Registration Dossier

Administrative data

First-aid measures

4.1. Description of first aid measures
First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Immediately remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.

On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.


4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11.


4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media:
foam, water spray

5.2. Special hazards arising from the substance or mixture

The substances/groups of substances mentioned can be released in case of fire.

carbon monoxide, nitrous gases, aromatic hydrocarbons
If product is heated above decomposition temperature, toxic vapours will be released.

5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Avoid inhalation. Avoid contact with the skin, eyes and clothing.

6.2. Environmental precautions
Do not discharge into drains/surface waters/groundwater.

6.3. Methods and material for containment and cleaning up
For small amounts: Pick up with absorbent material (e.g. sand, sawdust, general-purpose binder).
For large amounts: Pick up with suitable appliance and dispose of. Dispose of absorbed material in accordance with regulations.
Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.

6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas.

Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

7.2. Conditions for safe storage, including any incompatibilities

Suitable materials for containers: Stainless steel 1.4541, Stainless steel 1.4571, High density polyethylene (HDPE)
Further information on storage conditions: Containers should be stored tightly sealed in a dry place. Keep at temperature not exceeding 50°C.

Storage stability:
Storage temperature: < 50 °C
Storage duration: 12 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

7.3. Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

Shippingopen allclose all
Remarksopen allclose all
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters

Components with occupational exposure limits

No occupational exposure limits known.

PNEC
freshwater: 0.02245 mg/l

marine water: 0.002245 mg/l

intermittent release: 0.2245 mg/l

STP: 4 mg/l

sediment (freshwater): 34.1 mg/kg

sediment (marine water): 3.41 mg/kg

soil: 6.78 mg/kg

oral (secondary poisoning):
No PNEC oral derived, as accumulation in organisms is not to be expected.


DNEL
No DNELs have been derived.


8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2, corresponding > 30 minutes of permeation time according to EN 374)
neoprene/chloroprene gloves - material thickness: 0,75 mm

Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
nitrile rubber (NBR) - 0.4 mm coating thickness
butyl rubber (butyl) - 0.7 mm coating thickness

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. Take off immediately all contaminated clothing. Store work clothing separately.

Stability and reactivity

10.1. Reactivity

Corrosion to metals:
Corrosive effects to metal are not anticipated. In the presence of water or moisture metal corrosion cannot be excluded.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.


10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions
Reacts with acids.


10.4. Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat.

10.5. Incompatible materials

Substances to avoid:
acids
10.6. Hazardous decomposition products

No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

13.1. Waste treatment methods

Return to manufacturer.

Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.