Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

Inhalation: Move exposed person to fresh air. Keep person warm and at rest.
If not breathing, if breathing is irregular or if respiratory arrest occurs,
provide artificial respiration or oxygen by trained personnel. It may
be dangerous to the person providing aid to give mouth-to-mouth
resuscitation. Get medical attention if adverse health effects persist
or are severe. If unconscious, place in recovery position and get
medical attention immediately. Maintain an open airway. Loosen
tight clothing such as a collar, tie, belt or waistband.
Ingestion: Wash out mouth with water. Move exposed person to fresh air.
Keep person warm and at rest. If material has been swallowed and
the exposed person is conscious, give small quantities of water to
drink. Stop if the exposed person feels sick as vomiting may be
dangerous. Do not induce vomiting unless directed to do so by
medical personnel. If vomiting occurs, the head should be kept low
so that vomit does not enter the lungs. Get medical attention if
adverse health effects persist or are severe. Never give anything by
mouth to an unconscious person. If unconscious, place in recovery
position and get medical attention immediately. Maintain an open
airway. Loosen tight clothing such as a collar, tie, belt or waistband.
Skin contact: Wash contaminated skin with soap and water. Remove
contaminated clothing and shoes. Continue to rinse for at least 10
minutes. Get medical attention. Wash clothing before reuse.
Clean shoes thoroughly before reuse.
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the
upper and lower eyelids. Check for and remove any contact lenses.
Continue to rinse for at least 10 minutes. Get medical attention if
irritation occurs.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media: In case of fire, use water spray (fog), foam, dry chemical or CO2.
Unsuitable extinguishing media: None known.
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: No specific fire or explosion hazard.
Hazardous combustion products: No specific data.
Advice for firefighters
Special precautions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity
of the incident if there is a fire. No action shall be taken involving
any personal risk or without suitable training. This material is very
toxic to aquatic organisms. Fire water contaminated with this
material must be contained and prevented from being discharged to
any waterway, sewer or drain.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and selfcontained
breathing apparatus (SCBA) with a full face-piece
operated in positive pressure mode.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: No action shall be taken involving any personal risk or without
suitable training. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilt material. Provide
adequate ventilation. Put on appropriate personal protective equipment.
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil,
waterways, drains and sewers. Inform the relevant authorities if the
product has caused environmental pollution (sewers, waterways, soil
or air). Very toxic to aquatic organisms.
Methods and material for containment and cleaning up
Small spill: Move containers from spill area. Vacuum or sweep up material and
place in a designated, labelled waste container. Dispose of via a
licensed waste disposal contractor.
Large spill: Move containers from spill area. Prevent entry into sewers, water
courses, basements or confined areas. Vacuum or sweep up
material and place in a designated, labelled waste container.
Dispose of via a licensed waste disposal contractor.

Handling and storage

Precautions for safe handling: Put on appropriate personal protective equipment (see Section 8).
Eating, drinking and smoking should be prohibited in areas where
this material is handled, stored and processed. Workers should wash
hands and face before eating, drinking and smoking. Do not ingest.
Avoid contact with eyes, skin and clothing. Avoid release to the
environment. Keep in the original container or an approved
alternative made from a compatible material, kept tightly closed
when not in use. Empty containers retain product residue and can be
hazardous.
Conditions for safe storage, including any incompatibilities: Do not store above the following temperature: 40°C (104°F). Store
in accordance with local regulations. Store in original container
protected from direct sunlight in a dry, cool and well-ventilated area,
away from incompatible materials and food and
drink. Keep container tightly closed and sealed until ready for use.
Containers that have been opened must be carefully resealed and
kept upright to prevent leakage. Do not store in unlabelled
containers. Use appropriate containment to avoid environmental
contamination.
Seveso III Directive - Reporting thresholds (in tonnes)
Danger criteria
Category
E1: Hazardous to the aquatic environment - Acute 1 or Chronic 1
Notification and MAPP threshold: 100
Safety report threshold: 200
Category
C9i: Very toxic for the environment
Notification and MAPP threshold: 100
Safety report threshold: 200

