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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Description of first aid measures
Inhalation Remove from danger zone. Obtain immediate medical assistance.
Skin Contact Remove contaminated clothing. Rinse contaminated skin immediately with plenty of water and soap and seek medical advice.
If skin irritation persists, call a physician.
Eye Contact Immediately rinse eyes thoroughly with running water as long as possible (approx. 15 min).
Take injured quickly to factory medical center or call an ambulance (code word: eye accident).
Ingestion Do not induce vomiting. In case of consciousness wash mouth with water and let drink some of water. Seek medical advice. Keep patient at rest.
Self-protection of the first aider
For personal protection see SDS Section 8

Most important symptoms and effects, both acute and delayed

Indication of any immediate medical attention and special treatment needed
Notes to Physician Gastric lavage, activated charcoal
Treatment is essentially supportive and symptomatic.

Fire-fighting measures

Extinguishing media
Suitable Extinguishing Media Water spray or fog, foam, dry chemical powder, CO2, dry sand
Unsuitable Extinguishing Media No restrictions

Special hazards arising from the substance or mixture
Dangerous Combustion Products nitrogen oxides
hydrogen chloride

Advice for firefighters
Protective equipment for firefighters Wear self-contained breathing apparatus for fire fighting.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Personal precautions Avoid contact with skin, eyes and clothing.

Environmental precautions
Environmental precautions Do not release into the environment.

Methods and material for containment and cleaning up
Methods for cleaning Transfer large quantities into a container, rinse the rest with plenty of water. Consult experts for decontamination.

Reference to other sections
For personal protection see SDS Section 8, for disposal considerations see SDS Section 13

Handling and storage

Precautions for safe handling
Storage and Handling Precautions Provide exhaust ventilation system in case of open handling. Keep container tightly closed in a dry, cool a nd well-ventilated place. Avoid formation of dust.
For Industrial Hygiene Measures see SDS Section 8, Exposure controls / Personal protection

Conditions for safe storage, including any incompatibilities
Conditions of storage Protect against humidity
Preventive Precautions (fire/explosion) Observe the usual precautionary measures required for chemicals with dust explosive properties (Obs erve national regulations).

Specific end use(s)
See SDS Subsection 1.2

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
3077
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Labels:
9, M
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Marine transport (UN RTDG/IMDG)

UN number:
3077
Shipping information
Chemical name:
sodium 2-{2-[(2,6-dichlorophenyl)amino]phenyl}acetate
Labels:
9, M
Special provisions / remarks
Remarks:
LQ : 5 kg

Air transport (UN RTDG/ICAO/IATA)

UN number:
3077
Shipping information
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s. ( DICLOFENAC SODIUM)
Chemical name:
sodium 2-{2-[(2,6-dichlorophenyl)amino]phenyl}acetate
Labels:
9, M
Remarksopen allclose all

Additional transport information

Additional information
Special provisions / remarks / other:
Transport condition: NORMAL: Transport + intermediate storage <=40 °C

Exposure controls / personal protection

Control parameters
Internal exposure limit 0.25 mg/m3 Reprotox statement 2: Low probability pregnancy and/or developmental risks

Exposure controls
Industrial Hygiene The personal protective measure may be adapted appropriately when working in closed systems or under laboratory condit ions.
Regular cleaning of equipment, work area and clothing.
Open handling at operator intervention points with local exhaust ventilation (e.g. downflow booths).
Double wardrobe must be available.
Internal working procedures available to personnel covering personal hygiene, standard cleaning, waste disposal and mainten ance.
Personnel instructed and trained, regular refresher training established.

Open Handling Respiration : Disposable fine dust protection mask (EN149) or reusable halfmask (EN140)
Filter : P3 (EN143)
Eye : Safety glasses (EN166)
Hand : Normal length chemical-mechanical-resistant gloves (EN374/EN388)
Glove Material : Nitrile
Breakthrough time: > 480 min
Thickness: 0.2 mm
Additional protection : working clothes (EN 340)

These values are derived from experiments, literature and information from the glove manufacturer.
They can also be derived from similar materials. In daily work please be aware that the using time depends on several factors and can be shorter than the oficially tested permeation time.

Stability and reactivity

Reactivity
Reaction products with water no data available

Chemical stability
Stability in solvents no data available
Hydrolysis no data available

Possibility of hazardous reactions
Materials to avoid none known

Conditions to avoid
Conditions to avoid no data available

Incompatible materials
For Incompatible materials see Subsection 7.2 Conditions for safe storage, including any incompatibilities in SDS

Hazardous decomposition products
Hazardous Decomposition Products no data available

Disposal considerations

Disposal Requirements Fill into suitable waste receptacles, seal and label them properly.
Incineration in an approved, controlled furnace with combustion gas scrubbing and emission gas control.

Container Disposal For disposal local regulation is binding.