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Diss Factsheets

Environmental fate & pathways

Biodegradation in water: screening tests

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Administrative data

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Description of key information

Production: production of sodium sulfate is 4.6 million tonnes/year (1999), of which approximately 50% a by product of the chemical industry


and the remainder is extracted from natural deposits. Due to Sodium sulphate occurring naturally it can be considered to form part of the sulfur cycle. It is readily utilized by bacteria fungi and many aerobic and anaerobic prokaryotic species. For this reason no specific biodegradation tests are  


required. A summary of the potential pathways involved in the cycle of sodium sulphate are shown below. Reference (OECD SIDS 2005)  (The sulphur Cycle Microbiology Prescott Harley and Klein 1996) (College of Biological sciences 1993)

Key value for chemical safety assessment

Additional information

Microbes play pivotal roles in the Sulfur cycle. In the case of sulfate:


 


Sulfate provides microorganisms with the possibility of carrying out sulfate reduction to derive their energy. Sulfate is used as an electron acceptor to form sulfide (H2S) this is a process known as dissimilatory reduction and this occurs anaerobically. Alternatively reduction of sulphate for use in amino acid syntheses for example can also occur and is known as assmilatory reduction forming organic sulfur. Other microorganisms reduce the elemental sulpher further still. Sulphite is also a critical intermediate that can be reduced to sulfide as well as oxidized back to sulphate completing the cycle.


 


Some Species commonly associated with these steps are:


 


Aerobic sulfur oxidation - occurs in Thiobacillus Beggiatoa and Thiothrix sp


Anaerobic sulfur oxidation - occurs in Chlorobium and Chromatum and Desulfovibria sp


Sulfur reduction - occurs in Alteromonas,Clostridium sp


 


 


Summary written using data obtained from (The sulphur Cycle Microbiology Prescott Harley and Klein 1996)


A schematic representation of the sulfur cycle can be found on (http://www.lenntech.com/sulfur-cycle.htm).