Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

Description of first aid measures
Immediately remove contaminated clothing.

If inhaled:
If difficulties occur after dust has been inhaled, remove to fresh air and seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.

Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see
section 2) and/or in section 11 of the SDS. Further important symptoms and effects are so far not known.

Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media:
dry powder, foam

Unsuitable extinguishing media for safety reasons:
carbon dioxide

Additional information:
Avoid whirling up the material/product because of the danger of dust explosion.

Special hazards arising from the substance or mixture
harmful vapours
Evolution of fumes/fog. The substances/groups of substances mentioned can be released in case of
fire.

Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.

Further information:
The degree of risk is governed by the burning substance and the fire conditions. Contaminated
extinguishing water must be disposed of in accordance with official regulations.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Use personal protective clothing.

Environmental precautions
Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.

Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Contain with dust binding material and dispose of.
Avoid raising dust.

Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13 of the SDS.

Handling and storage

Precautions for safe handling
Breathing must be protected when large quantities are decanted without local exhaust ventilation.

Protection against fire and explosion:
Avoid dust formation. Take precautionary measures against static discharges.

Dust explosion class: Dust explosion class 3 (Kst-value >300 bar m s-1).

Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container tightly closed and dry; store in a cool place.

Transport information

Land transport (ADR/RID)

UN number:
3077
Shippingopen allclose all
Class:
9
Packaging group:
III
Labels:
9, EHSM
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Shippingopen allclose all
Class:
9
Packaging group:
III
Labels:
9, EHSM
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains 2-BENZYL-2-DIMETHYLAMINO-4-MORPHOLINOBUTYROPHENONE)
Chemical name:
2-BENZYL-2-DIMETHYLAMINO-4-MORPHOLINOBUTYROPHENONE
Class:
9
Packaging group:
III
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(contains 2-BENZYL-2-DIMETHYLAMINO-4-MORPHOLINOBUTYROPHENONE)
Chemical name:
2-BENZYL-2-DIMETHYLAMINO-4-MORPHOLINOBUTYROPHENONE
Class:
9
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters
Components with workplace control parameters
none

Exposure controls
Personal protective equipment
Respiratory protection:
Suitable respiratory protection for lower concentrations or short-term effect: Particle filter with medium
efficiency for solid and liquid particles (e.g. EN 143 or 149, Type P2 or FFP2)

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
e.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), polyvinylchloride (0.7 mm) and other
Supplementary note: The specifications are based on tests, literature data and information of glove
manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g.
temperature) it must be considered, that the practical usage of a chemical-protective glove in practice
may be much shorter than the permeation time determined through testing.
Manufacturer's directions for use should be observed because of great diversity of types.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of
dust).

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is required additionally to the stated personal protection equipment.

Stability and reactivity

Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Chemical stability
The product is stable if stored and handled as prescribed/indicated.

Possibility of hazardous reactions
Dust explosion hazard.

Conditions to avoid
Avoid electro-static discharge. Avoid light.

Incompatible materials
Substances to avoid:
strong acids, strong bases, strong oxidizing agents

Hazardous decomposition products:
No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

Waste treatment methods
Must be disposed of or incinerated in accordance with local regulations.

Contaminated packaging:
Uncontaminated packaging can be re-used.
Packs that cannot be cleaned should be disposed of in the same manner as the contents.