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Administrative data

Endpoint:
auto-flammability
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
test procedure in accordance with national standard methods
Remarks:
Directive VDI 2263, Part 1

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2016
Report date:
2016

Materials and methods

Test guideline
Qualifier:
according to guideline
Guideline:
other: Directive VDI 2263, Part 1

Test material

Constituent 1
Chemical structure
Reference substance name:
Trisodium 5-[[5-methyl-4-[(4-nitro-2-sulphonatophenyl)azo]-2-(3-sulphonatopropoxy)phenyl]azo]salicylate
EC Number:
277-753-9
EC Name:
Trisodium 5-[[5-methyl-4-[(4-nitro-2-sulphonatophenyl)azo]-2-(3-sulphonatopropoxy)phenyl]azo]salicylate
Cas Number:
74186-17-7
Molecular formula:
C23H21N5O12S2.3Na
IUPAC Name:
trisodium 2-hydroxy-5-({5-methyl-4-[(4-nitro-2-sulfonatophenyl)diazenyl]-2-(3-sulfonatopropoxy)phenyl}diazenyl)benzoate

Results and discussion

Auto-ignition temperature (liquids / gases)open allclose all
Auto-ignition temperature:
>= 220 °C
Atm. press.:
ca. 1 013 hPa
Remarks on result:
other: pure test substance
Auto-ignition temperature:
>= 230 °C
Atm. press.:
ca. 1 013 hPa
Remarks on result:
other: 1:1 mixture of test substance with Kieselguhr
Relative self-ignition temperature (solids)open allclose all
Relative self-ignition temperature:
>= 220 °C
Remarks on result:
other: pure test substance
Remarks:
at atm. press. of ca.1013.0 hPa
Relative self-ignition temperature:
>= 230 °C
Remarks on result:
other: 1:1 mixture of test substance with Kieselguhr
Remarks:
at atm. press. of ca.1013.0 hPa

Any other information on results incl. tables

In the screening test according to Grewer with the pure product an exothermal effect was detected starting at 220 °C. A multistage reaction was observed which led to a maximum product temperature of more than 500 °C.

In the screening test with the kieselgur mixture (1:1) an exothermal effect was detected starting at 230 °C. A multistage reaction was observed which led to a maximum product temperature of more than 450 °C

Between 60 and 160 °C an endothermal effect was observed. After the test the mesh wire basket of the pure product was black and swollen.

See figures 1 and 2 (attachment)

Applicant's summary and conclusion

Conclusions:
The substance has not to be classified as self-heating according to Regulation (EC) No 1272/2008, Annex I, 2.11.4