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Environmental fate & pathways

Biodegradation in water: screening tests

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Description of key information

EDTMP and its salts are considered not readily biodegradable and not inherently biodegradable. One study is available for EDTMP-xNa which shows 0%  biodegradation in a ready test. In tests performed with EDTMP-H, low  but recordable levels of biodegradation were seen in two other ready and two inherent tests. A high degree (75-90%) of removal was recorded in the longer term (extended SCAS test over 126 days; Horstmann and Grohmann, 1988). 

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Additional information

One reliable test of ready biodegradation is available for EDTMP-xNa. This showed 0% biodegradation in 28 d (Douglas and Pell, 1984).

Two reliable tests of ready biodegradation (similar to modified OECD screening test method) and two reliable tests of inherent biodegradation (semi-continuous activated sludge) are available for EDTMP-H. All available results are consistent with very low levels of biodegradation in the short term (28-day) time window. The levels of removal observed were ca. 30% in 28 d (Martienssen, 2010, modified OECD test of ready biodegradation); ca. 5 to ca. 10% in 28 d (Horstmann and Grohmann, 1988, modified OECD test of ready biodegradation)

, 1.85 and 6.67% in 24-h and 72-h cycles respectively in a 220-day test (Saeger, 1978, extended SCAS test) and 75-90% in 126 d (Horstmann and Grohmann, 1988, extended SCAS test).In dilute aqueous conditions of defined pH, a salt will behave no differently to the parent acid, at identical concentration of the particular speciated form present, and will be fully dissociatedto yield EDTMP and sodium ions.Hence some properties (measured or expressed in aqueous media) for a salt can be directly read across (with suitable mass correction) to the parent acid andvice versa (see CSR section 1 for mass correction values). In the present context the effect of the alkaline metal counter-ion (sodium) will not be significant and has been extensively discussed in the public literature. In biological systems and the environment, polyvalent metal ions will be present, and the phosphonate ions show very strong affinity to them.