Registration Dossier

Administrative data

First-aid measures

General advice : Immediate medical attention is required.
Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Burns may occur several hours after the removal of the
product.
If inhaled : Obtain medical attention immediately.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Carefully remove paste or solidified product.
Wash skin immediately with 0,5 % acetic acid in water, and
then with soap and water.
Immediate medical treatment is necessary as untreated
wounds from corrosion of the skin heal slowly and with
difficulty.
Skin irritation, if untreated may be prolonged and serious (eg
necrosis). This may be prevented by early treatment with
medium strength corticosteroids.
In case of eye contact : In case of contact with eyes, rinse immediately with 0.5%
acetic acid in water for a few minutes, followed by rinsing with
plenty of water for as long as possible. Eyelids should be held
away from the eyeball to ensure thorough rinsing.
Get medical attention immediately. Continue to rinse during
transport.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
Small amounts splashed into eyes can cause irreversible
tissue damage and blindness.
If swallowed : Clean mouth with water and drink afterwards plenty of water.
Never give anything by mouth to an unconscious person.
Take victim immediately to hospital.
Do not induce vomiting! May cause chemical burns in mouth
and throat.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : The symptoms and effects are as expected from the hazards
as shown in section 2. No specific product related symptoms
are known.
Risks : Causes serious eye damage.
Causes severe burns.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.

Fire-fighting measures

Suitable extinguishing media : Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Unsuitable extinguishing
media
: High volume water jet
5.2 Special hazards arising from the substance or mixture
Specific hazards during
firefighting / Specific hazards
arising from the chemical
: Treat as oil fire.
Do not use a solid water stream as it may scatter and spread
fire.
Water spray may be ineffective unless used by experienced
firefighters.
Do not allow run-off from fire fighting to enter drains or water
courses.
Combustion products : No hazardous combustion products are known
Special protective equipment
for firefighters
: In the event of fire, wear self-contained breathing apparatus.
Further information : Collect contaminated fire extinguishing water separately. This
must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions : Use personal protective equipment.
Ensure adequate ventilation.
6.2 Environmental precautions
Environmental precautions : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities.
6.3 Methods and materials for containment and cleaning up
Methods for cleaning up /
Methods for containment
: Pick up and arrange disposal without creating dust.
Keep in suitable, closed containers for disposal.

Handling and storage

Advice on safe handling : For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Dispose of rinse water in accordance with local and national
regulations.
Advice on protection against
fire and explosion
: Provide appropriate exhaust ventilation at places where dust
is formed.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage
areas and containers
: Keep container tightly closed in a dry and well-ventilated
place.
Avoid elevated temperatures.
Reacts with copper, aluminium, zinc and their alloys.
Other data : No decomposition if stored and applied as directed.

Transport information

Land transport (ADR/RID)

UN number:
UN 3259
Proper shipping name and description:
AMINES, SOLID, CORROSIVE, N.O.S.
Chemical name:
(Dialkyltripropylenetetramine)
Language:
English
Class:
8
Classification code:
C8
Packaging group:
III
Labels:
8
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3259
Proper shipping name and description:
AMINES, SOLID, CORROSIVE, N.O.S.
Chemical name:
(Dialkyltripropylenetetramine)
Language:
English
Class:
8
Classification code:
C8
Packaging group:
III
Labels:
8
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3259
Proper shipping name and description:
AMINES, SOLID, CORROSIVE, N.O.S.
Chemical name:
(Dialkyltripropylenetetramine)
Class:
8
Packaging group:
III
EmS code:
F-A, S-B
Labels:
8
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 3259
Proper shipping name and description:
AMINES, SOLID, CORROSIVE, N.O.S.
Chemical name:
(Dialkyltripropylenetetramine)
Class:
8
Packaging group:
III
Labels:
8
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering controls
Provide eyewash station and safety shower. Keep solutions of 0.5% acetic acid in water close at
hand.
Personal protective equipment
Respiratory protection : In the case of dust, vapour or aerosol formation use a
respirator with an approved filter.
Wear full face mask supplied with:
Combination filter: ABEKP.
Hand protection : Nitrile rubber
butyl-rubber
Eye protection : Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.
Skin and body protection : Protective suit
Hygiene measures : Avoid contact with skin, eyes and clothing.
Dry-clean contaminated clothes before reuse.
Environmental exposure controls
General advice : Do not flush into surface water or sanitary sewer system.
If the product contaminates rivers and lakes or drains inform
respective authorities

Stability and reactivity

10.1 Reactivity
Stable under normal conditions.
10.2 Chemical stabilityStable under recommended storage conditions.
10.3 Possibility of hazardous reactions
No dangerous reaction known under conditions of normal use.
10.4 Conditions to avoid
Conditions to avoid : Extremes of temperature and direct sunlight.
10.5 Incompatible materials
Materials to avoid : Reacts with copper, aluminium, zinc and their alloys.
10.6 Hazardous decomposition products
Hazardous decomposition
products
: No hazardous decomposition products are known.
Thermal decomposition : No data available

Disposal considerations

13.1 Waste treatment methods
Product : The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Hazardous waste
Dispose of contents/container in accordance with local
regulation.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.