Registration Dossier
Registration Dossier
Data platform availability banner - registered substances factsheets
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Diss Factsheets
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 202-411-2 | CAS number: 95-33-0
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Repeated dose toxicity: oral
Administrative data
- Endpoint:
- short-term repeated dose toxicity: oral
- Type of information:
- experimental study
- Adequacy of study:
- supporting study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- guideline study without detailed documentation
Data source
Reference
- Reference Type:
- publication
- Title:
- Unnamed
- Year:
- 1 997
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- equivalent or similar to guideline
- Guideline:
- OECD Guideline 407 (Repeated Dose 28-Day Oral Toxicity Study in Rodents)
- Qualifier:
- according to guideline
- Guideline:
- other: Guidelines for 28-day repeated dose toxicity testing of chemicals (Japan)
- Deviations:
- no
- Principles of method if other than guideline:
- N-cyclohexyl-2-benzothiazolesulfenamide was studied for oral toxicity in rats in a 28-day repeat dose toxicity test at doses of 0, 25, 80, 250 or 800 mg/kg bw/day.
- GLP compliance:
- yes
- Limit test:
- no
Test material
- Reference substance name:
- N-cyclohexylbenzothiazole-2-sulfenamide
- EC Number:
- 202-411-2
- EC Name:
- N-cyclohexylbenzothiazole-2-sulfenamide
- Cas Number:
- 95-33-0
- Molecular formula:
- C13H16N2S2
- IUPAC Name:
- N-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine
- Test material form:
- solid: granular
- Remarks:
- greyish white
- Details on test material:
- Purity: 98.8 %
Constituent 1
Test animals
- Species:
- rat
- Strain:
- Crj: CD(SD)
- Sex:
- male/female
Administration / exposure
- Route of administration:
- oral: gavage
- Vehicle:
- other: sesame oil
- Duration of treatment / exposure:
- 28 days
- Frequency of treatment:
- daily
Doses / concentrationsopen allclose all
- Dose / conc.:
- 0 mg/kg bw/day (nominal)
- Remarks:
- Vehicle control
- Dose / conc.:
- 25 mg/kg bw/day (nominal)
- Dose / conc.:
- 80 mg/kg bw/day (nominal)
- Dose / conc.:
- 250 mg/kg bw/day (nominal)
- Dose / conc.:
- 800 mg/kg bw/day (nominal)
- No. of animals per sex per dose:
- Six per dose and sex.
- Control animals:
- yes, concurrent vehicle
- Details on study design:
- Exposure period: 28 days
Post-exposure period: with and without 14 days recovery period
Examinations
- Observations and examinations performed and frequency:
- Signs of general condition,food consumption, body weight gain, Hematoloty, urinalysis
- Sacrifice and pathology:
- Organs weights, histopathological examination.
Results and discussion
Results of examinations
- Clinical signs:
- effects observed, treatment-related
- Description (incidence and severity):
- Signs of loss of general condition like piloerection and soiled fur were observed in females of the 800 mg/kg bw group.
- Mortality:
- no mortality observed
- Description (incidence):
- All animals survived until the end of the study.
- Body weight and weight changes:
- effects observed, treatment-related
- Description (incidence and severity):
- Suppression of food consumption and body weight gain was noted in females of the 250 mg/kg group and males and females of the 800 mg/kg bw group.
- Food consumption and compound intake (if feeding study):
- effects observed, treatment-related
- Description (incidence and severity):
- Suppression of food consumption and body weight gain was noted in females of the 250 mg/kg group and males and females of the 800 mg/kg bw group.
- Food efficiency:
- not specified
- Water consumption and compound intake (if drinking water study):
- not specified
- Ophthalmological findings:
- not examined
- Haematological findings:
- effects observed, treatment-related
- Description (incidence and severity):
- Shortening of prothrombin time in males of the 250 and 800 mg/kg bw groups.
Decreased hematocrit, reticulocyte count and platelet count in females of the 800 mg/kg bw group. - Clinical biochemistry findings:
- effects observed, treatment-related
- Description (incidence and severity):
- Total protein content was decreased in males of the 250 and 800 mg/kg bw groups.
Chloride levels were reduced in males and females of the 800 mg/kg-group. Calcium level was elevated and sodiumlevel reduced in females of the 800 mg/kg bw group. - Urinalysis findings:
- effects observed, treatment-related
- Description (incidence and severity):
- Increase of ketone bodies in males of 250 and 800 mg/kg bw groups.
- Behaviour (functional findings):
- not examined
- Immunological findings:
- not examined
- Organ weight findings including organ / body weight ratios:
- effects observed, treatment-related
- Gross pathological findings:
- effects observed, treatment-related
- Description (incidence and severity):
- Distended cecum in females of the 800 mg/kg bw group. Increased relative kidney weights in males and females of the 800 mg/kg bw group.
- Neuropathological findings:
- not examined
- Histopathological findings: non-neoplastic:
- effects observed, treatment-related
- Description (incidence and severity):
- Increased deposition of hyaline droplets in the renal proximal tubular epithelium in males of the 250 and 800 mg/kg w groups. After the 14 days recovery the histopathological changes in the kidneys tended to recover and the other substance-related changes had disappeared.
