legislation-obligation

Substance Regulatory Obligations

OBL

Trimagnesium diphosphide

EC number: 235-023-7

CAS number: 12057-74-8

Last updated: 11/10/2020
ECHA Legislation Regulatory Obligations

Regulatory obligations may exist for this substance under the legislations under ECHA’s remit or for which ECHA has delegated tasks (i.e. REACH, CLP, BPR, PIC, CAD / CMD, WFD, and POPs). Please check the substance Infocard.

CAD - Chemical Agents Directive

CAD - Chemical Agents Directive, Art. 2(b)(i) - Hazardous Agents

This list represents a calculated inventory of substances based on the list of harmonized substances contained in Table 3 of Annex VI to the CLP Regulation (1272/2008/EC). Note that this list is not exhaustive. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP.

Name CAS
magnesium phosphide; trimagnesium diphosphide
12057-74-8
EU Ecolabel Regulation

EU Ecolabels - Restrictions for Hazardous Substances/Mixtures

This database contains: (1) the list of hazardous substances harmonized for classification and labeling in EU (i.e. Table 3 of Annex VI to CLP Regulation); and (2) the Candidate List of substances of very high concern (SVHC). The EU Ecolabel may not be awarded to substances or mixtures classified as such. Note that this list is not exhaustive. While the harmonized list covers many hazardous substances, other ones not listed may also meet the classification criteria in accordance with the CLP.

Name CAS Restriction(s) Expressed As Table 3 of Annex VI to CLP EU REACH: List of SVHC Physical form Substance Description  
magnesium phosphide
trimagnesium diphosphide
12057-74-8
yes
Details
Inland Transport of Dangerous Goods Directive

Inland Transport of Dangerous Goods Directive, Annex I - ADR

This database contains the ADR's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID).

Name CAS Class Labels Packing Group Packaging UN No. ADR tank Classification code Hazard identification no. Limited and excepted quantities Vehicle for tank carriage Portable tank and bulk containers Special provisions Special provisions for carriage Transport category (Tunnel restriction code) Notes  
Mixed packing provisions Special packing provisions Packing instructions Tank code Special provisions Excepted quantities Limited quantities Unit Instructions Special provisions bulk Loading, unloading & handling Operation Packages Tunnel restriction code Transport category
MAGNESIUM PHOSPHIDE
12057-74-8
4.3
4.3+6.1
I
MP2
P403
2011
WT2
E0
CV23
CV28
S20
(E)
1
1 Not permitted to be carried in limited quantities
Details

Inland Transport of Dangerous Goods Directive, Annex II - RID

This database contains the RID's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID).

Name CAS Class Labels Packing Group UN No. Classification code Express parcels Hazard identification number RID Tanks Limited and excepted quantities Packaging Portable tanks and bulk containers Transport category Special provisions for carriage Special provisions Notes  
Tank code Special provisions Excepted quantities Units Limited quantities Special packaging provisions Packaging instructions Mixed packing provisions Special provisions Instructions Loading, unloading & handling bulk Packages
MAGNESIUM PHOSPHIDE
12057-74-8
4.3
4.3+6.1
I
2011
WT2
X462
E0
P403
MP2
1
CW23
CW28
W1
1 Not permitted to be carried in limited quantities
Details

Inland Transport of Dangerous Goods Directive, Annex III - AND

This database contains the ADN's Dangerous Goods List, as implemented by the EU's Directive 2008/68/EC. This Directive establishes rules for the safe transport of dangerous goods between EU countries by road, rail, and waterway. It applies the European Agreements on the international transport of dangerous goods by road (ADR) and inland waterways (ADN), and the Regulations concerning the international carriage of dangerous goods by rail (RID).

Name CAS Class Labels Packing Group UN No. or ID no. Carriage permitted Classification code Equipment required Limited and excepted quantities Number of blue cones/lights Provisions concerning loading, unloading and carriage Ventilation Remarks Special provisions Notes  
Excepted quantities Limited quantities Units Column (11c) Column (11b) Column (11a)
MAGNESIUM PHOSPHIDE
12057-74-8
4.3
4.3+6.1
I
2011
WT2
PP
EP
EX
TOX
A
E0
2
HA08
VE01
VE02
802
1 Not permitted to be carried in limited quantities
Details
Pesticide Residues Regulation

Annexes II, III, IV, VII - Defined & Temporary Maximum Residue Levels

This database contains the maximum residue level (MRLs) entries as listed in the following annexes of Regulation (EC) No 396/2005 on maximum residue levels of pesticides in or on food and feed of plant and animal origin and amending Council Directive 91/414/EEC: (1) Annex II: Maximum Residue Levels; (2) Annex III: Temporary MRLs; (3) Annex IV: Active Substances for Which No MRLs Are Required; and (4) Annex VII: Active Substance/Product Combinations.