Remarks : Keep away from direct sunlight or strong incandescent light.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(TIOXAZAFEN)
Chemical name:
3-phenyl-5-(2-thienyl)-1,2,4-oxadiazole
Language:
English
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. , (Tioxazafen)
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(TIOXAZAFEN)
Chemical name:
3-phenyl-5-(2-thienyl)-1,2,4-oxadiazole
Language:
English
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. , (Tioxazafen)
Special provisions / remarks
Remarks:
Hazard notes:
Environmentally hazardous substance.
Avoid heat above +40 °C
Keep separated frim foodstuffs

Marine transport (UN RTDG/IMDG)

UN number:
UN3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. , (Tioxazafen)
Chemical name:
3-phenyl-5-(2-thienyl)-1,2,4-oxadiazole
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. , (Tioxazafen)
Marine pollutant
Special provisions / remarks
Remarks:
Hazard notes:
Environmentally hazardous substance.
Avoid heat above +40 °C
Keep separated frim foodstuffs

Air transport (UN RTDG/ICAO/IATA)

UN number:
UN3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. , (Tioxazafen)
Chemical name:
3-phenyl-5-(2-thienyl)-1,2,4-oxadiazole
Labels:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. , (Tioxazafen)
Special provisions / remarks
Remarks:
Passenger aircraft: 956: 400 kg
Cargo aircraft: 956: 400 kg

Hazard notes:
Environmentally hazardous substance.
Avoid heat above +40 °C
Keep separated frim foodstuffs
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters
Exposure limit values : Not available.
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.
Exposure controls
Risk management measures
Occupational exposure controls
Technical measures: If this product contains ingredients with exposure limits, use process
enclosures, local exhaust ventilation or other engineering controls to
keep worker exposure below any recommended or statutory limits.
Personal protection measures
Respiratory protection: Use a properly fitted, air-purifying or air-fed respirator complying with
an approved standard if a risk assessment indicates this is
necessary. Respirator selection must be based on known or
anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Recommended: Full mask with type ABEK-P1 filter
Hand protection: Chemical-resistant, impervious gloves complying with an approved
standard should be worn at all times when handling chemical
products if a risk assessment indicates this is necessary. After
contamination with product change the gloves immediately and
dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) polyvinyl chloride (PVC) , Rubber gloves.
Eye protection: Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mists, gases or dusts.
Recommended: safety glasses with side-shields
Skin protection: Personal protective equipment for the body should be selected
based on the task being performed and the risks involved and
should be approved by a specialist before handling this product.
Recommended: Wear protective clothing.
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical
products, before eating, smoking and using the lavatory and at the
end of the working period. Appropriate techniques should be used
to remove potentially contaminated clothing. Wash contaminated
clothing before reusing. Ensure that eyewash stations and safety
showers are close to the workstation location.
Environmental exposure controls
Technical measures: Emissions from ventilation or work process equipment should be
checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable
levels.

Stability and reactivity

Reactivity: No specific test data related to reactivity available for this product or
its ingredients.
Chemical stability: The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions
will not occur.
Conditions to avoid: Avoid dust formation. Capable of causing a dust explosion
Incompatible materials: No specific data.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous
decomposition products should not be produced.

Disposal considerations

Waste treatment methods
Product
Methods of disposal: Examine possibilities for re-utilisation. Product residues and
uncleaned empty containers should be packaged, sealed, labelled,
and disposed of or recycled according to relevant national and local
regulations. Where large quantities are concerned, consult the
supplier. When uncleaned empty containers are passed on, the
recipient must be warned of any possible hazard that may be caused
by residues. For disposal within the EC, the appropriate code
according to the European Waste List (EWL) should be used. It is
among the tasks of the polluter to assign the waste to waste codes
specific to industrial sectors and processes according to the
European Waste List (EWL).
Hazardous waste: The classification of the product may meet the criteria for a
hazardous waste.
Packaging
Methods of disposal: The generation of waste should be avoided or minimised wherever
possible. Waste packaging should be recycled. Incineration or
landfill should only be considered when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way.
Care should be taken when handling emptied containers that have
not been cleaned or rinsed out. Empty containers or liners may
retain some product residues. Avoid dispersal of spilt material and
runoff and contact with soil, waterways, drains and sewers.