pregnant-women-protection

Protection of Pregnant and Breastfeeding Workers Directive, Annex I+II

EU. Chemical Agents: Annexes I & II, Directive 92/85/EEC on Pregnant Workers, 28 November 1992 (updated by table 3 of Annex VI to CLP, 5 October 2018)

This list contains a non-exhaustive inventory of substances to which pregnant workers and workers who have recently given birth or are breastfeeding may not be exposed. Employers are obligated to prevent the exposure of these workers to any agents that may have adverse health effects on either mother or child. The inventory originates from Table 3 of Annex VI to the CLP.

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Substance Name
EC No.
CAS No.
CLP (1272/2008) CMRs
ECCAR Directive 2004/37/EC
 
antimony trioxide
215-175-0
1309-64-4
Carc. 2
Details
amisulbrom (ISO); 3-(3-bromo-6-fluoro-2-methylindol-1-ylsulfonyl)-N,N-dimethyl-1H-1,2,4-triazole-1-sulfonamide
672-776-4
348635-87-0
Carc. 2
Details
alkanes, C10-13, chloro; chlorinated paraffins, C10-13
287-476-5
85535-84-8
Carc. 2
Details
aldrin (ISO)
206-215-8
309-00-2
Carc. 2
Details
alachlor (ISO); 2-chloro-2',6'-diethyl-N-(methoxymethyl)acetanilide
240-110-8
15972-60-8
Carc. 2
Details
aclonifen (ISO); 2-chloro-6-nitro-3-phenoxyaniline
277-704-1
74070-46-5
Carc. 2
Details
acetamide
200-473-5
60-35-5
Carc. 2
Details
6,6'-bis(diazo-5,5', 6,6'-tetrahydro-5,5'-dioxo)[methylene-bis(5-(6-diazo-5,6-dihydro-5-oxo-1-naphthylsulphonyloxy)-6-methyl-2-phenylene]di(naphthalene-1-sulfonate)
441-550-5
-
Carc. 2
Details
5-nitro-o-toluidine hydrochloride
256-960-8
51085-52-0
Carc. 2
Details
5-nitro-o-toluidine
202-765-8
99-55-8
Carc. 2
Details
5-fluoro-1,3-dimethyl-N-[2-(4-methylpentan-2-yl)phenyl]-1H-pyrazole-4-carboxamide; 2'-[(RS)-1,3-dimethylbutyl]-5-fluoro-1,3-dimethylpyrazole-4-carboxanilide; penflufen
619-823-7
494793-67-8
Carc. 2
Details
4-vinylcyclohexene
202-848-9
100-40-3
Carc. 2
Details
4-methylpentan-2-one; isobutyl methyl ketone
203-550-1
108-10-1
Carc. 2
Details
4-methyl-m-phenylene diisocyanate; toluene-2,6-di-isocyanate
209-544-5
584-84-9
Carc. 2
Details
4-[4-(1,3-dihydroxyprop-2-yl)phenylamino]-1,8-dihydroxy-5-nitroanthraquinone
ANTHRACHINON BLAU 27 HD
406-057-1
114565-66-1
Carc. 2
Details
4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate
202-966-0
101-68-8
Carc. 2
Details
4,4'-methylenebis(2-ethylaniline); 4,4'-methylenebis(2-ethylbenzeneamine)
243-420-1
19900-65-3
Carc. 2
Details
4,4'-carbonimidoylbis[N, N-dimethylaniline]
207-762-5
492-80-8
Carc. 2
Details
4,4'-bis(N-carbamoyl-4-methylbenzenesulfonamide)diphenylmethane
B-TUM
418-770-5
151882-81-4
Carc. 2
Details
3-(4-chlorophenyl)-1,1-dimethyluronium trichloroacetate; monuron-TCA
620-358-7
140-41-0
Carc. 2
Details
3,5,5-trimethylcyclohex-2-enone; isophorone
201-126-0
78-59-1
Carc. 2
Details
3,3'-dimethylbiphenyl-4,4'-diyl diisocyanate
202-112-7
91-97-4
Carc. 2
Details
2-methyl-m-phenylene diisocyanate; toluene-2,4-di-isocyanate
