Registration Dossier
Registration Dossier
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EC number: 203-815-1 | CAS number: 110-91-8
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Immediately remove contaminated clothing. If the patient is likely to become unconscious, place and
transport in stable sideways position (recovery position). If not breathing, give artificial respiration.
First aid personnel should pay attention to their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.
On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open,
consult an eye specialist.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Most important symptoms and effects, both acute and delayed
Symptoms: Information, i.e. additional information on symptoms and effects may be included in the
GHS labeling phrases available in Section 2 and in the Toxicological assessments available in
Section 11.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote. Pulmonary odema prophylaxis. Medical monitoring for at least 24 hours.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide
Special hazards arising from the substance or mixture
Endangering substances: toxic gases/vapours
Advice: The substances/groups of substances mentioned can be released in case of fire.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.
Accidental release measures
An explosive atmosphere can be formed in the case of a spillage. If large amounts are released contact the fire service.
Personal precautions, protective equipment and emergency procedures
Breathing protection required. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not empty into drains.
Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr).
Cleaning operations should be carried out only while wearing breathing apparatus. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. Product should be worked up in closed equipment as far as possible. Handle in accordance with good industrial hygiene and safety practice. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.
Protection against fire and explosion:
Vapours may form explosive mixture with air. Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.
Conditions for safe storage, including any incompatibilities
Segregate from acids and acid forming substances. Segregate from oxidants. Segregate from esters Segregate from lactones
Suitable materials for containers: Carbon steel (Iron), Stainless steel 1.4301 (V2), Stainless steel 1.4541, Stainless steel 1.4401, Stainless steel 1.4571, Low density polyethylene (LDPE), High density polyethylene (HDPE), glass
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.
Storage stability:
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Components with occupational exposure limits
109-86-4: 2-methoxyethanol
Skin Designation (WEL/EH 40 (UK))
The substance can be absorbed through the skin.
TWA value 3 mg/m3 ; 1 ppm (WEL/EH 40 (UK))
Skin Designation (OEL (EU))
The substance can be absorbed through the skin.
110-91-8: morpholine
Skin Designation (WEL/EH 40 (UK))
The substance can be absorbed through the skin.
TWA value 36 mg/m3 ; 10 ppm (WEL/EH 40 (UK))
TWA value 36 mg/m3 ; 10 ppm (OEL (EU))
indicative
STEL value 72 mg/m3 ; 20 ppm (OEL (EU))
indicative
STEL value 72 mg/m3 ; 20 ppm (WEL/EH 40 (UK))
Ceiling limit value/factor: 15 min
PNEC
freshwater: 0.163 mg/l
marine water: 0.0163 mg/l
intermittent release: 0.45 mg/l
sediment (freshwater): 1.83 mg/kg
sediment (marine water): 0.183 mg/kg
soil: 0.269 mg/kg
STP: 10 mg/l
oral (secondary poisoning):
No PNEC oral derived, as accumulation in organisms is not to be expected.
DNEL
worker:
Long-term exposure- systemic effects, dermal: 0.84 mg/kg
worker:
Long-term exposure - local effects, Inhalation: 36 mg/m3
8.2. Exposure controls
Page: 8/63
BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.
Date / Revised: 09.06.2021 Version: 18.0
Date previous version: 27.03.2020 Previous version: 17.0
Product: Morpholine
(ID no. 30036734/SDS_GEN_GB/EN)
Date of print 24.02.2022
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Combination filter for gases/vapours of
organic, inorganic, acid inorganic, alkaline compounds and toxic particles (e. g. EN 14387 Type
ABEK-P3) Suitable respiratory protection for higher concentrations or long-term effect: Selfcontained
breathing apparatus.
Consider the risk management measures as outlined in the exposure scenario.
Hand protection:
Chemical resistant protective gloves (EN ISO 374-1)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN ISO 374-1):
butyl rubber (butyl) - 0.7 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
Polyethylene-Laminate (PE laminate) - ca. 0.1 mm coating thickness
Suitable materials for short-term contact (recommended: At least protective index 2, corresponding >
30 minutes of permeation time according to EN ISO 374-1)
nitrile rubber (NBR) - 0.4 mm coating thickness
polyvinylchloride (PVC) - 0.7 mm coating thickness
chloroprene rubber (CR) - 0.5 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in
practice may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Tightly fitting safety goggles (cage goggles) (e.g. EN 166) and face shield.
Body protection:
chemical-protection suit (f.e. according to EN 14605)
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with the skin,
eyes and clothing. Avoid inhalation of vapour. When using, do not eat, drink or smoke. Hands and/or
face should be washed before breaks and at the end of the shift. Gloves must be inspected regularly
and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all
contaminated clothing. Wash contaminated clothing before reuse. Store work clothing separately.
Stability and reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
Corrosive effects to metal are not anticipated.
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
Strong exothermic reaction with acids.
Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame.
Incompatible materials
Substances to avoid:
oxidizing agents, acids, nitrosating agents, Avoid contact with reactive components such as acids and organic components, for example ester and lactone., Avoid contact with monomers that can induce in alkaline medium polymerization.
Hazardous decomposition products
Hazardous decomposition products:
carbon monoxide, Carbon dioxide
toxic gases/vapours
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
