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Diss Factsheets

Physical & Chemical properties

Nanomaterial specific surface area

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Administrative data

Endpoint:
nanomaterial specific surface area
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
data from handbook or collection of data

Data source

Referenceopen allclose all

Reference Type:
publication
Title:
The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses: Structure, Properties, Reactions, Occurences and Uses
Author:
Schwertmann U, Cornell RM
Year:
2003
Bibliographic source:
Verlag: Wiley-VCH; Auflage: 2., vollst. überarb. u. erw. Aufl. (29. Juli 2003); Sprache: Englisch; ISBN-10: 3527302743; ISBN-13: 978-3527302741
Reference Type:
other company data
Title:
Unnamed
Year:
2015

Materials and methods

Principles of method if other than guideline:
BET measurements (Brunauer, Emmett und Teller)
XRD line broadening techniques

Test material

Constituent 1
Chemical structure
Reference substance name:
Diiron trioxide
EC Number:
215-168-2
EC Name:
Diiron trioxide
Cas Number:
1309-37-1
Molecular formula:
Fe2O3
IUPAC Name:
diiron(3+) trioxidandiide
Test material form:
solid: nanoform
Details on test material:
no details given;

Results and discussion

Specific surface area
Specific Surface Area:
151 m²/g
Remarks on result:
other: A maximum surface area of 151 m²/g is reported.

Any other information on results incl. tables

During dehydroxylation, the surface area of goethite [FeO(OH)] usually rises initially as the expulsion of water leads to the progressive formation of slit-shaped micropores and finally rapidly upon heating above 300 -350°C as the micropores are transformed into mesopores and sintering takes place. It is reported that a maximum in surface area of 151 m²/g was reached after heating a natural goethite sample for 2 hr at 300°C in vacuo. Similar abservations have been recorded for synthetic samples heated in air. The transformation to hematite at this stage is almost complete.

Applicant's summary and conclusion

Conclusions:
The specific surface area of iron oxide pigments differs in dependence of the grade. The range is between 2 m²/g and about 20 m²/g.