Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

Description of first aid measures
In case of inhalation: Move victim to fresh air. Seek medical treatment in case of troubles.
Following skin contact: Immediately wipe affected skin area with paper towel or cloth.
Thoroughly wash skin with soap and water. In case of skin irritation, consult a physician.
After eye contact: Immediately flush eyes with plenty of flowing water for 10 to 15 minutes holding eyelids
apart. In case of troubles or persistent symptoms, consult an opthalmologist.
After swallowing: Never give an unconscious person anything through the mouth. Rinse mouth with water.
Consult physician immediately.

Most important symptoms and effects, both acute and delayed
Causes skin irritation. May cause sensitization by skin contact.

Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media:
Foam, extinguishing powder, water fog, carbon dioxide.

Extinguishing media which must not be used for safety reasons:
Full water jet

Special hazards arising from the substance or mixture
Combustible.
In case of fire may be liberated: silicon dioxide, traces of incompletely burned carbon
compounds, carbon monoxide and carbon dioxide.

Advice for firefighters
Special protective equipment for firefighters:
Wear self-contained breathing apparatus. Wear appropriate protective equipment.
Additional information: Hazchem-Code: •3Z
Cool endangered containers with water spray and, if possible, remove from danger zone.
Use water spray jet to knock down vapours. Do not breathe fumes. Do not allow water
used to extinguish fire to enter drains, ground or waterways.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Eliminate all ignition sources if safe to do so. Avoid contact with skin, eyes, and clothing.
Do not breathe vapours. Wear appropriate protective equipment. Provide adequate
ventilation.

Environmental precautions
Do not allow to penetrate into soil, waterbodies or drains.

Methods and material for containment and cleaning up
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal
binding agents) and place in closed containers for disposal. Final cleaning.
Additional information: Special danger of slipping by leaking/spilling product.

Handling and storage

Precautions for safe handling
Advices on safe handling: Provide adequate ventilation. Avoid contact with skin, eyes, and clothing. Do not breathe
vapours. Wear appropriate protective equipment. When using do not eat, drink or smoke.
Precautions against fire and explosion:
Usual measures for fire prevention.

Conditions for safe storage, including any incompatibilities
Requirements for storerooms and containers:
Keep container tightly closed in a cool, well-ventilated place.
Keep away from heat sources, sparks and open flames.
Store containers in upright position. Do not drop, drag or bang the container.
Do not re-use the empty container. Do not weld.
Protect from moisture contamination.
Hints on joint storage: Keep away from food, drink and animal feedingstuffs.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
3082
Shipping information
Proper shipping name and description:
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Triisopropyl acrylate)
Chemical name:
Triisopropyl acrylate
Language:
English
Labels:
class 9
dead fish dead tree
Special provisions / remarks
Special provisions:
274
335
601

Inland waterway transport (UN RTDG/ADN(R))

UN number:
3082
Shipping information
Proper shipping name and description:
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Triisopropyl acrylate)
Chemical name:
Triisopropyl acrylate
Language:
English
Labels:
class 9
dead fish dead tree
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
3082
Shipping information
Proper shipping name and description:
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Triisopropyl acrylate)
Chemical name:
Triisopropyl acrylate
Labels:
class 9
dead fish dead tree
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
3082
Shipping information
Proper shipping name and description:
UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Triisopropyl acrylate)
Chemical name:
Triisopropyl acrylate
Labels:
class 9
dead fish dead tree
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls
Provide for good room ventilation, suctioning/venting.

Personal protection equipment
Occupational exposure controls
Respiratory protection: Use a breathing protection against vapours/aerosol.
Use filter type A (= against vapours of organic substances) according to EN 14387.
Hand protection: Protective gloves according to EN 374.
Butyl caoutchouc (butyl rubber) (0.7 mm).
Breakthrough time: >480 min.
Observe glove manufacturer's instructions concerning penetrability and breakthrough time.
Eye protection: Tightly sealed goggles according to EN 166.
Body protection: Wear suitable protective clothing.
General protection and hygiene measures:
Avoid contact with skin, eyes, and clothing. Change contaminated clothing.
Do not breathe vapours. Work place should be equipped with a shower and an eye rinsing
apparatus.
Wash hands before breaks and after work.

Stability and reactivity

Reactivity
With exposure to humidity, product will release acrylic acid.
Vapours can form explosive mixtures with air.

Chemical stability
Stable under recommended storage conditions.

Possibility of hazardous reactions
No dangerous reactions with proper and specified storage and handling

Conditions to avoid
Keep away from heat. Protect from moisture contamination.

Incompatible materials
Water

Hazardous decomposition products
In case of strong heating / In case of fire may be liberated: silicon dioxide, traces of incompletely burned carbon compounds, carbon monoxide and carbon dioxide.
Thermal decomposition: 180 °C

Disposal considerations

13.1 Waste treatment methods
Product
Waste key number: 07 02 16* = Waste containing hazardous silicones
* = Evidence for disposal must be provided.
Recommendation: Incinerate as hazardous waste according to applicable local, state, and federal regulations.
Contaminated packaging
Waste key number: 15 01 04 = Metallic packaging.
Recommendation: Do not re-use the empty container.
Dispose of waste according to applicable legislation.