Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

Inhalation: Get medical attention immediately. Move exposed person to fresh
air. If it is suspected that fumes are still present, the rescuer
should wear an appropriate mask or self-contained breathing
apparatus. Keep person warm and at rest. If not breathing, if
breathing is irregular or if respiratory arrest occurs, provide artificial
respiration or oxygen by trained personnel. It may be dangerous to
the person providing aid to give mouth-to-mouth resuscitation. If
unconscious, place in recovery position and get medical attention
immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Ingestion: Make the patient drink a large quantity of water. Wash out mouth with water. Do not induce vomiting
unless directed to do so by medical personnel. Get medical
attention immediately.
Skin contact: Wash skin immediately with plenty of water and soap. Remove contaminated clothes and shoes.
Get medical attention immediately.
Eye contact: Get medical attention immediately. Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact
lenses. Continue to rinse for at least 15 minutes.
Notes to physician: Symptomatic treatment

Fire-fighting measures

Extinguishing media
Suitable extinguishing media: In case of fire foam, dry chemical or CO2.
Unsuitable extinguishing media: Water
Special hazards arising from the substance or mixture: Flammable liquid
Advice for firefighters
Special precautions for fire-fighters: Promptly isolate the scene by removing all persons from the
vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and selfcontained
breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without
suitable training. Evacuate surrounding areas. Keep unnecessary
and unprotected personnel from entering. Do not touch or walk
through spilt material. Avoid breathing vapour or mist. Provide adequate ventilation. Put on appropriate personal protective equipment.
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if
the product has caused environmental pollution (sewers, waterways, soil or air.)
Methods and materials for containment and cleaning up
Small spill: Stop leak if without risk. Move containers from spill area. Absorb with an inert dry
material and place in an appropriate waste disposal container.
Dispose of via a licensed waste disposal contractor.
Large spill: Stop leak if without risk. Move containers from spill area. Prevent
entry into sewers, water courses, basements or confined areas.
Contain and collect spillage with non-combustible, absorbent
material e.g. sand, earth, vermiculite or diatomaceous earth and
place in container for disposal according to local regulations. Dispose of via a licensed waste disposal contractor.
Contaminated absorbent material may pose the same hazard as
the spilt product.

Handling and storage

Manufacture and use of this chemical intermediate takes place under strictly controlled conditions, as described in Art. 17/18 REACH. The substance is rigorously contained during manufacturing and use and appropriate risk management measures including PPE (i.g. during charging or sampling) are applied. Occupational exposure is reduced to a minimum and well controlled by measurements. A management system covering all general aspects of a chemical production is in place, especially cleaning and maintenance of plants and equipment. An authorisation scheme based on instructions covering the whole process ensures that only trained and authorised staff handles the substance.
Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Workers should
wash hands and face before eating, drinking and smoking. Do not
get in eyes or on skin or clothing. Do not breathe vapour or mist. Do
not ingest. Use only with adequate ventilation. Wear appropriate
respirator when ventilation is inadequate. Keep in the original
container or an approved alternative made from a compatible
material, kept tightly closed when not in use. Empty containers
retain product residue and can be hazardous. The product is
registered with strictly controlled conditions as defined in Article 17
(3) or 18(4) of regulation (EC) no. 1907/2006 (REACH Regulation)
and must therefore be handled as such. Refer to the industry
guidance prepared by Concawe/Cefic/EFCG for advice on the
confirmation of strictly controlled conditions.
Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Store in original
container protected from direct sunlight in a dry, cool and wellventilated
area, away from incompatible materials and food and drink. Keep container tightly closed and sealed until
ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in
unlabelled containers. Use appropriate containment to avoid environmental contamination.

Transport information

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Marine transport (UN RTDG/IMDG)

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Exposure controls / personal protection

Control parameters
Exposure limit values: Not available
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.
Exposure controls
Risk management measures
Occupational exposure controls
Technical measures: Use only with adequate ventilation. The substance shall be
rigorously contained by technical means during its whole lifecycle
including manufacture, purification, cleaning and maintenance of
equipment, sampling, analysis, loading and unloading of
equipment or vessels, waste disposal or purification and storage.
Procedural and control technologies shall be used that minimise
emission and any resulting exposure. In cases of accident and
where waste is generated, procedural and/or control technologies
shall be used to minimise emissions and the resulting exposure
during purification or cleaning and maintenance procedures.
Organisational measures: Only properly trained and authorised personnel shall handle the
substance. In the case of cleaning and maintenance works,
special procedures such as purging and washing shall be applied before the system is opened and entered.
Personal protection measures
Respiratory protection: If exposure cannot be ruled out, e.g. during product transfer,
sampling or maintenance, a well-fitting respiratory mask
conforming to standards or well-fitting respiratory device
conforming to standards must be worn. Respirator selection must
be based on known or anticipated exposure levels, the hazards of
the product and the safe working limits of the selected respirator.
Wear breathing apparatus with separate air supply (compressed air respirator, tube apparatus) at higher concentrations.
Hand protection: Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if product contact cannot be excluded. After
contamination with product change the gloves immediately and
dispose of them according to relevant national and local
regulations
Eye protection: Safety eyewear complying with an approved standard should be
used to avoid exposure to liquid splashes, mists, gases or dusts.
Skin protection: Wear protective clothing. Personal protective equipment for the
body should be selected based on the task being performed and
the risks involved and should be approved by a specialist before
handling this product.
Recommended: Wear protective clothing.
Hygiene measures: Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the lavatory
and at the end of the working period. Appropriate techniques
should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash
stations and safety showers are close to the workstation location.
Environmental exposure controls: Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, special waste
water treatment, fume scrubbers, filters or engineering
modifications to the process equipment will be necessary to reduce
emissions to acceptable levels.

Stability and reactivity

Reactivity: No specific test data related to reactivity available for this product or its ingredients.
Chemical stability: The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid: Contact with humid air or water
Hazardous thermal decomposition products : Carbon dioxide. ,
carbon monoxide , Hydrogen chloride, sulfur oxides
Incompatible materials: strong bases and oxidizing agents.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous
decomposition products should not be produced.

Disposal considerations

Waste treatment methods
Product
Methods of disposal: Examine possibilities for re-utilisation. Product residues and
uncleaned empty containers should be packaged, sealed, labelled,
and disposed of or recycled according to relevant national and
local regulations. Where large quantities are concerned, consult
the supplier. When uncleaned empty containers are passed on,
the recipient must be warned of any possible hazard that may be
caused by residues. For disposal within the EC, the appropriate
code according to the European Waste List (EWL) should be used.
It is among the tasks of the polluter to assign the waste to waste
codes specific to industrial sectors and processes according to the European Waste List (EWL).
Hazardous waste: The classification of the product may meet the criteria for a hazardous waste.
Packaging
Methods of disposal: The generation of waste should be avoided or minimised wherever
possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.

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