Registration Dossier

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Administrative data

First-aid measures

Description of first aid measures
Immediately remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.


Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
dry powder, foam, carbon dioxide

Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.

Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

Accidental release measures

Accidental Release Measures
Personal precautions, protective equipment and emergency procedures
Avoid contact with the skin, eyes and clothing.

Environmental precautions
Do not empty into drains.

Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.

Handling and storage

Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Avoid contact with the skin, eyes and clothing. Avoid inhalation of dusts/mists/vapours.

Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

Conditions for safe storage, including any incompatibilities

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Control parameters

Components with occupational exposure limits


1336-21-6: ammonia...%
TWA value 14 mg/m3 ; 20 ppm (OEL (EU))
indicative
STEL value 36 mg/m3 ; 50 ppm (OEL (EU))
indicative

Exposure controls
Personal protective equipment
Respiratory protection:
Breathing protection if gases/vapours are formed. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Hand protection:
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
chloroprene rubber (CR) - 0.5 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen based on level of activity and exposure.

General safety and hygiene measures
Avoid contact with the skin, eyes and clothing.

Stability and reactivity

Reactivity

Corrosion to metals:
No data available.

Chemical stability

Possibility of hazardous reactions
No hazardous reactions known.

Disposal considerations

Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.


Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.