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Diss Factsheets
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EC number: 213-424-8 | CAS number: 947-04-6
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Toxicity to reproduction
Administrative data
- Endpoint:
- fertility, other
- Remarks:
- based on test type (migrated information)
- Type of information:
- migrated information: read-across from supporting substance (structural analogue or surrogate)
- Adequacy of study:
- weight of evidence
- Study period:
- unknown
- Reliability:
- 4 (not assignable)
- Rationale for reliability incl. deficiencies:
- other: Secondary literature
Data source
Reference
- Reference Type:
- publication
- Title:
- ε-Caprolactam / Toxikologisch-arbeitsmedizinische Begründungen von MAK-Werten
- Author:
- DFG (Deutsche Forschungsgemeinschaft)
- Year:
- 1 990
- Bibliographic source:
- WILEY-VCH GmbH, Weinheim
Materials and methods
- Principles of method if other than guideline:
- Method not described
- GLP compliance:
- not specified
- Limit test:
- no
Test material
- Reference substance name:
- ε-caprolactam
- EC Number:
- 203-313-2
- EC Name:
- ε-caprolactam
- Cas Number:
- 105-60-2
- Molecular formula:
- C6H11NO
- IUPAC Name:
- azepan-2-one
- Details on test material:
- no further details described
Constituent 1
Test animals
- Species:
- rat
- Strain:
- not specified
- Sex:
- male/female
- Details on test animals or test system and environmental conditions:
- no further information
Administration / exposure
- Route of administration:
- oral: feed
- Vehicle:
- other: test item was mixed in diet
- Details on exposure:
- no further information
- Details on mating procedure:
- no further information
- Analytical verification of doses or concentrations:
- not specified
- Details on analytical verification of doses or concentrations:
- no further information
- Duration of treatment / exposure:
- Duration of treatment: exposed over a period of 3 generations
- Frequency of treatment:
- daily ad libitum (via food intake)
- Details on study schedule:
- no further information
Doses / concentrations
- Remarks:
- Doses / Concentrations:
1000; 5000; 10000 mg/kg diet
Basis:
nominal in diet
mg/kg diet
- No. of animals per sex per dose:
- no information
- Control animals:
- not specified
- Details on study design:
- no further details
- Positive control:
- no data
Examinations
- Parental animals: Observations and examinations:
- food consumption; body weight gain; birth behaviour
- Oestrous cyclicity (parental animals):
- no data
- Sperm parameters (parental animals):
- no data
- Litter observations:
- no data
- Postmortem examinations (parental animals):
- macroscopic examinations
- Postmortem examinations (offspring):
- no data
- Statistics:
- no data
- Reproductive indices:
- no data
- Offspring viability indices:
- survival time of offspring; food consumption; body weight gain
Results and discussion
Results: P0 (first parental generation)
General toxicity (P0)
- Clinical signs:
- not specified
- Body weight and weight changes:
- effects observed, treatment-related
- Food consumption and compound intake (if feeding study):
- effects observed, treatment-related
- Organ weight findings including organ / body weight ratios:
- not specified
- Histopathological findings: non-neoplastic:
- not specified
- Other effects:
- not specified
Reproductive function / performance (P0)
- Reproductive function: oestrous cycle:
- not specified
- Reproductive function: sperm measures:
- not specified
- Reproductive performance:
- no effects observed
Details on results (P0)
- at doses of 5000 and 10000 mg/kg diet: dose dependent reduction of food intake and body weight gain
- at a dose of 10000 mg/kg diet: macroscopic slightly damage of kidneys in male rats
- no effects on birth behaviour and survival of new bornsat examined
Effect levels (P0)
open allclose all
- Dose descriptor:
- LOEL
- Effect level:
- 5 000 mg/kg diet
- Sex:
- male/female
- Basis for effect level:
- other: reduced food consumption and body weight increase in parents and new borns
- Remarks on result:
- other: Generation: all generations examined (migrated information)
- Dose descriptor:
- LOEL
- Effect level:
- 500 mg/kg bw/day
- Sex:
- male/female
- Basis for effect level:
- other: calculated from the NOAEL described in the publication (5000 mg/kg diet) under assumption that the average food intake of rats is 10 g/100g bw/day
- Remarks on result:
- other: Generation: all generations examined (migrated information)
- Dose descriptor:
- NOEL
- Effect level:
- 1 000 mg/kg diet
- Sex:
- male/female
- Remarks on result:
- other: Generation: all generations examined (migrated information)
- Dose descriptor:
- NOEL
- Effect level:
- 100 mg/kg bw/day
- Sex:
- male/female
- Basis for effect level:
- other: calculated from the NOEL described in the publication (1000 mg/kg diet) under assumption that the average food intake of rats is 10 g/100g bw/day
- Remarks on result:
- other: Generation: all generations examined (migrated information)
- Dose descriptor:
- NOAEL
- Effect level:
- 500 mg/kg bw/day
- Sex:
- male/female
- Basis for effect level:
- other: calculated from LOEL
- Remarks on result:
- other: Generation: all generations examined (migrated information)
Results: F1 generation
General toxicity (F1)
- Clinical signs:
- not specified
- Mortality / viability:
- no mortality observed
- Body weight and weight changes:
- effects observed, treatment-related
- Sexual maturation:
- not specified
- Organ weight findings including organ / body weight ratios:
- not specified
- Gross pathological findings:
- effects observed, treatment-related
- Histopathological findings:
- not specified
Details on results (F1)
- at a dose of 10000 mg/kg diet: macroscopic slightly damage of kidneys in male rats
Effect levels (F1)
- Dose descriptor:
- LOAEL
- Generation:
- F1
- Effect level:
- 5 000 mg/kg diet
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- body weight and weight gain
Overall reproductive toxicity
- Reproductive effects observed:
- not specified
Any other information on results incl. tables
no further remarks
Applicant's summary and conclusion
- Conclusions:
- The substance ε-caprolactam was tested over three generations of rats for its potential reproduction toxicity by oral gavage of doses of 1000, 5000and 10000 mg/kg diet. The birth behaviour of dams and the time of survival of offspring was not affected (NOEL: 1000 mg/kg diet (calculated: approx. 100 mg/kg bw/day); LOEL: 5000 mg/kg diet (calculated: approx. 500 mg/kg bw/day).
- Executive summary:
The substance ε-caprolactam was tested over three generations of rats for its potential reproduction toxicity by oral gavage of doses of 1000, 5000 and 10000 mg/kg diet. A decreased food consumption and bodyweight gain was observed on doses of 5000 and 10000 mg/kg diet in dams and offspring. At 10000 mg/kg diet macroscopic slightly damages of kidneys in male rats were observed. The birth behaviour of dams and the time of survival of offspring was not affected. The NOEL was determined as 1000 mg/kg diet (calculated: approx. 100 mg/kg bw/day) and the LOEL is 5000 mg/kg diet (calculated: approx.500 mg/kg bw/day).
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