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Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

4.1. Description of first aid measures
General advice:
First aider needs to protect himself. Take off all contaminated clothing immediately. Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.
Inhalation:
Move subject to fresh air and keep him calm. See a physician.
Skin contact:
Wash off immediately with soap and water. If skin irritation occurs consult a physician.
Eye contact:
Flush eyes thoroughly with a large amount of water and consult a physician.
Ingestion:
Do not induce vomiting. Call a physician immediately.
4.2. Most important symptoms and effects, both acute and delayed
sensitising effects, irritant effects, Eye irritation, coughing
4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media:
foam
dry chemical
carbon dioxide
water spray
Unsuitable extinguishing media:
High volume water jet
5.2. Special hazards arising from the substance or mixture
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.
5.3. Advice for firefighters
Wear self-contained breathing apparatus.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Assure sufficient ventilation.
Wear protective gloves/protective clothing/eye protection/face protection.
Keep away sources of ignition.
Use breathing apparatus if exposed to vapours/dust/mist/aerosol.
Do not breathe vapours or spray mist.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly with soap and water after handling.
6.2. Environmental precautions
Prevent product from getting into drains/surface water/groundwater.
6.3. Methods and material for containment and cleaning up
Larger quantities: Take up mechanically (by pumping).
Smaller quantities and/or residues:
Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust).
Dispose of in accordance with regulations.
6.4. Reference to other sections
For personal protection see section 8.

Handling and storage

7.1. Precautions for safe handling
Safe handling advice:
Keep container tightly closed. Ensure there is good room ventilation.
Advice on protection against fire and explosion:
Keep away from sources of ignition --- No smoking. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air. Take precautionary measures against static discharges.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Protect from the action of light. Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability. Keep only in the original container at a temperature not exceeding 30 °C.
7.3. Specific end use(s)
no

Transport information

Land transport (ADR/RID)

Shippingopen allclose all
Remarks:
Not a dangerous good within the meaning of transportation regulations.

Inland waterway transport (ADN(R))

Shippingopen allclose all
Remarks
Not a dangerous good within the meaning of transportation regulations.

Marine transport (IMDG)

Remarks
Not a dangerous good within the meaning of transportation regulations.

Air transport ICAO/IATA

Remarks
Not a dangerous good within the meaning of transportation regulations.
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1.
Control parameters
see section 8.2.
Components or products of decomposition according to point 10, with limit values related to the place of work which require monitoring
methyl methacrylate 80-62-6
EH40 WEL Short Term Exposure Limit (STEL): 12 2011 / 416 mg/m3 / 100 ppm
EH40 WEL Time Weighted Average (TWA): 12 2011 / 208 mg/m3 / 50 ppm

8.2.
Exposure controls
For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health

DNEL
Critical component / Routes of exposure / Workers Industry / trade / Note
ethane-1,2-diol dimethacrylate / Inhalation / 2.45 mg/m3 / Long-term - systemic effects
ethane-1,2-diol dimethacrylate / dermal / 1.3 mg/kg bodyweight/day / Long-term - systemic effects

PNEC
Critical component / Routes of exposure / Workers Industry / trade / Note
ethane-1,2-diol dimethacrylate / freshwater / 0.139 mg/l / -
ethane-1,2-diol dimethacrylate / marine water / 0.0139 mg/l / -
ethane-1,2-diol dimethacrylate / Fresh water sediment / 1.6 mg/kg / -
ethane-1,2-diol dimethacrylate / Marine sediment / 0.160 mg/kg / -
ethane-1,2-diol dimethacrylate / Soil / 0.239 mg/kg / -
ethane-1,2-diol dimethacrylate / sewage treatment plant (STP) / 57 mg/l / -

Protective measures:
Do not breathe vapours. Avoid contact with eyes and skin. Do not eat, drink or smoke during use.
Hygiene measures:
Store work clothing separately. Take off all contaminated clothing immediately. Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream.
Respiratory protection:
Breathing apparatus in case of high concentrations, short term: filter appliance, filter A
Hand protection:
Glove material: Nitrile rubber
EN 374
Suitable as spray protection.
Glove material: butyl-rubber
Break through time: 60 min
Glove thickness: 0.3 mm
EN 374
The abovementioned hand protection is based on special knowledge of the chemical and the intended handling of this product, however, it still may not be suited for all workplaces. A qualified hazard assessment should be made prior to the onset of work in order to determine the suitability of gloves for specific working environments and processes.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Eye protection:
tightly fitting goggles
Skin and body protection:
On handling of larger quantities: face mask, chemical-resistant boots and apron

Stability and reactivity

10.1. Reactivity
see section 10.2.
10.2. Chemical stability
No decomposition if used as directed.
10.3. Possibility of hazardous reactions
Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.
10.4. Conditions to avoid
The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.
10.5. Incompatible materials
Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing agents and oxidizing agents. Mineral acids. Free radical initiators.
10.6. Hazardous decomposition products
None when used as directed.

Disposal considerations

Product
Waste is hazardous. It must be disposed of in accordance with the regulations after
consultation of the competent local authorities and the disposal company in a
suitable and licensed facility.

Uncleaned packaging
Contaminated packaging should be emptied optimally and after appropriate
professional cleansing may be taken for reuse. Packaging that cannot be cleaned
should be disposed of professionally. Uncontaminated packaging may be taken for
recycling.

Code of waste
EWC 07 02 08
waste from the manufacture, formulation, supply and use (MFSU) of plastics,
synthetic rubber and man-made fibres - other still bottoms and reaction residues
Always check the given waste codes according to the actual conditions of
manufacturing, formulation or use in your facilities.