Name CAS Annex No. Product Name Category CodeNumber Category Group/SubGroup CodeNumber Group/SubGroup MRL  
Magnesium phosphide
12057-74-8
Annex VII
Beans (with pods)
Beans (without pods)
Lentils
Other legume vegetables
Peas (with pods)
Peas (without pods)
0200000
Vegetables, fresh or frozen
0260000
Legume vegetables
Details
Magnesium phosphide
12057-74-8
Annex VII
Aubergines/eggplants
Courgettes
Cucumbers
cucurbits with edible peel
cucurbits with inedible peel
Gherkins (Bur gherkins)
Melons
Okra/lady's fingers
Other cucurbits with edible peel
Other cucurbits with inedible peel
other fruiting vegetables
Other solanaceae and malvaceae
Pumpkins
Solanaceae and Malvaceae
sweet corn (Baby corn)
Sweet peppers/bell peppers
Tomatoes
Watermelons
0200000
Vegetables, fresh or frozen
0230000
Fruiting vegetables
Details
Magnesium phosphide
12057-74-8
Annex VII
0200000
Vegetables, fresh or frozen
0290000
Algae and prokaryotes organisms
Details
Magnesium phosphide
12057-74-8
Annex VII
0600000
Teas, Coffee, Herbal Infusions, Cocoa and Carobs
0620000
Coffee beans
Details
Magnesium phosphide
12057-74-8
Annex VII
Cultivated fungi
Mosses and lichens
Wild fungi
0200000
Vegetables, fresh or frozen
0280000
Fungi, mosses and lichens
Details
Magnesium phosphide
12057-74-8
Annex VII
0600000
Teas, Coffee, Herbal Infusions, Cocoa and Carobs
0650000
Carobs/Saint John's breads
Details
Magnesium phosphide
12057-74-8
Annex VII
Cinnamon
Other bark spices
0800000
Spices
0830000
Bark spices
Details
Magnesium phosphide
12057-74-8
Annex VII
American persimmons/Virginia kaki
Avocados
Bananas
Breadfruits
Carambolas
Cherimoyas
Dates
Durians
edible peel
Figs
Granate apples/pomegranates
Guavas
inedible peel, large
inedible peel, small
Jambuls/jambolans
Kaki/Japanese persimmons
Kiwi fruits (green, red, yellow)
Kumquats
Litchis/lychees
Mangoes
Other edible peel
Other inedible peel, large
Other inedible peel, small
Papayas
Passionfruits/maracujas
Pineapples
Prickly pears/cactus fruits
Soursops/guanabanas
Star apples/cainitos
Table olives
0100000
Fruits, fresh or frozen and Tree nuts
0160000
Miscellaneous fruits
Details
Magnesium phosphide
12057-74-8
Annex VII
Allspice/pimento
Caraway (Ajowan)
Cardamom (Marjoram, Star anise)
Juniper berry
Other fruit spices
Peppercorn
Sichuan pepper
Tamarind
Vanilla
0800000
Spices
0820000
Fruit spices
Details
Magnesium phosphide
12057-74-8
Annex VII
Capers
Cloves
Other bud spices
0800000
Spices
0850000
Bud spices
Details
Magnesium phosphide
12057-74-8
Annex VII
Apricots
Cherries (sweet)
Other stone fruits
Peaches
Plums
0100000
Fruits, fresh or frozen and Tree nuts
0140000
Stone fruits
Details
Magnesium phosphide
12057-74-8
Annex VII
Grapefruits
Lemons
Limes
Mandarins
Oranges
Other citrus fruits
0100000
Fruits, fresh or frozen and Tree nuts
0110000
Citrus fruits
Details
Magnesium phosphide
12057-74-8
Annex VII
Arrowroots
Beetroots
Carrots
Cassava roots/manioc
Celeriacs/turnip rooted celeries
Horseradishes
Jerusalem artichokes
other root and tuber vegetables except sugar beets
Other tropical root and tuber vegetables
Parsley roots/Hamburg roots parsley
Parsnips
potatoes (Andigena)
Radishes
Salsifies
Swedes/rutabagas
Sweet potatoes
tropical root and tuber vegetables
Turnips )
Yams
0200000
Vegetables, fresh or frozen
0210000
Root and tuber vegetables
Details
Magnesium phosphide
12057-74-8
Annex VII
Chamomile
flowers
Ginseng (Siberian ginseng)
Herbal infusions from parts of the plant not explicitly defined
Hibiscus/roselle
Jasmine
leaves and herbs
Lime/linden
Mate/maté
Other Herbal infusions from flowers
Other Herbal infusions from leaves and herbs
