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Diss Factsheets
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EC number: 200-471-4 | CAS number: 60-34-4
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Toxicity to other aquatic organisms
Administrative data
- Endpoint:
- toxicity to other aquatic vertebrates
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Reliability:
- 4 (not assignable)
- Rationale for reliability incl. deficiencies:
- other: Non-GLP, non-guideline data, no analytical follow-up (issue when considering the long exposure time), lacking details on design (media characteristics)
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 976
Materials and methods
Test guideline
- Qualifier:
- no guideline available
- Principles of method if other than guideline:
- Teratogenicity towards Xenopus (amphibian) embryos:
Test using embryonic and larval stages of frogs, aimed at assaying the effects on the development of frogs and determining EC50 and no-effect levels.
- Greenhouse, G. (1976). A method for evaluating the toxic effects of pollutants on fresh water systems using embryos and larvae of Xenopus laevis, the South African clawed toad. Environ. Pollut.
- Nieuwkoop, P. and Faber, J. (1956). Normal Table of Xenopus Laevis (Daudin). North Holland, Amsterdam. - GLP compliance:
- no
- Remarks:
- prior to GLP
Test material
- Reference substance name:
- Methylhydrazine
- EC Number:
- 200-471-4
- EC Name:
- Methylhydrazine
- Cas Number:
- 60-34-4
- Molecular formula:
- CH6N2
- IUPAC Name:
- methylhydrazine
- Details on test material:
- source: Aldrich Chemical Company
Constituent 1
Sampling and analysis
- Analytical monitoring:
- no
Test solutions
- Details on test solutions:
- Each glass bowl contained one liter of water and 100 embryos.
Test organisms
- Test organisms (species):
- Xenopus laevis
- Details on test organisms:
- Xenopus laevis embryos/larvae:
embryos (obtained by injection of frogs with human chorionic gonadotropin) were dejellied in 3% cystein, 0.1% papain, pH 8.0, and then cultured in aged dechlorinated tap water in glass bowls.
Only clutches of eggs which proved to be at least 95% fertile were used.
, source: wild-caught (drainage ditches in Costa Mesa, California) or commercial (South African Snake Farm, South Africa).
maintained in glass aquaria
fed Purina Trout Chow twice weekly
Study design
- Test type:
- static
- Water media type:
- not specified
- Limit test:
- no
- Remarks on exposure duration:
- from blastula to hatching
- Post exposure observation period:
- no data
Test conditions
- Hardness:
- no data
- Test temperature:
- no data
- pH:
- no data
- Dissolved oxygen:
- no data
- Salinity:
- no data
- Nominal and measured concentrations:
- Nominal test concentrations of <5, 5, 7.5, 10 and 15 mg/L.
- Details on test conditions:
- no data
- Reference substance (positive control):
- no
Results and discussion
Effect concentrations
- Dose descriptor:
- EC50
- Effect conc.:
- > 5 - < 7.5 mg/L
- Nominal / measured:
- nominal
- Conc. based on:
- test mat.
- Basis for effect:
- morphology
- Remarks:
- teratogenicity
- Details on results:
- =< 5% embryos malformed at =< 5 mg/L
>= 97% embryos malformed at >= 7.5 mg/L
very steep dose-effect curve, so no precise EC50 value could be derived statistically - Reported statistics and error estimates:
- not applicable
Applicant's summary and conclusion
- Validity criteria fulfilled:
- not applicable
- Remarks:
- non-guideline
- Executive summary:
MMH was teratogenic to Xenopus laevis frog embryos. The EC50 for malformations lied between 5 and 7.5 mg/L, with an extremely steep dose-effect curve.
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