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Physical & Chemical properties

Stability: thermal, sunlight, metals

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Administrative data

Endpoint:
stability: thermal, sunlight, metals, other
Remarks:
Migrated from section 'Stability: thermal, sunlight, metals'
Type of information:
experimental study
Adequacy of study:
other information
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: GLP guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2012
Report date:
2012

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
OECD Guideline 113 (Screening Test for Thermal Stability and Stability in Air)
GLP compliance:
yes (incl. QA statement)

Test material

Constituent 1
Chemical structure
Reference substance name:
Sodium 2-methylpropan-2-olate
EC Number:
212-741-9
EC Name:
Sodium 2-methylpropan-2-olate
Cas Number:
865-48-5
Molecular formula:
C4H10O.Na
IUPAC Name:
sodium 2-methylpropan-2-olate
Details on test material:
- Name of test material (as cited in study report): Na-tert.-8utylat L (PRD 30153329)
- Analytical purity: 98.1 % by 1H-NMR spectroscopy using the internal standard method.
- Lot/batch No.: 35694816K0

Results and discussion

For thermal stability study

Test substance thermally stable:
no
Operating temperature
Operating temp.:
30 - 500 °C
Remarks on result:
other: 1st reaction: onset temperature 300 °C, peak temperature 346 °C, energy release 170 J/g. 2nd reaction: onset temperature 415 °C, peak temperature 490 °C, energy release >200 J/g.

Any other information on results incl. tables

Test parameters
Apparatus: Mettler TA 8000
Sample containers: closed high pressure cell made of V4A
Sample weight: 18.3 mg
Reference material: empty container
Heating rate: 2.5 °C/min
Temperature range: from 30 °C to 500 °C
Results
1st reaction:
Onset temperature: 300 °C
Peak temperature: 346 °C
Energy release: 170 J/g
2nd reaction:
Onset temperature: 415 °C
Peak temperature: 490 °C
Energy release: >200 J/g

Applicant's summary and conclusion