18-0
Professional use cosmetic products for coloring eyelashes
2 %
For professional use only
After mixing under oxidative conditions the maximum concentration applied to eyelashes must not exceed 2 % calculated as free base
As free base
To be printed on the label: The mixing ratio. ''For professional use only. This product can cause severe allergic reactions. Read and follow instructions. This product is not intended for use on persons under the age of 16. Temporary ''black henna'' tattoos may increase the risk of allergy. Eyelashes shall not be coloured if the consumer: has a rash on the face or sensitive, irritated and damaged scalp, has experienced any reaction after colouring hair or eyelashes, has experienced a reaction to a temporary ''black henna'' tattoo in the past. Rinse eyes immediately if product comes into contact with them. Contains phenylenediamines. Wear suitable gloves.''
Details
EU Ecolabel Regulation

EU. Dangerous Substances - Eco-Labels

This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). The EU Ecolabel may not be awarded to substances or mixtures classified as such. Note that this list is not exhaustive. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP.

Name CAS Restriction(s) Expressed As Table 3 of Annex VI to CLP EU REACH: List of SVHC Physical form Substance Description  
p-phenylenediamine dihydrochloride
benzene-1,4-diamine dihydrochloride
624-18-0
yes
Details
Protection of Young People Directive

EU. Young People at Work (94/33)

This list contains biological and chemical agents, in accordance with Art. 7 and points 2 and 3 of the Annex to Directive 94/33/EC, to which young persons (under 18 years of age) may not be exposed at the workplace. The database represents a non-exhaustive list of such substances based on: 1) agents of risk groups 3 and 4 under Directive 2000/54/EC; 2) Table 3 of Annex VI to the CLP Regulation; 3) and Annex I of Directive 2004/37/EC.

Name CAS EC_YOUNG ECCAR Directive 2004/37/EC EU CLP (1272/2008) EU_BA Directive 2000/54/EC Notes  
benzene-1,4-diamine dihydrochloride; p-phenylenediamine dihydrochloride
624-18-0
Acute Tox. 3; Skin Sens. 1
Details
Safety and/or Health Signs at Work Directive

EU. Workplace Signs

This directive requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced. The annexes to this directive provide detailed information about the minimum requirements for all safety and health signs. According to the annexes to the directive, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation (1272/2008/EC) must be marked and/or labeled.

Name EC Number CAS Index Sustance Description Danger Symbols Restriction Physical form  
benzene-1,4-diamine dihydrochloride; p-phenylenediamine dihydrochloride
210-834-9
624-18-0
612-029-00-1
Skull and crossbones
Details
WFD - Waste Framework Directive

EU. Hazardous Waste Properties: Annex III (2008/98/EC)

This database contains substances that have been assigned hazard property (HP) waste codes 1-15, as defined in terms of the hazard class & category, hazard (H) statement, and/or concentration limits provided in Annex III of the Waste Framework Directive (2008/98/EC). The classifications of the substances listed in the database are based on their harmonized classifications per Table 3 of Annex VI to the CLP Regulation (1272/2008/EC).

Name EC Number CAS EU CLP (1272/2008) HP Code Index
benzene-1,4-diamine dihydrochloride; p-phenylenediamine dihydrochloride
210-834-9
624-18-0
Acute Tox. 3
Skin Sens. 1
Aquatic Acute 1
Aquatic Chronic 1
HP6 Acute Toxicity: waste which can cause acute toxic effects following oral or dermal administration, or inhalation exposure.
HP13 Sensitising: waste which contains one or more substances known to cause sensitising effects to the skin or the respiratory organs.
HP14 Ecotoxic: waste which presents or may present immediate or delayed risks for one or more sectors of the environment.
612-029-00-1

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