Registration Dossier

Administrative data

First-aid measures

Description of necessary first-aid measures

General advice : Show this safety data sheet to the doctor in attendance.
First aider needs to protect himself.
Place affected clothing in a sealed bag for subsequent decontamination.

Skin contact : Take off contaminated clothing and shoes immediately.
In case of skin contact Wash off with soap and plenty of water.
Wash immediately and thoroughly for a prolonged period (at least 15 minutes). Call a physician if irritation develops or persists.

Eye contact : Rinse immediately with plenty of water for at least 15 minutes. If eye irritation persists, consult a physician

Ingestion : Do NOT induce vomiting. Rinse mouth with water.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media : Water spray
Carbon dioxide (CO2) powder
Unsuitable extinguishing media : Do not use a solid water stream as it may scatter and spread fire.

Special hazards arising from the substance or mixture
Specific hazards during fire fighting: Combustible liquid
Harmful or toxic vapours are released.

Advice for firefighters
Special protective equipment for fire-fighters
: For further information refer to "Exposure controls/personal protection".
Specific fire fighting methods : Evacuate personnel to safe areas.
Cool containers / tanks with water spray.
Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Accidental release measures

Personal precautions, protective equipment and emergency procedures : Avoid contact with the skin and the eyes.
Do not breathe vapour.
Wear suitable protective equipment.
Do not allow uncontrolled discharge of product into the environment.

Personal protective equipment
Eye/face protection
PVC or other plastic material gloves
For further information refer to section "Exposure controls/personal protection".
Collect spillage.
Measures for separation from incompatible substances and mixtures
Environmental precautions : Prevent product from entering drains.
Treat recovered material as described in the section "Disposal considerations".

Methods for Cleaning or Taking Up
Recovery : Soak up with inert absorbent material.
Keep in properly labelled containers.
Keep in suitable, closed containers for disposal.
Decontamination/cleaning : Wash off with plenty of water.
Disposal : Dispose of contents/ container to an approved waste disposal plant.

Handling and storage

Handling
Technical measures : Provide adequate ventilation.

Advice on safe handling and usage : Avoid the formation or spread of mists in the atmosphere.
Do not heat the product.
Do NOT handle without gloves.

Storage
Technical Measures for storage : The floor of the depot should be impermeable and designed to form a water-tight basin.

Storage conditions
Recommended : Keep in a cool, well-ventilated place.
Keep container tightly closed.
Incompatible products : Strong bases
Strong oxidizing agents
Packaging Measures
Packaging materials - Recommended : Keep only in the original container.

Transport information

Land transport (ADR/RID)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
Bis(2,4,4-trimethylpentyl)phosphinic acid
Language:
English
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
Bis(2,4,4-trimethylpentyl)phosphinic acid
Language:
English
Class:
9
Classification code:
M6
Packaging group:
III
Labels:
9
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
Bis(2,4,4-trimethylpentyl)phosphinic acid
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
Bis(2,4,4-trimethylpentyl)phosphinic acid
Class:
9
Packaging group:
III
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Personal protective equipment
Respiratory protection : If mist is formed:
Respirator with a particle filter (EN 143)

Hand protection : PVC disposable gloves
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the
gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Gloves must be inspected prior to use.
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Eye protection : Safety glasses. Face-shield

Skin and body protection : impervious clothing
Boots
Choose body protection according to the amount and concentration of the dangerous substance at the work place.
Remove and wash contaminated clothing.

Hygiene measures : Ensure that eyewash stations and safety showers are close to the workstation location.
Use clean, well-maintained personal protection equipment. Wash hands before breaks and at the end of workday.
When using do not eat, drink or smoke.

Protective measures : The protective equipment must be selected in accordance with current CEN standards and in cooperation with the supplier of the protective equipment. Selection of appropriate personal protective equipment should be based on an evaluation of the performance characteristics of the protective equipment relative to the task(s) to be performed, conditions present, duration of use, and the potential hazards
and/or risks that may occur during use.

General advice : Prevent product from entering drains. Treat recovered material as described in the section "Disposal considerations".

Stability and reactivity

Chemical stability : Stable under recommended storage conditions.

Hazardous reactions
Conditions to avoid : May decompose: on heating.
Materials to avoid : Strong oxidizing agents, Strong bases

Decomposition products : On combustion or on thermal decomposition (pyrolysis) releases:
harmful and corrosive vapours.
Oxides of phosphorus
(Carbon oxides (CO + CO2)).

Disposal considerations

Product Disposal
Interdiction : Should not be released into the environment.
Advice on Disposal : Refer to manufacturer/supplier for information on recovery/recycling.
Dispose of as hazardous waste in compliance with local and national regulations.
Do NOT put down the drain. Must undergo physico-chemical treatment prior to disposal.
Advice on cleaning and disposal of packaging
Measures for waste avoidance. : Do NOT dispose of untreated packaging with industrial waste.
Advice : Rinse with an appropriate solvent.
Allow it to drain thoroughly.
After recovery of solvent dispose of by special waste incineration.
Reason for waste disposal : Reuse or recycle following decontamination.
Other data : Dispose of in accordance with local regulations.