Cyclohex-3-ene-1-carbaldehyde

Phototransformation in air

Link to relevant study record(s)

Reference

Endpoint:

phototransformation in air

Type of information:

(Q)SAR

Reliability:

2 (reliable with restrictions)

Rationale for reliability incl. deficiencies:

results derived from a valid (Q)SAR model and falling into its applicability domain, with adequate and reliable documentation / justification

Justification for type of information:

QSAR prediction

Principles of method if other than guideline:

Calculated with AOP Program v1.92 of EPI-Suite Software. The Atmospheric Oxidation Program (AOPWIN) estimates the rate constant for the atmospheric, gas-phase reaction between photochemically produced hydroxyl radicals and organic chemicals. The rate constants are then used to calculate atmospheric half-lives for organic compounds based upon average atmospheric concentrations of hydroxyl radicals and ozone.

GLP compliance:

no

Estimation method (if used):

PHOTOCHEMICAL REACTION WITH OH RADICALS
- sensitiser for indirect photolysis: OH radicals
- Concentration of OH radicals: 0.5 E6 OH/cm³, 24 h/d

Key result

% Degr.:

50

Key result

DT50:

4.3 h

Test condition:

at 25 °C

A 24-hour day and an OH radical concentration of 0.5*10⁶ OH/cm³ are assumed for the calculation.

Rate constant = 89*10 ^-12 cm³/(molecule*sec)

Conclusions:

The photodegradation of cyclohex-3-ene-1-carbaldehyde was calculated at t ½ = 4.3 hours at 25 °C and rate constant = 89E-12 cm3/(molecule*sec) by AOPWIN v. 1.92.

Executive summary:

The photodegradation of cyclohex-3-ene-1-carbaldehyde was calculated at t _½ = 4.3 hours at 25 °C and rate constant = 89E-12 cm³/(molecule*sec) by AOPWIN v. 1.92.

Description of key information

The photodegradation of cyclohex-3-ene-1-carbaldehyde was calculated at t ½ = 4.3 hours at 25 °C and rate constant = 89E-12 cm3/(molecule*sec) by AOPWIN v. 1.92.

Key value for chemical safety assessment

Half-life in air:

4.3 h

Degradation rate constant with OH radicals:

0 cm³ molecule-1 s-1