Other Herbal infusions from roots
Rooibos
roots
Rose
Strawberry
Valerian
0600000
Teas, Coffee, Herbal Infusions, Cocoa and Carobs
0630000
Herbal infusions from
Details
Magnesium phosphide
12057-74-8
Annex VII
Anise/aniseed
Black caraway/black cumin (Nigella)
Celery (Angelica, Lovage)
Coriander
Cumin
Dill
Fennel
Fenugreek
Nutmeg
Other seed spices
0800000
Spices
0810000
Seed spices
Details
Magnesium phosphide
12057-74-8
Annex VII
Apples
Loquats/Japanese medlars
Medlars
Other pome fruits
Pears
Quinces
0100000
Fruits, fresh or frozen and Tree nuts
0130000
Pome fruits
Details
Magnesium phosphide
12057-74-8
Annex VII
Other flower pistil spices
Saffron
0800000
Spices
0860000
Flower pistil spices
Details
Magnesium phosphide
12057-74-8
Annex VII
0600000
Teas, Coffee, Herbal Infusions, Cocoa and Carobs
0640000
Cocoa beans
Details
Magnesium phosphide
12057-74-8
Annex VII
Almonds
Brazil nuts
Cashew nuts
Chestnuts
Coconuts
Hazelnuts/cobnuts
Macadamias
Other tree nuts
Pecans
Pine nut kernels
Pistachios
Walnuts
0100000
Fruits, fresh or frozen and Tree nuts
0120000
Tree nuts
Details
Magnesium phosphide
12057-74-8
Annex VII
Baby leaf crops (including brassica species)
Basil and edible flowers
Celery leaves
Chards/beet leaves
Chervil
Chives
Cresses and other sprouts and shoots
Escaroles/broad-leaved endives
grape leaves and similar species
herbs and edible flowers
Lamb's lettuces/corn salads
Land cresses
Laurel/bay leaves
Lettuces
lettuces and salad plants
Other herbs and edible flowers
Other lettuces and salad plants
Other spinaches and similar leaves
Parsley (Root parsley leaves)
Purslanes
Red mustards
Roman rocket/rucola (Wall rocket)
Rosemary
Sage
Spinaches
spinaches and similar leaves
Tarragon
Thyme
watercresses
witloofs/Belgian endives
0200000
Vegetables, fresh or frozen
0250000
Leaf vegetables, herbs and edible flowers
Details
Magnesium phosphide
12057-74-8
Annex VII
Garlic (Twistedleaf garlic)
Onions
Other bulb vegetables
Shallots
Spring onions/green onions and Welsh onions
0200000
Vegetables, fresh or frozen
0220000
Bulb vegetables
Details
Magnesium phosphide
12057-74-8
Annex VII
Mace
Other aril spices
0800000
Spices
0870000
Aril spices
Details
Magnesium phosphide
12057-74-8
Annex VII
Ginger
Horseradish
Liquorice
Other root and rhizome spices
Turmeric/curcuma
0800000
Spices
0840000
Root and rhizome spices
Details
Magnesium phosphide
12057-74-8
Annex VII
Broccoli
Brussels sprouts
Cauliflowers
Chinese cabbages/pe-tsai
flowering brassica
head brassica
Head cabbages
Kales
kohlrabies
leafy brassica
Other flowering brassica
Other head brassica
Other leafy brassica
0200000
Vegetables, fresh or frozen
0240000
Brassica vegetables (excluding brassica roots and brassica baby leaf crops)
Details
Magnesium phosphide
12057-74-8
Annex VII
0600000
Teas, Coffee, Herbal Infusions, Cocoa and Carobs
0610000
Teas
Details
Magnesium phosphide
12057-74-8
Annex VII
Asparagus (Hop sprouts)
Bamboo shoots
Cardoons (Borage stems)
Celeries
Florence fennels
Globe artichokes
Leeks
Other stem vegetables
Palm hearts
Rhubarbs
0200000
Vegetables, fresh or frozen
0270000
Stem vegetables
Details
Magnesium phosphide
12057-74-8
Annex VII
Azaroles/Mediterranean medlars
Blackberries
Blueberries
cane fruits
Cranberries
Currants (black, red and white)
Dewberries
Elderberries
Gooseberries (green, red and yellow)
grapes
Mulberries (black and white)
Other cane fruits
other small fruits and berries
Raspberries (red and yellow)
Rose hips
strawberries
Table grapes
Wine grapes
0100000
Fruits, fresh or frozen and Tree nuts
0150000
Berries and small fruits
Details
PPP - Plant Protection Products Regulation

