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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Additional information on environmental fate and behaviour

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Administrative data

Endpoint:
additional information on environmental fate and behaviour
Type of information:
experimental study
Adequacy of study:
other information
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
study well documented, meets generally accepted scientific principles, acceptable for assessment
Remarks:
The study is well described in terms of both experimental conditions and results. It gives interesting information on oxidation of catechol.

Data source

Reference
Reference Type:
publication
Title:
Effect of polar substituents on autoxidation of phenols
Author:
Moussavi M
Year:
1979
Bibliographic source:
Water Research, 13, 1125-1128

Materials and methods

Principles of method if other than guideline:
No data
GLP compliance:
not specified
Type of study / information:
The autoxidation of phenolic compounds, including catechol, was studied in mild alkaline media of pH 7 to 9 at room temperature.

Test material

Constituent 1
Chemical structure
Reference substance name:
Pyrocatechol
EC Number:
204-427-5
EC Name:
Pyrocatechol
Cas Number:
120-80-9
Molecular formula:
C6H6O2
IUPAC Name:
pyrocatechol
Details on test material:
- Name of test material (as cited in study report): pyrocatechol
- Analytical purity: > 99%
No further data.

Results and discussion

Any other information on results incl. tables

The kinetic constants of the reaction of catechol with oxygen were presented in the following table. These kinetics correspond to the autoxidation of the first -OH group.

pH

k (h-1)

t1/2(h)

7

1.55x 10-3

447

8

1.67 x 10-3

415

9

1.68 x 10-3

412

The autoxidation reaction followed first-order kinetics. No reaction was found to proceed a significant extent during the periods in which the experiment was conducted.

Applicant's summary and conclusion