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EC number: 200-289-5 | CAS number: 56-81-5
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Repeated dose toxicity: inhalation
Administrative data
- Endpoint:
- sub-chronic toxicity: inhalation
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- not stated
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- other: The study was not conducted according to guideline/s and GLP but the report contains sufficient data for interpretation of study results
Data source
Reference
- Reference Type:
- publication
- Title:
- 2-week and 13-week inhalation studies of aerosolized glycerol in rats
- Author:
- Renne R.
- Year:
- 1 992
- Bibliographic source:
- Inhal Toxicol 4:95-111
Materials and methods
- Principles of method if other than guideline:
- Study design appears to follow intent of OECD 413 but publication does not indicate that OECD 413 was followed.
- GLP compliance:
- not specified
- Limit test:
- no
Test material
- Reference substance name:
- Glycerol
- EC Number:
- 200-289-5
- EC Name:
- Glycerol
- Cas Number:
- 56-81-5
- Molecular formula:
- C3H8O3
- IUPAC Name:
- propane-1,2,3-triol
- Details on test material:
- purity >99.8% USP grade
Constituent 1
Test animals
- Species:
- rat
- Strain:
- Sprague-Dawley
- Sex:
- male/female
- Details on test animals or test system and environmental conditions:
- Rats were obtained from Charles River Breeding Laboratories. Animals were subjected to a 3-week quarantine, health screening five rats of each sex for viral and Mycoplasma infection at the beginning and toward the end of quarantine, physical examinations, body weight measurements, acclimation to the restraining tubes of the nose only exposure system, randomized assignment to exposure groups and individual identification.
Administration / exposure
- Route of administration:
- inhalation: aerosol
- Type of inhalation exposure:
- nose only
- Vehicle:
- air
- Remarks on MMAD:
- MMAD / GSD: MMAD <2.0 um (respirable)
- Details on inhalation exposure:
- A viscous-liquid aerosol generator was used to generate aerosol.
- Analytical verification of doses or concentrations:
- yes
- Details on analytical verification of doses or concentrations:
- ANALYSES: target concentration and homogeneity of aerosol
- Method: sampling with aerosol monitor and gravimetric and GC analyses
- Sampling times: actual concentration 2 samples per exposure chamber; homogeneity and uniformity in mock exposure before start of the experiment (6 samples) and during animal exposure (20 samples/concentration) - Duration of treatment / exposure:
- 6 hours/day
- Frequency of treatment:
- 5 days/week for 13 weeks
Doses / concentrations
- Remarks:
- Doses / Concentrations:
33, 165 and 660 mg/m3
Basis:
nominal conc.
- No. of animals per sex per dose:
- 15/sex/dose level
- Control animals:
- yes, concurrent no treatment
- Details on study design:
- CLINICAL OBSERVATIONS AND FREQUENCY:
- Mortality/clinical signs: twice daily
- Body weight: weekly
- Food consumption: weekly
- Haematology: not specified (complete blood count included)
- Biochemistry: blood urea nitrogen, creatinine, glucose, protein, albumin, albumin/globulin, ASAT, ALAT, LDH, gamma glutamyl transferase, cholesterol, triglycerides and phospholipids
ORGANS EXAMINED AT NECROPSY (MACROSCOPIC AND MICROSCOPIC):
- Organ weights: lungs, liver, kidneys, brain and heart
- Macroscopic: not specified (complete necropsy).
- Microscopic: total of 40 tissues of high dose and control animals; lungs trachea and anterior nasal cavity were stained with hematoxylin and eosin and duplicate slides with Alcian blue/periodic acid Schiff (Goblet cell changes)
Three rats/sex of control and high dose group were killed during week 10, lung lobes were excised and 2 samples/rat were examined by transmission electron microscopy for abnormalities associated with the Clara cells. The same procedure was followed for 3 rats/sex of all groups during terminal necropsy
ANALYSES: target concentration and homogeneity of aerosol
- Method: sampling with aerosol monitor and gravimetric and GC analyses
- Sampling times: actual concentration 2 samples per exposure chamber; homogeneity and uniformity in mock exposure before start of the experiment (6 samples) and during animal exposure (20 samples/concentration) - Positive control:
- No data
Examinations
- Observations and examinations performed and frequency:
- CLINICAL OBSERVATIONS AND FREQUENCY:
- Mortality/clinical signs: twice daily
- Body weight: weekly
- Food consumption: weekly
- Haematology: not specified (complete blood count included)
- Biochemistry: blood urea nitrogen, creatinine, glucose, protein, albumin, albumin/globulin, ASAT, ALAT, LDH, gamma glutamyl transferase, cholesterol, triglycerides and phospholipids - Sacrifice and pathology:
- ORGANS EXAMINED AT NECROPSY (MACROSCOPIC AND MICROSCOPIC):
- Organ weights: lungs, liver, kidneys, brain and heart
- Macroscopic: not specified (complete necropsy)
- Microscopic: total of 40 tissues of high dose and control animals; lungs trachea and anterior nasal cavity were stained with hematoxylin and eosin and duplicate slides with Alcian blue/periodic acid Schiff (Goblet cell changes)
Three rats/sex of control and high dose group were killed during week 10, lung lobes were excised and 2 samples/rat were examined by transmission electron microscopy for abnormalities associated with the Clara cells. The same procedure was followed for 3 rats/sex of all groups during terminal necropsy - Other examinations:
- No additional information available.
