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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Hydrolysis

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
hydrolysis
Data waiving:
study scientifically not necessary / other information available
Justification for data waiving:
other:

Description of key information

Sodium methanolate reacts vigorously on contact with water forming methanol and sodium hydroxide.

Key value for chemical safety assessment

Additional information

Sodium methanolate is an extremely strong conjugated base. In contact with water, sodium methanolate reacts violently exothermic forming sodium hydroxide and methanol (OECD, 2006). The heat of this exothermic reaction may be sufficient to ignite surrounding combustible materials or sodium methanolate itself, particularly if there is only little water available.
The spontaneous degradation products methanol and sodium hydroxide are hydrolytically stable since they do not contain any chemical groups associated with hydrolysis. In addition, methanol is considered to be readily biodegradable. Thus, in accordance with Annex VIII, column 2 no hydrolysis testing is needed.