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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Boiling point

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Administrative data

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Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
weight of evidence
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
secondary literature
Principles of method if other than guideline:
No data
GLP compliance:
not specified
Type of method:
other: no data
Key result
Boiling pt.:
>= 175.5 - <= 176 °C
Atm. press.:
1 atm
Remarks on result:
other: Atm. pressure is not reported, only supposed
Conclusions:
Boiling point of l-limonene is between 175.5 and 176 °C.
Executive summary:

Boiling point of l-limonene was reported to be between 175.5 and 176 °C. It is an experimental value but the reliability is not assignable because the data come from secondary literature.

Endpoint:
boiling point
Type of information:
experimental study
Adequacy of study:
weight of evidence
Study period:
no data
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
data from handbook or collection of data
Principles of method if other than guideline:
Method followed unknown, data from handbook
GLP compliance:
not specified
Type of method:
other: no data
Key result
Boiling pt.:
>= 175.5 - <= 176.5 °C
Atm. press.:
763 mm Hg

None

Conclusions:
The boiling point of l-limonene is 175.5-176.5 °C at 763 mm Hg.
Executive summary:

The boiling point of l-limonene is 175.5-176.5 °C at 763 mm Hg.

The reliability of this result has been considered as 2 (reliable with restrictions) because ‘The Merck Index’ is cited as a reference book containing peer reviewed data in the REACH Guidance Document R.7a.

Endpoint:
boiling point
Type of information:
read-across from supporting substance (structural analogue or surrogate)
Adequacy of study:
weight of evidence
Study period:
1991
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
other: Read-across from an analogue substance for which information (Klimish =4 ) is available.
Justification for type of information:
REPORTING FORMAT FOR THE ANALOGUE APPROACH
See cross-reference to justification of read-across.
Reason / purpose for cross-reference:
read-across source
Reason / purpose for cross-reference:
read-across: supporting information
Key result
Boiling pt.:
450.6 K
Atm. press.:
101.32 kPa
Remarks on result:
other: Based on the read-across from the analogue d-limonene.
Conclusions:
Based on the read-across from the analogue d-limonene, l-limonene is concluded to have a boiling point of 450.6 K at 101.32 kPa.
Executive summary:

Based on the read-across from the analogue d-limonene, l-limonene is concluded to have a boiling point of 450.6 K at 101.32 kPa.

Endpoint:
boiling point
Type of information:
read-across from supporting substance (structural analogue or surrogate)
Adequacy of study:
weight of evidence
Study period:
no data
Reliability:
4 (not assignable)
Rationale for reliability incl. deficiencies:
other: Read-across from an analogue substance for which information (Klimish =4 ) is available.
Justification for type of information:
REPORTING FORMAT FOR THE ANALOGUE APPROACH
See cross-reference to justification of read-across.
Reason / purpose for cross-reference:
read-across source
Reason / purpose for cross-reference:
read-across: supporting information
Key result
Boiling pt.:
178 °C
Remarks on result:
other: Based on the read-across from the analogue substance d-limonene.
Conclusions:
Based on the read.across from the analogue substance d-limonene, l-limonene is concluded to have a boiling point of 178ºC.
Executive summary:

Based on the read.across from the analogue substance d-limonene, l-limonene is concluded to have a boiling point of 178ºC.

Endpoint:
boiling point
Type of information:
read-across from supporting substance (structural analogue or surrogate)
Adequacy of study:
weight of evidence
Study period:
no data
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Read-across from an analogue substance for which information (Klimish =2 ) is available.
Justification for type of information:
REPORTING FORMAT FOR THE ANALOGUE APPROACH
See cross-reference to justification of read-across.
Reason / purpose for cross-reference:
read-across source
Reason / purpose for cross-reference:
read-across: supporting information
Key result
Boiling pt.:
>= 175.5 - <= 176 °C
Atm. press.:
763 mm Hg
Conclusions:
Based on the read-across from the analogue substance d-limonene, the boiling point of l-limonene is estimated to be 175.5-176 °C at 763 mm Hg.
Executive summary:

Based on the read-across from the analogue substance d-limonene, the boiling point of l-limonene is estimated to be 175.5-176 °C at 763 mm Hg.

Description of key information

Weight of evidence: Boiling point at ca. 101 kPa : 176 - 178 °C.

Key value for chemical safety assessment

Boiling point at 101 325 Pa:
176 °C

Additional information

In a weight of evidence approach a melting point of l-limonene is calculated consistent with all values reported for the two enantiomers (d- and l-limonene) being in the same order of magnitude.