- Histopathological findings: neoplastic:
- not examined
Effect levels
open allclose all
- Key result
- Dose descriptor:
- NOAEL
- Effect level:
- 80 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- male/female
- Basis for effect level:
- other: based on signs of coagulopathy and kidney adversity in male rats, suppression of food consumption and body weight gain in female rats
- Key result
- Dose descriptor:
- LOAEL
- Effect level:
- 250 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- male
- Basis for effect level:
- haematology
- histopathology: non-neoplastic
- Key result
- Dose descriptor:
- LOAEL
- Effect level:
- 250 mg/kg bw/day (nominal)
- Based on:
- test mat.
- Sex:
- female
- Basis for effect level:
- body weight and weight gain
Any other information on results incl. tables
All animals survived until the end of the study.
Males:
25, 80 mg/kg bw: no adverse effects (decrease of GPT* at 25, and 80 mg/kg bw)
250 mg/kg bw: increase of ketone bodies, shortening of the prothrombin time, on blood chemical examination: total protein was decreased,
Histopathology: an increase in deposition of hyaline droplets in the renal proximal tubular epithelium.
800 mg/kg bw: Suppression of food consumption and body weight gain, urin analysis revealted an increase of ketone bodies,shortening of the prothrombin time,on blood chemical examination: total protein was decreased, reduced chloride levels,
Histopathology: an increase in deposition of hyaline droplets in the renal proximal tubular epithelium, increase of the relative kidney weights
No abnormalities were detected in: pancreas, stomach, small intestine, large intestine, thyroid, parathyroid, spleen, lymph node, bone marrow or brain, 1/6 males of the 800 mg/kg bw group + 14 d recovery showed a moderate effect on the testis (atrophy, seminiferous tubule, diffuse).
Females
25,80 mg/kg bw: no adverse effects (decrease of GPT* at 80 mg/kg bw)
250 mg/kg bw: Suppresion of food consumption and body weight gain
800 mg/kg bw: Clinical signs:signs of loss of general conditions like piloerection and soiled fur;
Supression of food consumption and body weight gain; hematology findings: decrease in the hematocrit value, reticulocyte count and platelet count; reduced chlorid levels, calcium elevated and sodium reduced.
Necropsy: cecum was distended;increase in relative kidney weights
No abnormalities were detected: heart, pancreas, stomach, small intestine, large intestine, urinary bladder, ovary, pituitary, thyroid, parathyroid, spleen, lymph node, bone marrow or brain
Remarks: Histopathological changes in the kidney tended to recover and the other changes related to the test substance disappeared after 14 -day recovery period.
The authors consider: NOAEL: 80 mg/kg bw/day for both sexes
*GPT: serum glutamic pyruvic transaminase (synonym: alanine aminotransferase ALAT).
Applicant's summary and conclusion
- Conclusions:
- No relevant systemic toxic effects were observed in male and female rats after repeated oral administration of 80 mg/kg bw and day CBS. A NOAEL of 80 mg/kg bw/day was assigned for both sexes based on signs of a coagulopathy and adverse effects in the kidney of male rats, suppression of food consumption and body weight gain in female rats (MHWJ 1997).
- Executive summary:
Study design
The test substance CBS was evaluated in a subacute gavage study with Crj: CD (SD) rats, which was performed mostly in accordance to regulation requirements (mostly according to OECD TG 407) (MHWJ 1997). Male and female rats (6 per dose and sex) were administered with 0, 25, 80, 250 and 800 mg/kg bw/day for 28 days and were scarified on day 29. Another control and 800 mg/kg bw/day group were treated for 28 days and then kept for a recovery period of 14 days before sacrifice on day 43. In this study data on haematology, clinical biochemistry, organ weights and incidences of histopathological findings were provided.
Results
No mortality occurred during the study period. After administration of 800 mg/kg bw/day signs associated with loss of general condition like piloerection and solid fur were observed in female rats. Suppression of food consumption and body weight gain was observed in females given ≥250 mg/kg bw/day (significant p=0.01 at 800 mg/kg bw/day) and in males at 800 mg/kg bw/day.
Hematology revealed statistically significant shortening of the prothrombin time in males given = 250 mg/kg bw/day, and statistically significant decrease in hematocrit value, reticulocyte count and platelet count for the 800 mg/kg bw/day females.
Clinical biochemistry revealed statistically significant decreases in alanine aminotransferase (ALAT) for males of all CBS treated groups and for females given ≥ 80 mg/kg bw/day, in total protein for males treated at ≥ 250 mg/kg bw and day, in chloride levels in males and females at 800 mg/kg bw and day and in sodium levels in females at 800 mg/kg bw/day. In addition, calcium concentration was elevated in females at the 800 mg/kg bw/day dose group.
Urinalysis revealed an increase of ketone bodies in males ≥ 250 mg/kg bw/day.
The statistically significant increase in relative kidney weights in the 800 mg/kg bw/day in males was considered to be associated with an increase in deposition of hyaline droplets in the proximal tubular epithelium of the kidneys in male rats evident at 250 and 800 mg/kg bw/day. This effect in male kidney showed a clear tendency towards reversibility. All other changes were completely reversible after the 14 day recovery period.
Conclusion
In summary, CBS-related effects were present in male and females Crj: CD (SD) rats at = 250 mg/kg bw/day. There were signs of coagulopathy of the blood in both sexes and effects in the kidney of male rats. No relevant systemic toxic effects were observed in male and female rats after repeated oral administration of 80 mg/kg bw and day CBS. Based on these findings, the author considered a NOAEL of 80 mg/kg bw/day appropriate for both sexes (MHWJ 1997).
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.