202-039-0
91-08-7
Carc. 2
Details
2-furaldehyde
202-627-7
98-01-1
Carc. 2
Details
2-ethylphenylhydrazine hydrochloride
2-EPH
421-460-2
19398-06-2
Carc. 2
Details
2-ethyl-2-[[(1-oxoallyl)oxy]methyl]-1,3-propanediyl diacrylate; 2,2-bis(acryloyloxymethyl)butyl acrylate; trimethylolpropane triacrylate
239-701-3
15625-89-5
Carc. 2
Details
2,6-xylidine; 2,6-dimethylaniline
201-758-7
87-62-7
Carc. 2
Details
2,4,6-trichlorophenol
201-795-9
88-06-2
Carc. 2
Details
2,3,4-trichlorobut-1-ene
219-397-9
2431-50-7
Carc. 2
Details
2,2-dibromo-2-nitroethanol
PERMACHEM N21
412-380-9
69094-18-4
Carc. 2
Details
2,2'-methylenediphenyl diisocyanate; diphenylmethane-2,2'-diisocyanate
219-799-4
2536-05-2
Carc. 2
Details
2,2'-((3,3', 5,5'-tetramethyl-(1,1'-biphenyl)-4,4'-diyl)-bis(oxymethylene))-bis-oxirane
EPIKOTE YX4000; EPIKOTE YX4000H; YX-4000
413-900-7
85954-11-6
Carc. 2
Details
1-vinyl-2-pyrrolidone
201-800-4
88-12-0
Carc. 2
Details
1-bromo-3,4,5-trifluorobenzene
1-BROM-3,4,5-TRIFLUORBENZOL; 1-BROMO-3,4,5-TRIFLUOROBENZENE
418-480-9
138526-69-9
Carc. 2
Details
1-bromo-2-methylpropyl propionate
422-900-6
158894-67-8
Carc. 2
Details
1,5-naphthylenediamine
218-817-8
2243-62-1
Carc. 2
Details
1,4-dichlorobenzene; p-dichlorobenzene
203-400-5
106-46-7
Carc. 2
Details
1,3,5-triazine-2,4,6-triamine; melamine
203-615-4
108-78-1
Carc. 2
Details
1,2-epoxybutane
203-438-2
106-88-7
Carc. 2
Details
1,2,3,4,5,6-hexachlorcyclohexanes with the exception of those specified elsewhere in this Annex
210-168-9
608-73-1
Carc. 2
Details
1,1-dichloroethylene; vinylidene chloride
200-864-0
75-35-4
Carc. 2
Details
1,1,2-trichloroethane
201-166-9
79-00-5
Carc. 2
Details
(Z)-2-methoxymino-2-[2-(tritylamino)thiazol-4-yl]acetic acid
431-520-1
64485-90-1
Carc. 2
Details
(5-chloro-2-methoxy-4-methyl-3-pyridyl) (4,5,6-trimethoxy-o-tolyl)methanone; pyriofenone
692-456-8
688046-61-9
Carc. 2
Details
(4-phenylbutyl)phosphinic acid
420-450-5
86552-32-1
Carc. 2
Details
(3-chloro-2-hydroxypropyl); trimethylammonium chloride ... %
222-048-3
3327-22-8
Carc. 2
Details
butanone oxime; ethyl methyl ketoxime; ethyl methyl ketone oxime
202-496-6
96-29-7
Carc. 1B; STOT SE 1
yes
 Details
α, α, α,4-tetrachlorotoluene; p-chlorobenzotrichloride
226-009-1
5216-25-1
Carc. 1B; Repr. 2
yes
 Details
tetrasodium 3,3'-[[1,1'-biphenyl]-4,4'diylbis(azo)]bis[5-amino-4-hydroxynaphthalene-2,7-disulphonate]; C.I. Direct Blue 6
220-012-1
2602-46-2
Carc. 1B; Repr. 2
yes
 Details
spirodiclofen (ISO); 3-(2,4-dichlorophenyl)-2-oxo-1-oxaspiro[4.5]dec-3-en-4-yl 2,2-dimethylbutyrate
604-636-5
148477-71-8
Carc. 1B; Repr. 2
yes
 Details
indium phosphide
244-959-5
22398-80-7
Carc. 1B; Repr. 2
yes
 Details
disodium 4-amino-3-[[4'-[(2,4-diaminophenyl)azo][1,1'-biphenyl]-4-yl]azo]-5-hydroxy-6-(phenylazo)naphtalene-2,7-disulphonate; C.I. Direct Black 38
217-710-3
1937-37-7
Carc. 1B; Repr. 2
yes
 Details
disodium 3,3'-[[1,1'-biphenyl]-4,4'-diylbis(azo)]bis(4-aminonaphthalene-1-sulphonate); C.I. Direct Red 28
