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EC number: 500-035-6 | CAS number: 25214-63-5 (>1 <8.5 mol PO)
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Skin sensitisation
Administrative data
- Endpoint:
- skin sensitisation: in vivo (non-LLNA)
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: Guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 004
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- OECD Guideline 406 (Skin Sensitisation)
- GLP compliance:
- yes
- Type of study:
- guinea pig maximisation test
- Justification for non-LLNA method:
- study performed prior to the implementation of REACH and thus at a time when the LLNA was not the only preferred method for skin sensitising potential assessment.
Test material
- Reference substance name:
- Ethylenediamine, propoxylated
- EC Number:
- 500-035-6
- EC Name:
- Ethylenediamine, propoxylated
- Cas Number:
- 25214-63-5
- Molecular formula:
- (C3H6O)n (C3H60)n (C3H6O)n(C3H6O)n C2H8N2 sum of n: >1 - 8.5
- IUPAC Name:
- Ethylenediamine, propoxylated
- Details on test material:
- Name: Ethylenediamine, propoxylated mw 480 (NLP)
Physical state: clear, yellowish, viscous liquid
Purity: > 99%
Constituent 1
In vivo test system
Test animals
- Species:
- guinea pig
- Sex:
- female
- Details on test animals and environmental conditions:
- TEST ANIMALS: guinea pig
- Strain: Hsd Poc:DH (SPF)
- Sex: female
- Source: Harlan Winkelmann GmbH, Borchen, GER
- Age: about 7 weeks
- Weight at study initiation: 337 g - 363 g
- Number of animals: 10 treated
- Controls: 5 animals
Study design: in vivo (non-LLNA)
Induction
- Route:
- intradermal
- Vehicle:
- physiological saline
Challenge
- Route:
- epicutaneous, occlusive
- Vehicle:
- physiological saline
- No. of animals per dose:
- 15
- Details on study design:
- 1st application: Induction 5 % intracutaneous
2nd application: Induction undiluted occlusive epicutaneous
3rd application: Challenge undiluted occlusive epicutaneous
ADMINISTRATION/EXPOSURE
- Formulation of test substance for induction: 0.9% aqueous NaCl-solution
- Induction schedule: Intradermal induction using adjuvant technique on day 0. Occlusive epicutaneous induction with undiluted TS 7 days thereafter
- Concentration in Freuds Complete Adjuvant (FCA): TS 5% in Freund's adjuvant / 0.9% aqueous NaCl-solution (1:1)
- Challenge schedule: day 21 after untradermal induction
- Concentrations used for challenge: undiluted
- Positive controls: historical data
EXAMINATIONS
- Grading system: scale of Magnusson and Kligman
- Evaluation of skin reactions: The number of animals with skin findings at 24 and/or 48 hours after the removal of the patch was taken into account for the determination of the sensitization rate. The evaluation "sensitizing" results if at least 30 per cent of the test animals exhibit skin reactions in this adjuvant test.
- Pilot study: yes
Results and discussion
In vivo (non-LLNA)
Resultsopen allclose all
- Key result
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- test chemical
- Dose level:
- 0.5 ml of test substance
- No. with + reactions:
- 0
- Total no. in group:
- 9
- Clinical observations:
- One animal from the test group was terminated due to rectal prolaps on study day 9.
- Remarks on result:
- other: see Remark
- Remarks:
- Reading: 1st reading. . Hours after challenge: 24.0. Group: test group. Dose level: 0.5 ml of test substance. No with. + reactions: 0.0. Total no. in groups: 9.0. Clinical observations: One animal from the test group was terminated due to rectal prolaps on study day 9..
- Key result
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- test chemical
- Dose level:
- 0.5 ml of test substance
- No. with + reactions:
- 0
- Total no. in group:
- 9
- Remarks on result:
- other: Reading: 2nd reading. . Hours after challenge: 48.0. Group: test group. Dose level: 0.5 ml of test substance. No with. + reactions: 0.0. Total no. in groups: 9.0.
- Reading:
- 1st reading
- Hours after challenge:
- 24
- Group:
- negative control
- Dose level:
- 0
- No. with + reactions:
- 0
- Total no. in group:
- 5
- Remarks on result:
- other: Reading: 1st reading. . Hours after challenge: 24.0. Group: negative control. Dose level: 0. No with. + reactions: 0.0. Total no. in groups: 5.0.
- Reading:
- 2nd reading
- Hours after challenge:
- 48
- Group:
- negative control
- Dose level:
- 0
- No. with + reactions:
- 0
- Total no. in group:
- 5
- Remarks on result:
- other: Reading: 2nd reading. . Hours after challenge: 48.0. Group: negative control. Dose level: 0. No with. + reactions: 0.0. Total no. in groups: 5.0.
Applicant's summary and conclusion
- Interpretation of results:
- not sensitising
- Remarks:
- Migrated information
- Conclusions:
- There was no evidence that TS caused skin hypersensitivity in the guinea pig, since no responses were observed in the experimental animals following the challenge.
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