- Statistics:
- STATISTICAL METHODS: ANOVA, least significant difference
Results and discussion
Results of examinations
- Clinical signs:
- no effects observed
- Mortality:
- no mortality observed
- Body weight and weight changes:
- no effects observed
- Food consumption and compound intake (if feeding study):
- no effects observed
- Food efficiency:
- not examined
- Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not specified
- Haematological findings:
- no effects observed
- Clinical biochemistry findings:
- effects observed, treatment-related
- Description (incidence and severity):
- triglycerides decreased in males at 33 (34%) and 167 mg/m3 (22%) only.
- Urinalysis findings:
- not specified
- Behaviour (functional findings):
- not specified
- Organ weight findings including organ / body weight ratios:
- no effects observed
- Gross pathological findings:
- no effects observed
- Histopathological findings: non-neoplastic:
- effects observed, treatment-related
- Description (incidence and severity):
- minimal squamous metaplasia of the epiglottis in 2/25, 1/19, 4/20 and 10/21 rats at 0, 33, 167 and 662 mg/m3; 1 male at 662 mg/m3 showed mild squamous metaplasia. No differences in morphology of the Clara cells in control and high dose rats
- Histopathological findings: neoplastic:
- not specified
- Details on results:
- ANALYTICAL ANALYSES:
- Actual dose level: 33, 167 and 662 mg/m3 (100-101% of target)
- Homogeneity (uniformity): relative standard deviation <1% of mean value
- Hematology: No differences between the exposed rats in any group of either sex when compared to their respective control group.
- Clinical chemistry: triglycerides decreased in males at 33 (34%) and 167 mg/m3 (22%) only.
- Gross lesions: few gross lessions observed with no evidence of changes attributed to exposure to glycerol.
- Histopathology: minimal squamous metaplasia of the epiglottis in 2/25, 1/19, 4/20 and 10/21 rats at 0, 33, 167 and 662 mg/m3; 1 male at 662 mg/m3 showed mild squamous metaplasia.
No differences in morphology of the Clara cells in control and high dose rats
STATISTICAL RESULTS: all effects mentioned showed statistical significance (squamous metaplasia only significant at high concentration)
Effect levels
open allclose all
- Dose descriptor:
- NOAEC
- Effect level:
- 662 mg/m³ air (analytical)
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- other:
- Remarks on result:
- not determinable due to absence of adverse toxic effects
- Dose descriptor:
- NOEC
- Effect level:
- 167 mg/m³ air (analytical)
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- other: based on local irritant effects on the upper respiratory tract.
Target system / organ toxicity
- Critical effects observed:
- no
Any other information on results incl. tables
No additional information available.
Applicant's summary and conclusion
- Conclusions:
- Because the metaplasia of the squamous epithelium of the larynx seen in rats at 662 mg/m3 with glycerol aerosol was only minimal to slight, is not interpreted as adverse.
The NOEC of 165 is mg/m3 for local toxicity was based on local irritant effects on the upper respiratory tract.
The NOAEC for local and systemic toxicity is 662 mg/m3. - Executive summary:
The subchronic toxicity of glycerol was examined following aerosol exposure.
Because the metaplasia of the squamous epithelium of the larynx seen in rats at 662 mg/m3 with glycerol aerosol was only minimal to slight, is not interpreted as adverse.
The NOEC of 165 for local toxicity is mg/m3 was based on local irritant effects on the upper respiratory tract.
The NOAEC for local and systemic toxicity is 662 mg/m3.
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