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Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

Description of first aid measures
Remove contaminated clothing.
If inhaled:
If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical
attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Rinse mouth and then drink plenty of water.
Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11., Further important symptoms and effects are so far not known.
Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific
antidote.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam
Unsuitable extinguishing media for safety reasons:
water jet
Special hazards arising from the substance or mixture
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.
Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.
Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Breathing protection required.
Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface
waters/groundwater.
Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material. Dispose of absorbed material in accordance
with regulations.
Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found
in section 8 and 13.

Handling and storage

Precautions for safe handling
No special measures necessary provided product is used correctly.
Protection against fire and explosion:
Take precautionary measures against static discharges.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed and dry; store in a cool place.
Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be
observed.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 3082
Shippingopen allclose all
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains BENZOTRIAZOLE DERIVATIVE)
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 3082
Shippingopen allclose all
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains BENZOTRIAZOLE DERIVATIVE)
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains BENZOTRIAZOLE DERIVATIVE)
Chemical name:
BENZOTRIAZOLE DERIVATIVE
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains BENZOTRIAZOLE DERIVATIVE)
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains BENZOTRIAZOLE DERIVATIVE)
Chemical name:
BENZOTRIAZOLE DERIVATIVE
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(contains BENZOTRIAZOLE DERIVATIVE)
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls
Personal protective equipment
Respiratory protection:
Suitable respiratory protection for higher concentrations or long-term effect: Gas filter for
gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials short-term contact and/or splashes (recommended: At least protective index 2,
corresponding > 30 minutes of permeation time according to EN 374)
butyl rubber (butyl) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is recommended.

Stability and reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
No hazardous reactions when stored and handled according to instructions.
Conditions to avoid
Avoid electro-static discharge. Avoid sources of ignition.
Incompatible materials
Substances to avoid:
strong acids, strong bases, strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

Waste treatment methods
Must be disposed of or incinerated in accordance with local regulations.
Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.

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