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Diss Factsheets
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EC number: 210-478-4 | CAS number: 616-38-6
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Phototransformation in air
Administrative data
- Endpoint:
- phototransformation in air
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: well documented study
Data source
Reference
- Reference Type:
- publication
- Title:
- Atmospheric loss processes of dimethyl and diethyl carbonate.
- Author:
- Katrib Y, Deiber G, Mirabel P, Le Calvé S, George C, Mellouki A, Le Bras G
- Year:
- 2 002
- Bibliographic source:
- J Atmos Chem 43: 151-174 (2002)
Materials and methods
Test guideline
- Qualifier:
- no guideline followed
- Principles of method if other than guideline:
- Absolute rate coefficient data are reported for the OH radical reaction with dimethyl carbonate in the temperature range 263-372K. OH radicals were produced by pulsed laser photolysis of H2O2 at 248 nm. The concentration of OH radicals was monitored at various reaction times ranging from 10 µs to 10 ms by pulsed laser induced fluorescence. A Nd:YAG pumped frequency doubled dye laser was used to probe the OH radical at 282 nm, the subsequent fluorescence was detected by a photomultiplier. The output pulse from the photomultiplier was integrated for a preset period by a gated charge integrator. Typically the fluorescence signal resulting from 100 probe laser shots was measured for 10 to 15 different delay times and averaged to generate OH concentration-time profiles over at least three lifetimes. For the kinetic measurements, carbonate/H2O2 mixtures in helium diluent were flowed slowly through the cell, so that each photolysis/probe sequence interrogated a fresh gas mixture and reaction products did not build up in the cell. All experiments were carried out under pseudo-first-order conditions with [carbonate]>> [OH], the initial concentration of OH being lower than 2 × 10E11 molecule/cm³. The concentrations of the carbonates were calculated from their mass flow rates, temperature and pressure in the reaction cell.
- GLP compliance:
- not specified
Test material
- Reference substance name:
- Dimethyl carbonate
- EC Number:
- 210-478-4
- EC Name:
- Dimethyl carbonate
- Cas Number:
- 616-38-6
- Molecular formula:
- C3H6O3
- IUPAC Name:
- dimethyl carbonate
- Details on test material:
- - Name of test material (as cited in study report): dimethyl carbonate
- Substance type: ester
- Physical state: liquid
- Analytical purity: >99% (obtained from Fluka), further purified by repeated freeze-pump-thaw cycles and fractional distillation
- Impurities (identity and concentrations): not reported
Constituent 1
Study design
- Light source:
- other: laser
- Light spectrum: wavelength in nm:
- 248
- Reference substance:
- no
Results and discussion
% Degradation
- % Degr.:
- 50
- Sampling time:
- 22.9 d
- Test condition:
- 25°C; 1 x 10E6 OH/cm³
Applicant's summary and conclusion
- Validity criteria fulfilled:
- not applicable
- Conclusions:
- Half-lives in the range between 15.3 and 45.8 d can be calculated for the photodegradation of dimethyl carbonate by reaction with OH radicals in dependance of the OH concentration.
- Executive summary:
The OH reaction rate coefficient of dimethyl carbonate was determined using laser photolysis - laser induced fluorescence. Based on the kinetic data a rate coefficient k (OH)=0.35 x 10E-12 cm³/molecule x s was obtained. Taking into account the reaction rate coefficient and OH radical concentrations of 5 x 10E5 OH/cm³ (24 h day) and 1.5 x 10E6 OH/cm³ (12 h day) resulted in half-lives of 45.8 and 15.3 d, respectively. The calculation of the tropospheric half-life using a OH radical concentration of 1 x 10E6 OH/cm³ as cited in this publication yielded a value of 22.9 d.
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