EU. Annex of Approved Active Substances for Plant Protection Products

This list contains the annex of active substances contained in Regulation 540/2011/EU, separated into Part A (deemed to have been approved under Regulation 1107/2009/EC), Part B (approved under Regulation 1107/2009/EC), and Part C (basic substances approved under Regulation 1107/2009/EC). Entries include common name, IUPAC name, identification numbers (e.g., CAS, CIPAC), purity information, and dates of approval and approval expiration, as well as specific provisions.

Name CAS Ref No. CIPAC No. Purity Qualifier Expressed As Date of approval Expiration of approval Part Use Notes  
Magnesium phosphide
12057-74-8
262
228
880.0 g/kg
1 September 2009
31 August 2022
A Active substances deemed to have been approved under Regulation (EC) No 1107/2009
Only uses as insecticide, rodenticide, talpicide and leporicide in the form of ready-to-use magnesium phosphide containing products may be authorised; As rodenticide, talpicide and leporicide only outdoor uses may be authorised; Authorisations should be limited to professional users
1 Please refer the original source document for applicable additional specific provisions (https://eur-lex.europa.eu/legal-content/EN/TXT/?uri=CELEX:32011R0540).
Details
Protection of Young People Directive

Physical, Biological and Chemical Agents & Processes and Work

This list contains biological and chemical agents, in accordance with Art. 7 and points 2 and 3 of the Annex to Directive 94/33/EC, to which young persons (under 18 years of age) may not be exposed at the workplace. The database represents a non-exhaustive list of such substances based on: 1) agents of risk groups 3 and 4 under Directive 2000/54/EC; 2) Table 3 of Annex VI to the CLP Regulation; 3) and Annex I of Directive 2004/37/EC.

Name CAS EC_YOUNG ECCAR Directive 2004/37/EC EU CLP (1272/2008) EU_BA Directive 2000/54/EC Notes  
magnesium phosphide; trimagnesium diphosphide
12057-74-8
Acute Tox. 2; Acute Tox. 3; Acute Tox. 1
Details
Safety and/or Health Signs at Work Directive

Workplace Signs - minimum requirements & signs on containers and pipes

This directive requires employers to ensure proper signage is posted in areas where hazards cannot be avoided or reduced. The annexes to this directive provide detailed information about the minimum requirements for all safety and health signs. According to the annexes to the directive, storage areas and containers containing chemical substances or mixtures that are classified as hazardous according to the CLP Regulation (1272/2008/EC) must be marked and/or labeled.

Name EC Number CAS Index Sustance Description Danger Symbols Restriction Physical form  
magnesium phosphide; trimagnesium diphosphide
235-023-7
12057-74-8
015-005-00-3
Flame
Skull and crossbones
Details
WFD - Waste Framework Directive

Waste Framework Directive, Annex III - Waste - Hazardous Properties

This database contains substances that have been assigned hazard property (HP) waste codes 1-15, as defined in terms of the hazard class & category, hazard (H) statement, and/or concentration limits provided in Annex III of the Waste Framework Directive (2008/98/EC). The classifications of the substances listed in the database are based on their harmonized classifications per Table 3 of Annex VI to the CLP Regulation (1272/2008/EC).

Name EC Number CAS EU CLP (1272/2008) HP Code Index
magnesium phosphide; trimagnesium diphosphide
235-023-7
12057-74-8
Water-react. 1
Acute Tox. 2
Acute Tox. 3
Acute Tox. 1
Aquatic Acute 1
EUH029
EUH032
HP3 Flammable Waste (FW): (a)liq FW with flash pt <60°C or FW gas, diesel and light heating oils with flash pt >55°C and ≤75°C (b)pyrophoric liq/solid FW liable to ignite within 5 min after air contact (c)solid FW readily combustible or which may cause/contribute to fire by friction (d)gas FW which is F in air at 20°C and 101.3 kPa (e)water reactive FW which, in contact with water, emits F gases in dangerous quantities (f)other: aerosols, self-heating, organic peroxides and self-reactive FWs.
HP6 Acute Toxicity: waste which can cause acute toxic effects following oral or dermal administration, or inhalation exposure.
HP14 Ecotoxic: waste which presents or may present immediate or delayed risks for one or more sectors of the environment.
HP12 Release of an acute toxic gas: waste which releases acute toxic gases (Acute Tox. 1, 2 or 3) in contact with water or an acid.
015-005-00-3

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