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EC number: 271-692-1 | CAS number: 68604-41-1 The complex residuum from the distillation of the methyl ester of C16-18 and C18-unsatd. fatty acids. It consists primarily of trialkyl glycerides and undistilled methyl ester of the fatty acids.
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Skin irritation / corrosion
Administrative data
- Endpoint:
- skin irritation / corrosion, other
- Remarks:
- in vivo existing study
- Type of information:
- experimental study
- Remarks:
- based on read across
- Adequacy of study:
- key study
- Study period:
- From February 11, 1988 to February 25, 1988
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- comparable to guideline study with acceptable restrictions
- Justification for type of information:
- The main components of the UVCB substance are fatty acids and fatty acids methyl esters. Biodiesel was used to assess the endpoint.
Cross-reference
- Reason / purpose for cross-reference:
- read-across source
Reference
- Endpoint conclusion:
- no adverse effect observed (not irritating)
- Endpoint conclusion:
- no adverse effect observed (not irritating)
The substance is not skin and eye irritating
The substance is not skin and eye irritating.
There is no structural alerts or physical chemical property that can support a risk for respiratory tract. Due to the low vapour pressure of the substance, the inhalatory route is of minimal relevance
No classification for skin irritation is warranted under 67/548/EEC or Regulation 1272/2008.
No classification for eye irritation is warranted under 67/548/EEC or Regulation 1272/2008.
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 1 988
- Report date:
- 1988
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 404 (Acute Dermal Irritation / Corrosion)
- Deviations:
- no
- GLP compliance:
- no
Test material
- Reference substance name:
- Fatty acids, C16-18 and C18-unsatd., Me esters
- EC Number:
- 267-015-4
- EC Name:
- Fatty acids, C16-18 and C18-unsatd., Me esters
- Cas Number:
- 67762-38-3
- Molecular formula:
- UVCB substance, not univocal molecular formula available
- IUPAC Name:
- UVCB substance, no IUPAC name avalilable Chemical name: C16-C18 and C18 unsaturated alkyl carboxylic acids methyl esters
- Test material form:
- liquid: viscous
- Details on test material:
- - Name of test material: Fatty acids C16-C18 and C18 unsaturated methyl esters
- Physical state: light yellow liquid
- Analytical purity: 79.01% (sum of methylesters of C18 fatty acids)
- Certificate of analysis reference EST_P77220_0806159_080814_13
- Water solubility: < 0.13 mg/L (20°C) according to SDS
- Relative density at 20°C: 890 kg/m^3 according to SDS
Constituent 1
- Specific details on test material used for the study:
- fatty acid methyl esters, (biodiesel)
Test animals
- Species:
- rabbit
- Details on test animals or test system and environmental conditions:
- Male adult rabbits of the tribe Little Russian Chbb: HM / Fa. Thomae, Biberach / D.
Test system
- Type of coverage:
- occlusive
- Preparation of test site:
- shaved
- Vehicle:
- unchanged (no vehicle)
- Controls:
- no
- Amount / concentration applied:
- The substance was tested in undiluted form for primary skin irritation. 0.5 g of the product was applied to a 2.5 cm x 2.5 cm linen lobe
- Duration of treatment / exposure:
- 4 hours
- Observation period:
- Post observation of 3 days
- Number of animals:
- 4 adult males
- Details on study design:
- Experimental procedure
Approximately 24 hours before the application, the back skin of the test animals was shaved and the skin was examined for its state of health before the exposure. Only animals with uninjured skin were used.
The substance was tested in undiluted form for primary skin irritation. 0.5 g of the product was applied to a 2.5 cm x 2.5 cm linen lobe and spread evenly on the linen lobe. The linen lobes were placed on the shaved back skin of the rabbits, covered with a larger plastic sheet fixed at the edges with adhesive plaster, and then secured with acrylicastic tape for secure fixation and occlusive coverage.
The contact time was 4 hours. During this time, the experimental animals were kept in special boxes, which prevented a shift of the linen lobes on the dorsal skin.
Results and discussion
In vivo
Resultsopen allclose all
- Irritation parameter:
- erythema score
- Basis:
- mean
- Time point:
- other: 1 hour
- Score:
- ca. 0.75
- Max. score:
- 4
- Reversibility:
- fully reversible within: 24h
- Irritation parameter:
- erythema score
- Basis:
- mean
- Time point:
- other: 24h
- Score:
- ca. 0
- Max. score:
- 4
- Irritation parameter:
- erythema score
- Basis:
- mean
- Time point:
- other: 48h
- Score:
- ca. 0
- Max. score:
- 4
- Irritation parameter:
- erythema score
- Basis:
- mean
- Time point:
- other: 72h
- Score:
- ca. 0
- Max. score:
- 4
- Irritation parameter:
- edema score
- Basis:
- mean
- Time point:
- other: 1h
- Score:
- ca. 0
- Max. score:
- 4
- Irritation parameter:
- edema score
- Basis:
- mean
- Time point:
- other: 24h
- Score:
- ca. 0
- Max. score:
- 4
- Irritation parameter:
- edema score
- Basis:
- mean
- Time point:
- other: 48
- Score:
- ca. 0
- Max. score:
- 4
- Irritation parameter:
- edema score
- Basis:
- mean
- Time point:
- other: 72h
- Score:
- ca. 0
- Max. score:
- 4
Applicant's summary and conclusion
- Interpretation of results:
- not irritating
- Remarks:
- Migrated information Criteria used for interpretation of results: EU
- Conclusions:
- Not irritating
- Executive summary:
The substance was tested for primary irritation under occlusive conditions on the shaved back skin of 4 rabbits. After a contact time of 4 hours the skin reaction were evaluated. Three of four animals had a slight skin redness one hour after application. The redness completely disappear after 24 hours. The substance is considered not irritating
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