Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

First aider needs to protect himself. Take off all contaminated clothing immediately. Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.
4.1 Description of first aid measures
Move subject to fresh air and keep him calm. In case of discomfort: Supply with medical care.
Skin Contact:
Wash off immediately with soap and water. If skin irritation occurs consult a physician.
Eye contact:
Flush eyes thoroughly with a large amount of water and consult a physician.
Do not induce vomiting. Call a physician immediately.
4.2 Most important symptoms and effects, both acute and delayed:
Sensitization Serious eye irritation
4.3 Indication of any immediate medical attention and special treatment needed
No data available.
Symptomatic treatment.

Fire-fighting measures

5.1 Extinguishing media
Suitable extinguishing media:
foam Dry chemical. Carbon dioxide
Unsuitable extinguishing media:
High volume water jet
5.2 Special hazards arising from the substance or mixture:
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.
5.3 Advice for firefighters
Special fire fighting procedures:
Take precautionary measures against static discharges. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air.
Special protective equipment for fire-fighters:
Wear self-contained breathing apparatus.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:
Assure sufficient ventilation. Use personal protective clothing. Keep away sources of ignition. Use breathing apparatus if exposed to vapours/dust/mist/aerosol. Do not eat, drink or smoke when using this product. Wash hands thoroughly with soap and water after handling.
6.1.1 For non-emergency personnel:
No data available.
6.1.2 For emergency responders:
No data available.
6.2 Environmental Precautions:
Prevent product from getting into drains/surface water/groundwater.
6.3 Methods and material for containment and cleaning up:
Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment! Smaller quantities and/or residues: Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust). Dispose of in accordance with regulations.
6.4 Reference to other sections:
For personal protection see section 8. For disposal considerations see section 13.

Handling and storage

7.1 Precautions for safe handling:
Do not breathe vapors. Avoid contact with skin and eyes. When using do not eat, drink or smoke. Take precautionary measures against static discharges. In the event of fire, cool the endangered containers with water. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air. Keep container tightly closed. Ensure there is good room ventilation.
7.2 Conditions for safe storage, including any incompatibilities:
Protect from the action of light. Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability.Keep only in the original container at a temperature not exceeding 30 °C.Can polymerize with intense heat release.
7.3 Specific end use(s):
We are unaware of any specific end uses which go beyond the data reported in Section 1.

Transport information

Land transport (ADR/RID)

Shippingopen allclose all
Not dangerous according to transport regulations.

Inland waterway transport (ADN(R))

Shippingopen allclose all
Not dangerous according to transport regulations.

Marine transport (IMDG)

Not dangerous according to transport regulations.

Air transport ICAO/IATA

Not dangerous according to transport regulations.

Additional transport information

Additional transport information
Further information
Not a dangerous good within the meaning of transportation regulations.

Exposure controls / personal protection

8.1. Control parameters
see section 8.2.

8.2. Exposure controls
For monitoring procedures refer to for instance "Empfohlene Analysenverfahren für
Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and
"NIOSH Manual of Analytical Methods", National Institute for Occupational Safety
and Health.

Critical component Routes of exposure Workers Industry / trade Note
hydroxypropyl methacrylate Inhalation 14.7 mg/m3
hydroxypropyl methacrylate dermal 4.2 mg/kg/d

Critical component Routes of exposure Workers Industry / trade Note
hydroxypropyl methacrylate Freshwater 0.904 mg/l
hydroxypropyl methacrylate Fresh water sediment 6.28 mg/kg
hydroxypropyl methacrylate Soil 0.727 mg/kg
hydroxypropyl methacrylate sewage treatment plant (STP) 10 mg/l

Individual protection measures, such as personal protective equipment
Eye/face protection:
tightly fitting goggles
Hand Protection:
Material: nitrile rubber gloves
Additional Information: Suitable as spray protection.
Material: butyl rubber gloves (minimal thickness 0.3 mm)
Break-through time: 480 min
Guideline: EN 374
Additional Information: Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time., The above mentioned hand protection is based on special knowledge of the chemical and the intended handling of this product, however, it still may not be suited for all workplaces. A qualified hazard assessment should be made prior to the onset of work in order to determine the suitability of gloves for specific working environments and processes., Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.
Skin and Body Protection:
On handling of larger quantities: face mask, chemical-resistant boots and apron
Respiratory Protection:
Breathing apparatus in case of high concentrations short term: filter appliance, filter A
Hygiene measures:
Store work clothing separately. Take off all contaminated clothing immediately. Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream.
Environmental Controls:
see section 6.

Stability and reactivity

10.1 Reactivity:
No data available.
10.2 Chemical Stability:
No decomposition if used as directed.
10.3 Possibility of hazardous reactions:
Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.
10.4 Conditions to avoid:
The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.
10.5 Incompatible Materials:
Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing agents and oxidizing agents. Free radical initiators. Mineral Acid
10.6 Hazardous Decomposition Products:
None when used as directed.

Disposal considerations

13.1 Waste treatment methods
General information:
Dispose of waste and residues in accordance with local authority requirements.
Disposal methods:
Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the disposal company in a suitable and licensed facility. Strictly controlled conditions during disposal or treatment to air, wastewater and waste. Do not add wastewater to a biological wastewater treatment plant Bring wastewater containing AOX for professional disposal. The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Contaminated Packaging:
Contaminated packaging should ideally be emptied; it can then be recycled after having been decontaminated. Packaging that cannot be cleaned should be disposed of professionally. Uncontaminated packaging may be taken for recycling.