209-358-4
573-58-0
Carc. 1B; Repr. 2
yes
 Details
2,3-dibromopropan-1-ol; 2,3-dibromo-1-propanol
202-480-9
96-13-9
Carc. 1B; Repr. 2
yes
 Details
reaction mass of: 1,3,5-tris(3-aminomethylphenyl)-1,3,5-(1H,3H,5H)-triazine-2,4,6 trione; reaction mass of oligomers of; 3,5-bis(3-aminomethylphenyl)1-poly[3,5-bis(3-aminomethylphenyl)-2,4,6-trioxo-1,3,5-(1H,3H,5H)-triazin-1-yl]-1,3,5(1H,3H,5H)-triazine-2,4,6-trione
BLENDUR I VP KU 3-4519
421-550-1
-
Carc. 1B; Repr. 1B
yes
 Details
nitrofen (ISO); 2,4-dichlorophenyl 4-nitrophenyl ether
217-406-0
1836-75-5
Carc. 1B; Repr. 1B
yes
 Details
methyl-ONN-azoxymethyl acetate; methyl azoxy methyl acetate
209-765-7
592-62-1
Carc. 1B; Repr. 1B
yes
 Details
4-methylimidazole
212-497-3
822-36-6
Carc. 1B; Repr. 1B
yes
 Details
1,2,3-trichloropropane
202-486-1
96-18-4
Carc. 1B; Repr. 1B
yes
 Details
lead sulfochromate yellow; C.I. Pigment Yellow 34 [This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 77603.]
This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 77603.
215-693-7
1344-37-2
Carc. 1B; Repr. 1A
yes
 Details
lead chromate molybdate sulfate red; C.I. Pigment Red 104 [This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 77605.]
This substance is identified in the Colour Index by Colour Index Constitution Number, C.I. 77605.
235-759-9
12656-85-8
Carc. 1B; Repr. 1A
yes
 Details
lead chromate
231-846-0
7758-97-6
Carc. 1B; Repr. 1A
yes
 Details
4,4'-diaminodiphenylmethane; 4,4'-methylenedianiline
202-974-4
101-77-9
Carc. 1B; Muta. 2; STOT SE 1
yes
 Details
phenolphthalein
201-004-7
77-09-8
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
methyl-phenylene diamine
246-910-3
25376-45-8
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
dinitrotoluene
246-836-1
25321-14-6
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
diaminotoluene [technical product — reaction mass of 4-methyl-m-phenylene diamine (EC No 202-453-1) and 2-methyl-m-phenylene diamine (EC No 212-513-9)]
-
-
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
cadmium sulphide
215-147-8
1306-23-6
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
cadmium oxide (non-pyrophoric)
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Monteponite (CdO) EC / List no: - | CAS no: 12139-21-8
215-146-2
1306-19-0
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
cadmium (non-pyrophoric);cadmium (pyrophoric)
231-152-8
7440-43-9
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
cadmium (non-pyrophoric);cadmium (pyrophoric)
231-152-8
7440-43-9
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
4-methyl-m-phenylenediamine; 2,4-toluenediamine
202-453-1
95-80-7
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
3,5-dinitrotoluene
210-566-2
618-85-9
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
3,4-dinitrotoluene
210-222-1
610-39-9
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
2,6-dinitrotoluene
210-106-0
606-20-2
