Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 202-867-2 | CAS number: 100-58-3
Guidance on Safe Use
Administrative data
First-aid measures
After skin contact: Remove contaminated clothing. Wash affected area with plenty water. Obtain medical attention when corrosion occurs. Rub skin
with cream.
After eye contact: Immediately flush affected eye(s) with water and continue flushing for at least 15 min. Obtain medical attention and continue
to flush during transport. Risk of permanent eye damage.
After ingestion: Flush mouth with water and drink plenty of water or milk. Do not try to induce vomiting. Do not give unconscious patients anything to drink. Obtain medical attention.
Fire-fighting measures
Formation of toxic and corrosive gasses is possible. Avoid inhalation of fumes.
Accidental release measures
Absorb spillage in absorbing material and transfer to suitable container. Wash the spillage area with plenty of water, and prevent entry into drains.
Handling and storage
Pregnant and breastfeeding women should not be exposed to the substance.
Avoid inhalation of vapours.
Immediately remove contaminated clothes.
The substance should preferable be used in closed systems and be handled in well-ventialted systems.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 3399
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE FLAMMABLE
- Chemical name:
- Phenylmagnesiumbromide in THF
- Language:
- English
- Labels:
- 4.3+3
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 3399
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE FLAMMABLE
- Chemical name:
- Phenylmagnesiumbromide in THF
- Language:
- English
- Labels:
- 4.3+3
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 3399
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE FLAMMABLE
- Chemical name:
- Phenylmagnesiumbromide in THF
- Labels:
- 4.3+3
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 3399
Shipping information
- Proper shipping name and description:
- ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE FLAMMABLE
- Chemical name:
- Phenylmagnesiumbromide in THF
- Labels:
- 4.3+3
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Use tightly sealed goggles.
Use protective gloves (FKM).
Stability and reactivity
The product is a flammable liquid and and vapours may form explosive mixtures with air.
The product should be disposed of according to local regulations.
Disposal considerations
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
