Registration Dossier

Diss Factsheets

Administrative data

First-aid measures

General advice: Take the victim out of the contaminated area. Remove contaminated clothing immediately and dispose of safely.
If inhaled: Make the victim breathe fresh air. Make the victim blow his nose. Seek medical advice.
In case of skin contact: Rinse immediately with plenty of water for at least 15 minutes. Seek medical advice.
In case of eye contact: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical advice.
If swallowed: Do not induce vomiting. Make the victim rinse his mouth with water. Seek medical advice.

Most important symptoms and effects, both acute and delayed
Symptoms: Irritations. Lachrymator.

Fire-fighting measures

Extinguishing media:
Suitable extinguishing media: All means (e.g. water, carbon dioxide, dry chemical extinguisher).
Unsuitable extinguishing media: Strong water jet.

Special hazards arising from the substance or mixture:
In case of fire, the product may emit toxic and/or irritating fumes. Supposed thermal decomposition/oxidation:
Carbon monoxide and carbon dioxide
Hydrogen chloride (HCl)
Possible explosive mixtures (vapors heavier than air).

Advice for firefighters:
Special protective equipment: Use self-contained breathing apparatus. Wear full protective suit.
Further information: Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Cool containers/tanks with water spray. Avoid discharging extinguishing water in the environment.

Accidental release measures

Personal precautions, protective equipment and emergency procedures: Appropriate gas full face respirator or air supplied hood depending on released quantities. Suitable gloves. Dedicated work clothes.

Environmental precautions: Avoid any spreading of the product.

Methods and materials for containment and cleaning up:
General advice: Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep and shovel the solid product into a container specially adapted for its recovery or destroying (avoiding dust formation). Close and label thoroughly.
Cleaning of contaminated zone: After cleaning up the product, rinse the polluted area with water.
Elimination of recovered materials: Deliver to the Environmental service of the factory or to any specialized and approved disposal company.

Additional advice: Evacuation of area and intervention of special services recommended.

Handling and storage

Precautions for safe handling:
Advice on safe handling (industrial scale): Local ventilation and emission point fume extraction. Enclosed transfer recommended. Earth vessels and equipment well. Take precautionary measures against electrostatic loading.
Advice on safe handling (laboratory scale): Handling in a hood.

Conditions for safe storage, including any incompatibilities:
Requirements for storage rooms and vessels: Keep in a cool, well-ventilated place.
Advice on common storage: Do not store with strong oxidizing agents.
Further information on storage conditions: Keep containers tightly closed. Storage under inert gas (eg. nitrogen) recommended. Provide for a retention basin.
Storage temperature: Recommended storage temperature: +2°C to +8°C.
Advised packaging material: Brown glass.

Sensitivity
Light: The product is sensitive to light.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
1224
Shippingopen allclose all
Labels:
30
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
1224
Shippingopen allclose all
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
1224
Shippingopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Personal protection equipment
(IMPORTANT: to be adapted following the workplace risk assessment.)

Industrial workplace
Respiratory protection: Appropriate gas full face respirator or powered-air purifying respirator.
Hand protection: Suitable gloves. Glove material : Butyl rubber Layer thickness : 0,11 mm Break through time: > 480 min
Eye/face protection: See respiratory protection.
Body Protection: Dedicated working clothes recommended.
Hygiene measures: Wash hands.

Laboratory
Respiratory protection: Handling in a hood.
Hand protection: Suitable gloves.
Eye/face protection: Safety glasses.
Body Protection: Working clothes.
Hygiene measures: Wash hands.

Stability and reactivity

Safety remarks: Flammable. Keep away from sources of ignition --- No smoking.

Reactivity: No data available.
Chemical stability: No data available.
Possibility of hazardous reactions: No data available.
Conditions to avoid: No data available.
Incompatible materials: Strong oxidizing agents.
Hazardous decomposition products: Supposed thermal decomposition/oxidation:
Carbon monoxide and carbon dioxide
Hydrogen chloride (HCl)

Disposal considerations

Waste treatment methods:

Product: Deliver to the Environmental service of the factory or to any specialized and approved disposal service.
Uncleaned packaging: Deliver to the Environmental service of the factory or to any specialized and approved disposal service.