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
2,5-dinitrotoluene
210-581-4
619-15-8
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
2,4-dinitrotoluene
204-450-0
121-14-2
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
2,3-epoxypropyltrimethylammonium chloride ... %; glycidyl trimethylammonium chloride ... %
221-221-0
3033-77-0
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
2,3-dinitrotoluene
210-013-5
602-01-7
Carc. 1B; Muta. 2; Repr. 2
yes
 Details
R—2,3-epoxy-1-propanol
R-GLYCIDOL
404-660-4
57044-25-4
Carc. 1B; Muta. 2; Repr. 1B
yes
 Details
cobalt sulfate
233-334-2
10124-43-3
Carc. 1B; Muta. 2; Repr. 1B
yes
 Details
cobalt dinitrate
233-402-1
10141-05-6
Carc. 1B; Muta. 2; Repr. 1B
yes
 Details
cobalt dichloride
231-589-4
7646-79-9
Carc. 1B; Muta. 2; Repr. 1B
yes
 Details
cobalt di(acetate)
200-755-8
71-48-7
Carc. 1B; Muta. 2; Repr. 1B
yes
 Details
cobalt carbonate
208-169-4
513-79-1
Carc. 1B; Muta. 2; Repr. 1B
yes
 Details
cobalt
231-158-0
7440-48-4
Carc. 1B; Muta. 2; Repr. 1B
yes
 Details
7-oxa-3-oxiranylbicyclo [4.1.0]heptane; 1,2-epoxy- 4-epoxyethylcyclohexane; 4-vinylcyclohexene diepoxide
203-437-7
106-87-6
Carc. 1B; Muta. 2; Repr. 1B
yes
 Details
2,3-epoxypropyl methacrylate; glycidyl methacrylate
203-441-9
106-91-2
Carc. 1B; Muta. 2; Repr. 1B
yes
 Details
2,3-epoxypropan-1-ol; glycidol; oxiranemethanol
209-128-3
556-52-5
Carc. 1B; Muta. 2; Repr. 1B
yes
 Details
trichloroethylene; trichloroethene
201-167-4
79-01-6
Carc. 1B; Muta. 2
yes
 Details
sodium N-(hydroxymethyl)glycinate; [formaldehyde released from sodium N-(hydroxymethyl)glycinate]
274-357-8
70161-44-3
Carc. 1B; Muta. 2
yes
 Details
safrole; 5-allyl-1,3-benzodioxole
202-345-4
94-59-7
Carc. 1B; Muta. 2
yes
 Details
reaction products of paraformaldehyde with 2-hydroxypropylamine (ratio 1:1); [formaldehyde released from α,α,α-trimethyl-1,3,5-triazine-1,3,5(2H,4H,6H)-triethanol]; [HPT]
-
-
Carc. 1B; Muta. 2
yes
 Details
reaction products of paraformaldehyde and 2-hydroxypropylamine (ratio 3:2); [formaldehyde released from 3,3'-methylenebis [5-methyloxazolidine]; formaldehyde released from oxazolidin]; [MBO]
-
-
Carc. 1B; Muta. 2
yes
 Details
reaction mass of: N-[3-hydroxy-2-(2-methylacryloylaminomethoxy)propoxymethyl]-2-methylacrylamide; N-[2,3-bis-(2-methylacryloylaminomethoxy)propoxymethyl]-2-methylacrylamide; methacrylamide; 2-methyl-N-(2-methylacryloylaminomethoxymethyl)-acrylamide; N-(2,3-dihydroxypropoxymethyl)-2-methylacrylamide
VERNETZER TMAG
412-790-8
-
Carc. 1B; Muta. 2
yes
 Details
quinoline
202-051-6
91-22-5
Carc. 1B; Muta. 2
yes
 Details
phenylhydrazinium sulphate; (2:1)
257-622-2
52033-74-6
Carc. 1B; Muta. 2
yes
 Details
phenylhydrazinium chloride
200-444-7
59-88-1
Carc. 1B; Muta. 2
yes
 Details
phenylhydrazine hydrochloride
248-259-0
27140-08-5
Carc. 1B; Muta. 2
yes
 Details
phenylhydrazine
202-873-5
100-63-0
Carc. 1B; Muta. 2
yes
 Details
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