Registration Dossier

Administrative data

Endpoint:
explosiveness
Type of information:
experimental study
Adequacy of study:
key study
Study period:
2010
Reliability:
1 (reliable without restriction)

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2010
Report date:
2010

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
EU Method A.14 (Explosive properties)
GLP compliance:
yes

Test material

Constituent 1
Chemical structure
Reference substance name:
Fatty acids, tall-oil, reaction products with diethylenetriamine, maleic anhydride, tetraethylenepentamine and triethylenetetramine
EC Number:
273-601-0
EC Name:
Fatty acids, tall-oil, reaction products with diethylenetriamine, maleic anhydride, tetraethylenepentamine and triethylenetetramine
Cas Number:
68990-47-6
Molecular formula:
The substance is a UVCB substance. One of the most likely and the smallest molecule arising from the reaction process is assumed to be: C18H33O. C18H31O. 2C4H12N3 . C4H2O2
IUPAC Name:
Reaction product of 2,5-Furandione with reaction products of tall-oil fatty acids, diethylenetriamine, triethylenetetramine and tetraethylenepentamine
Details on test material:
Name: Fatty acid, tall oil, reaction products with diethylenetriamine, maleic anhydride, tetraethylenepentamine and triethylenetramine
Structural Formula: UVCB substance
Molecular weight:>700
Declared purity: 97%
Appearance: concentrated suspension

Results and discussion

Small-scale preliminary testsopen allclose all
Parameter:
other: More sensitive to shock than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: More sensitive to friction than m-dinitrobenzene
Remarks:
migrated information
Remarks on result:
negative (not further specified)
Parameter:
other: Explosive under influence of flame
Remarks:
migrated information
Remarks on result:
negative (not further specified)

Any other information on results incl. tables

Thermal sensitivity (effect of a flame)

The tests with 6,0mm diameter orifice plate showed the following trend:

-         after 153 seconds, flame event and rain of fire;

-         start of an intense phase characterized by ejection of the sample, rain fire and production of white smokes after 180 seconds;

-         the intense phase ends after about 290 seconds.

The tests with 2,0mm diameter orifice plate showed a behaviour similar to those with 6,0mm diameter orifice plate; a more intense production of smokes and a higher ejection rate of products was observed.

No explosion occurred during the six tests performed on the sample labelled asFatty acid, tall oil, reaction products with diethylenetriamine, maleic anhydride, tetraethylenepentamine and triethylenetramine.

The test result is considered negative.

Mechanical sensitivity (shock)

No explosion was obtained during the series of six tests at 40J performed on the sample labelled asFatty acid, tall oil, reaction products with diethylenetriamine, maleic anhydride, tetraethylenepentamine and triethylenetramine(bursting into flame and/or a report is equivalent to explosion).

The test result is considered negative.

Mechanical sensitivity (friction)

No explosion was obtained during the series of six tests performed with a 360 N loading on the sample labelledas Fatty acid, tall oil, reaction products with diethylenetriamine, maleic anhydride, tetraethylenepentamine and triethylenetramine (crepitation and/or a report or bursting into flame are equivalent to explosion)

The test result is considered negative.

Applicant's summary and conclusion

Interpretation of results:
non explosive
Remarks:
Migrated information
Conclusions:
The sample is not considered to present a danger of explosion in the sense of A.14. method.